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Polylithionite |
 |
Brigatti M F, Mottana A, Malferrari D, Cibin G |
 |
American Mineralogist 92 (2007) 1395-1400 |
|
Crystal structure and chemical composition of Li-, Fe-, and Mn-rich micas |
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Locality: Hirukawa mine, Ena county, Gifu prefecture, Chibu region, Japan |
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Sample: Hirukawa |
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_database_code_amcsd 0004416 |
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5.264 9.086 10.099 90 100.719 90 C2 |
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atom x y z occ Uiso U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3) |
|
SiT1 .0749 .1698 .2290 .86 .012 .012 .003 .019 0 .002 -.002 |
|
AlT1 .0749 .1698 .2290 .14 .012 .012 .003 .019 0 .002 -.002 |
|
SiT11 .5862 .3331 .2299 .86 .010 .008 .007 .017 .001 .004 -.001 |
|
AlT11 .5862 .3331 .2299 .14 .010 .008 .007 .017 .001 .004 -.001 |
|
LiM1 0 .9929 .5 .72 .012 .012 .007 .020 0 .008 0 |
|
FeM1 0 .9929 .5 .19 .012 .012 .007 .020 0 .008 0 |
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MnM1 0 .9929 .5 .08 .012 .012 .007 .020 0 .008 0 |
|
MgM1 0 .9929 .5 .01 .012 .012 .007 .020 0 .008 0 |
|
AlM2 0 .3234 .5 .010 .010 .009 .014 0 .007 0 |
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LiM3 .5 .1613 .5 .72 .012 .008 .005 .022 0 -.003 0 |
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FeM3 .5 .1613 .5 .19 .012 .008 .005 .022 0 -.003 0 |
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MnM3 .5 .1613 .5 .09 .012 .008 .005 .022 0 -.003 0 |
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KA 0 .5020 0 .95 .028 .027 .022 .034 0 .008 0 |
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NaA 0 .5020 0 .05 .028 .027 .022 .034 0 .008 0 |
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O1 .0405 1.0026 .1710 .022 .030 .011 .024 .002 .002 -.006 |
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O2 .3160 .2422 .1693 .025 .019 .030 .026 -.003 .002 -.003 |
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O22 .8183 .2592 .1627 .021 .015 .021 .027 .004 .009 -.003 |
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O3 .1173 .1760 .3921 .014 .012 .013 .017 -.001 0 -.004 |
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O33 .6618 .3270 .3930 .018 .015 .011 .026 0 .003 -.002 |
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OH4 .1090 .4715 .3987 .06 .018 .024 .008 .023 -.004 .007 0 |
|
F4 .1090 .4715 .3987 .94 .018 .024 .008 .023 -.004 .007 0 |
|
|
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| |
|
Polylithionite |
|
Brigatti M F, Mottana A, Malferrari D, Cibin G |
|
American Mineralogist 92 (2007) 1395-1400 |
|
Crystal structure and chemical composition of Li-, Fe-, and Mn-rich micas |
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Locality: Mokrusha mine, Yuzhakova village, Murzinka region, Russia |
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Sample: Mokrusha |
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_database_code_amcsd 0004417 |
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5.297 9.133 10.168 90 100.78 90 C2 |
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atom x y z occ Uiso U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3) |
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SiT1 .0754 .1693 .2296 .83 .013 .009 .010 .023 .004 .006 .001 |
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AlT1 .0754 .1693 .2296 .17 .013 .009 .010 .023 .004 .006 .001 |
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SiT11 .5859 .3332 .2291 .83 .011 .013 .008 .011 .003 0 .002 |
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AlT11 .5859 .3332 .2291 .17 .011 .013 .008 .011 .003 0 .002 |
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LiM1 0 .9920 .5 .66 .015 .011 .010 .025 0 .005 0 |
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FeM1 0 .9920 .5 .17 .015 .011 .010 .025 0 .005 0 |
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MnM1 0 .9920 .5 .16 .015 .011 .010 .025 0 .005 0 |
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MgM1 0 .9920 .5 .01 .015 .011 .010 .025 0 .005 0 |
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AlM2 0 .3226 .5 .014 .005 .009 .028 0 .006 0 |
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LiM3 .5 .1620 .5 .66 .009 .008 .008 .008 0 -.003 0 |
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FeM3 .5 .1620 .5 .19 .009 .008 .008 .008 0 -.003 0 |
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MgM3 .5 .1620 .5 .15 .009 .008 .008 .008 0 -.003 0 |
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KA 0 .5010 0 .94 .029 .028 .023 .035 0 .003 0 |
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NaA 0 .5010 0 .04 .029 .028 .023 .035 0 .003 0 |
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CaA 0 .5010 0 .01 .029 .028 .023 .035 0 .003 0 |
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O1 .0301 1.0026 .1717 .023 .023 .018 .025 .005 0 -.011 |
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O2 .3206 .2370 .1697 .027 .020 .037 .023 -.006 .005 -.008 |
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O22 .8197 .2635 .1633 .021 .019 .023 .023 .007 .010 -.003 |
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O3 .1203 .1770 .3937 .017 .018 .021 .010 .009 -.001 -.002 |
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O33 .6602 .3288 .3931 .021 .027 .008 .028 .010 .004 .002 |
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OH4 .1116 .4749 .4001 .05 .019 .019 .017 .021 -.005 .002 -.001 |
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F4 .1116 .4749 .4001 .95 .019 .019 .017 .021 -.005 .002 -.001 |
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| |
|
Masutomilite |
|
Brigatti M F, Mottana A, Malferrari D, Cibin G |
|
American Mineralogist 92 (2007) 1395-1400 |
|
Crystal structure and chemical composition of Li-, Fe-, and Mn-rich micas |
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Locality: Sawtooth Mountains, Boise county, Idaho, USA |
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Sample: Boise |
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_database_code_amcsd 0004418 |
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5.2984 9.1461 10.0966 90 100.818 90 C2 |
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atom x y z occ Uiso U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3) |
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SiT1 .0745 .1699 .2275 .78 .011 .008 .011 .014 .001 .002 0 |
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AlT1 .0745 .1699 .2275 .22 .011 .008 .011 .014 .001 .002 0 |
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SiT11 .5852 .3328 .2273 .78 .011 .008 .011 .013 .001 .001 0 |
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AlT11 .5852 .3328 .2273 .22 .011 .008 .011 .013 .001 .001 0 |
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LiM1 0 .9921 .5 .51 .012 .012 .010 .014 0 .004 0 |
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FeM1 0 .9921 .5 .22 .012 .012 .010 .014 0 .004 0 |
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MnM1 0 .9921 .5 .26 .012 .012 .010 .014 0 .004 0 |
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MgM1 0 .9921 .5 .01 .012 .012 .010 .014 0 .004 0 |
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AlM2 0 .3231 .5 .91 .009 .008 .010 .008 0 .001 0 |
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LiM2 0 .3231 .5 .05 .009 .008 .010 .008 0 .001 0 |
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TiM2 0 .3231 .5 .02 .009 .008 .010 .008 0 .001 0 |
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MgM2 0 .3231 .5 .02 .009 .008 .010 .008 0 .001 0 |
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LiM3 .5 .1615 .5 .50 .013 .008 .015 .016 0 0 0 |
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FeM3 .5 .1615 .5 .24 .013 .008 .015 .016 0 0 0 |
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MnM3 .5 .1615 .5 .26 .013 .008 .015 .016 0 0 0 |
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KA 0 .5029 0 .92 .029 .026 .030 .030 0 .003 0 |
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NaA 0 .5029 0 .05 .029 .026 .030 .030 0 .003 0 |
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RbA 0 .5029 0 .02 .029 .026 .030 .030 0 .003 0 |
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O1 .0359 1.0025 .1718 .023 .027 .020 .020 -.002 .001 -.001 |
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O2 .3222 .2398 .1724 .021 .017 .027 .019 -.006 .005 -.001 |
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O22 .8149 .2616 .1594 .021 .019 .026 .017 .006 .003 .001 |
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O3 .1143 .1754 .3924 .012 .011 .013 .012 .002 .004 .001 |
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O33 .6641 .3272 .3921 .014 .010 .014 .018 .002 .001 0 |
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OH4 .1092 .4718 .3978 .06 .016 .015 .017 .015 -.002 .002 .003 |
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F4 .1092 .4718 .3978 .94 .016 .015 .017 .015 -.002 .002 .003 |
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|
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|
| |
|
Wiluite |
| |
Bellatreccia F, Camara F, Ottolini L, Della Ventura G, Cibin G, Mottana A |
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The Canadian Mineralogist 43 (2005) 1457-1468 |
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Wiluite from Ariccia, Latium, Italy: Occurrence and crystal structure |
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Locality: Ariccia, Latium, Italy |
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_database_code_amcsd 0006057 |
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15.716 15.716 11.704 90 90 90 *P4/nnc |
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.25 .25 .25 |
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atom x y z occ Uiso U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3) |
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CaX1 .75 .25 .25 .0092 .0137 .0080 .0058 0 0 0 |
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CaX2 -.19038 .04495 .37987 .97875 .0101 .0096 .0119 .0087 .0016 -.0011 .0001 |
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MgX2 -.19038 .04495 .37987 .01875 .0101 .0096 .0119 .0087 .0016 -.0011 .0001 |
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SrX2 -.19038 .04495 .37987 .0025 .0101 .0096 .0119 .0087 .0016 -.0011 .0001 |
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CaX3 -.10090 -.17893 .89483 .97861 .0175 .0131 .0160 .0234 .0004 -.0044 -.0023 |
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LaX3 -.10090 -.17893 .89483 .00625 .0175 .0131 .0160 .0234 .0004 -.0044 -.0023 |
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CeX3 -.10090 -.17893 .89483 .005 .0175 .0131 .0160 .0234 .0004 -.0044 -.0023 |
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NdX3 -.10090 -.17893 .89483 .00125 .0175 .0131 .0160 .0234 .0004 -.0044 -.0023 |
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CaX4 .75 .75 .14318 .5 .0105 .0087 .0087 .0142 0 0 0 |
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Fe3+Y1 .75 .75 .05586 .18 .0188 .0102 .0102 .0359 0 0 0 |
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TiY1 .75 .75 .05586 .135 .0188 .0102 .0102 .0359 0 0 0 |
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MgY1 .75 .75 .05586 .13 .0188 .0102 .0102 .0359 0 0 0 |
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MnY1 .75 .75 .05586 .055 .0188 .0102 .0102 .0359 0 0 0 |
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AlY2 0 0 0 .9175 .0091 .0076 .0078 .0118 .0005 -.0002 -.0009 |
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Fe3+Y2 0 0 0 .0475 .0091 .0076 .0078 .0118 .0005 -.0002 -.0009 |
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MgY2 0 0 0 .035 .0091 .0076 .0078 .0118 .0005 -.0002 -.0009 |
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MgY3 -.11165 .12018 .12789 .41875 .0094 .0101 .0100 .0081 .0007 .0004 -.0004 |
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AlY3 -.11165 .12018 .12789 .41125 .0094 .0101 .0100 .0081 .0007 .0004 -.0004 |
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Fe3+Y3 -.11165 .12018 .12789 .17 .0094 .0101 .0100 .0081 .0007 .0004 -.0004 |
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BT1 .05304 .05304 .25 .545 .0183 .0217 .0217 .0115 -.0066 -.0089 .0089 |
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AlT1 .05304 .05304 .25 .005 .0183 .0217 .0217 .0115 -.0066 -.0089 .0089 |
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BeT1 .05304 .05304 .25 .005 .0183 .0217 .0217 .0115 -.0066 -.0089 .0089 |
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HT1 .05304 .05304 .25 .1175 .0183 .0217 .0217 .0115 -.0066 -.0089 .0089 |
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BT2 .25 .25 .25 .68 .0100 |
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HT2 .25 .25 .2070 .16 .0200 |
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SiZ1 .75 .25 0 .0069 .0075 .0075 .0056 0 0 0 |
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SiZ2 -.17859 .04304 .87208 .0099 .0096 .0129 .0073 .0017 -.0006 .0018 |
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SiZ3 -.08389 -.15020 .36491 .0079 .0099 .0070 .0070 .0014 .0006 .0003 |
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O1 -.21994 .17280 .08462 .0107 .0140 .0092 .0090 .0000 -.0005 .0008 |
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O2 -.12070 .16054 .28284 .0127 .0166 .0102 .0113 -.0002 -.0046 .0014 |
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O3 -.04282 .22472 .07802 .0133 .0173 .0126 .0101 .0056 .0029 .0020 |
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O4 -.06177 .10461 .47133 .0103 .0122 .0097 .0091 .0004 -.0018 .0008 |
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O5 -.17148 .01169 .17953 .0117 .0119 .0131 .0101 .0048 .0004 -.0014 |
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O6 -.12105 -.27629 .05351 .0148 .0190 .0122 .0133 .0021 .0023 .0053 |
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O7A .05565 .1760 .3201 .5 .0102 |
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O7B .0445 .1466 .3069 .5 .0172 |
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O8 -.06037 -.09201 .06654 .0099 .0089 .0093 .0114 .0018 .0017 -.0003 |
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O9 -.14607 -.14607 .25 .0124 .0136 .0136 .0099 -.0018 -.0015 .0015 |
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O10 .75 .75 .8700 .66 .0305 .0317 .0317 .0279 0 0 0 |
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O11A -.0030 .0628 .1351 .48438 .0079 |
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O11B -.0013 .0536 .1543 .36438 .0109 |
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F11B -.0013 .0536 .1543 .15124 .0109 |
|
O12 .1772 .2733 .2044 .34 .0263 |
|
|
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|
| |
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Muscovite |
|
Brigatti M F, Galli E, Medici L, Poppi L, Cibin G, Marcelli A, Mottana A |
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European Journal of Mineralogy 13 (2001) 377-389 |
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Chromium-containing muscovite: crystal chemistry and XANES spectroscopy |
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Locality: Westland |
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_database_code_amcsd 0006858 |
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5.192 9.011 20.028 90 95.74 90 C2/c |
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atom x y z occ Biso B(1,1) B(2,2) B(3,3) B(1,2) B(1,3) B(2,3) |
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O11 .7510 .3106 .15823 1.18 .0093 .0043 .0007 -.0017 -.0002 .0004 |
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O21 .2504 .3707 .16935 1.05 .0090 .0037 .0006 .0018 .0000 -.0002 |
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O22 .4165 .0931 .16878 1.04 .0134 .0023 .0006 .0002 .0005 .0001 |
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O31 .3853 .2518 .05356 .67 .0071 .0016 .0005 .0001 .0000 .0000 |
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O32 .9612 .4436 .05363 .66 .0056 .0022 .0004 .0003 .0002 .0001 |
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O4 .9567 .0626 .05052 .083 .75 .0059 .0024 .0005 -.0002 .0004 -.0003 |
|
OH4 .9567 .0626 .05052 .9145 .75 .0059 .0024 .0005 -.0002 .0004 -.0003 |
|
Cl4 .9567 .0626 .05052 .0025 .75 .0059 .0024 .0005 -.0002 .0004 -.0003 |
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SiT1 .45154 .25856 .13581 .7775 .47 .0038 .0013 .0004 .0001 .0000 .0000 |
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AlT1 .45154 .25856 .13581 .2225 .47 .0038 .0013 .0004 .0001 .0000 .0000 |
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SiT2 .9649 .4297 .13577 .7775 .46 .0040 .0012 .0004 .0000 .0001 .0001 |
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AlT2 .9649 .4297 .13577 .2225 .46 .0040 .0012 .0004 .0000 .0001 .0001 |
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AlM1 .75 .25 0 .929 .50 |
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TiM1 .75 .25 0 .0015 .50 |
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FeM1 .75 .25 0 .0195 .50 |
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CrM1 .75 .25 0 .031 .50 |
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MgM1 .75 .25 0 .0405 .50 |
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AlM2 .24994 .08338 .00005 .4645 .51 .0041 .0014 .0004 -.0001 .0001 .0000 |
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TiM2 .24994 .08338 .00005 .0007 .51 .0041 .0014 .0004 -.0001 .0001 .0000 |
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FeM2 .24994 .08338 .00005 .0098 .51 .0041 .0014 .0004 -.0001 .0001 .0000 |
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CrM2 .24994 .08338 .00005 .0155 .51 .0041 .0014 .0004 -.0001 .0001 .0000 |
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MgM2 .24994 .08338 .00005 .0202 .51 .0041 .0014 .0004 -.0001 .0001 .0000 |
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BaA 0 .09883 .25 .044 1.54 .0151 .0049 .0009 .0000 .0003 .0000 |
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NaA 0 .09883 .25 .103 1.54 .0151 .0049 .0009 .0000 .0003 .0000 |
|
KA 0 .09883 .25 .857 1.54 .0151 .0049 .0009 .0000 .0003 .0000 |
|
|
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|
| |
|
Muscovite |
|
Brigatti M F, Galli E, Medici L, Poppi L, Cibin G, Marcelli A, Mottana A |
| |
European Journal of Mineralogy 13 (2001) 377-389 |
|
Chromium-containing muscovite: crystal chemistry and XANES spectroscopy |
|
Locality: Northwest Nelson - Campbell Creek |
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_database_code_amcsd 0006859 |
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5.175 8.979 19.915 90 95.66 90 C2/c |
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atom x y z occ Biso B(1,1) B(2,2) B(3,3) B(1,2) B(1,3) B(2,3) |
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O11 .7524 .3077 .15853 1.20 .0067 .0036 .0011 -.0013 .0001 .0003 |
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O21 .2518 .3727 .17000 1.08 .0069 .0032 .0009 .0008 0 -.0001 |
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O22 .4108 .0928 .16950 1.07 .0113 .0025 .0008 .0003 .0005 0 |
|
O31 .3842 .2518 .05401 .65 .0046 .0013 .0007 -.0005 -.0001 .0001 |
|
O32 .9620 .4442 .05384 .73 .0038 .0021 .0007 .0005 .0002 0 |
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O4 .9571 .0622 .05080 .0245 .76 .0041 .0019 .0008 -.0004 .0004 -.0003 |
|
OH4 .9571 .0622 .05080 .96 .76 .0041 .0019 .0008 -.0004 .0004 -.0003 |
|
F4 .9571 .0622 .05080 .0155 .76 .0041 .0019 .0008 -.0004 .0004 -.0003 |
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SiT1 .4508 .25839 .13644 .7673 .54 .0028 .0011 .0006 0 .0001 0 |
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AlT1 .4508 .25839 .13644 .2327 .54 .0028 .0011 .0006 0 .0001 0 |
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SiT2 .9645 .42948 .13638 .7673 .53 .0032 .0009 .0006 -.0001 .0002 .0001 |
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AlT2 .9645 .42948 .13638 .2327 .53 .0032 .0009 .0006 -.0001 .0002 .0001 |
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AlM2 .2498 .08334 .00001 .9215 .57 .0033 .0011 .0006 -.0001 .0002 .0001 |
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TiM2 .2498 .08334 .00001 .0095 .57 .0033 .0011 .0006 -.0001 .0002 .0001 |
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FeM2 .2498 .08334 .00001 .0105 .57 .0033 .0011 .0006 -.0001 .0002 .0001 |
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CrM2 .2498 .08334 .00001 .0495 .57 .0033 .0011 .0006 -.0001 .0002 .0001 |
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MgM2 .2498 .08334 .00001 .01 .57 .0033 .0011 .0006 -.0001 .0002 .0001 |
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CaA 0 .0979 .25 .004 1.84 .0161 .0056 .0013 0 .0006 0 |
|
NaA 0 .0979 .25 .268 1.84 .0161 .0056 .0013 0 .0006 0 |
|
KA 0 .0979 .25 .725 1.84 .0161 .0056 .0013 0 .0006 0 |
|
|
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|
| |
|
Muscovite |
|
Brigatti M F, Galli E, Medici L, Poppi L, Cibin G, Marcelli A, Mottana A |
| |
European Journal of Mineralogy 13 (2001) 377-389 |
|
Chromium-containing muscovite: crystal chemistry and XANES spectroscopy |
|
Locality: Northwest Nelson - Anatoki River |
|
_database_code_amcsd 0006860 |
|
5.206 9.040 20.058 90 95.79 90 C2/c |
|
atom x y z occ Biso B(1,1) B(2,2) B(3,3) B(1,2) B(1,3) B(2,3) |
|
O11 .7490 .3126 .1590 1.60 .0100 .0044 .0014 -.0004 0 0 |
|
O21 .2465 .3673 .1688 1.33 .0103 .0052 .0008 .0022 .0005 -.0001 |
|
O22 .4204 .0911 .1686 1.55 .0147 .0042 .0011 .0009 .0009 -.0002 |
|
O31 .3861 .2515 .0536 1.27 .0114 .0043 .0007 .0006 0 .0001 |
|
O32 .9614 .4416 .0538 1.05 .0101 .0027 .0007 .0004 .0002 -.0001 |
|
O4 .9566 .0619 .0504 .251 1.19 .0101 .0027 .0010 .0008 .0007 0 |
|
OH4 .9566 .0619 .0504 .728 1.19 .0101 .0027 .0010 .0008 .0007 0 |
|
F4 .9566 .0619 .0504 .0205 1.19 .0101 .0027 .0010 .0008 .0007 0 |
|
Cl4 .9566 .0619 .0504 .0005 1.19 .0101 .0027 .0010 .0008 .0007 0 |
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SiT1 .4520 .2587 .13564 .7838 .92 .0076 .0028 .0006 .0003 .0002 0 |
|
AlT1 .4520 .2587 .13564 .2162 .92 .0076 .0028 .0006 .0003 .0002 0 |
|
SiT2 .9653 .43054 .13556 .7838 .84 .0078 .0019 .0007 0 .0002 .0001 |
|
AlT2 .9653 .43054 .13556 .2162 .84 .0078 .0019 .0007 0 .0002 .0001 |
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AlM1 .75 .25 0 .913 2.03 |
|
TiM1 .75 .25 0 .0165 2.03 |
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FeM1 .75 .25 0 .051 2.03 |
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CrM1 .75 .25 0 .054 2.03 |
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MgM1 .75 .25 0 .055 2.03 |
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MnM1 .75 .25 0 .0005 2.03 |
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AlM2 .2494 .0836 .00008 .4565 1.10 .0100 .0027 .0008 .0001 .0001 .0001 |
|
TiM2 .2494 .0836 .00008 .0083 1.10 .0100 .0027 .0008 .0001 .0001 .0001 |
|
FeM2 .2494 .0836 .00008 .0255 1.10 .0100 .0027 .0008 .0001 .0001 .0001 |
|
CrM2 .2494 .0836 .00008 .027 1.10 .0100 .0027 .0008 .0001 .0001 .0001 |
|
MgM2 .2494 .0836 .00008 .0275 1.10 .0100 .0027 .0008 .0001 .0001 .0001 |
|
MnM2 .2494 .0836 .00008 .0002 1.10 .0100 .0027 .0008 .0001 .0001 .0001 |
|
BaA 0 .0977 .25 .012 2.23 .0183 .0068 .0016 0 .0005 0 |
|
NaA 0 .0977 .25 .029 2.23 .0183 .0068 .0016 0 .0005 0 |
|
KA 0 .0977 .25 .959 2.23 .0183 .0068 .0016 0 .0005 0 |
|
|
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|
| |
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