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Al11 Gd0.46 La0.43 Mg0.635 O18.46 |
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Salem Y, Linares C, Jacquier B, Saine M, Gasperin M, Lejus A, Vivien D |
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Journal of Chemical Physics 93 (1990) 7076-7084 |
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The sites of Gd^3+^ in the luminescent matrix La1-xGdxMgAl11O19: |
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single crystal structure determination and site-selective excitation of Gd^3+^ |
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_cod_database_code 1001462 |
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_database_code_amcsd 0013019 |
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5.565 5.565 21.89 90 90 120 P6_3/mmc |
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atom x y z occ |
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La1 2/3 1/3 .25 .43 |
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Gd1 .6727 .3755 .25 .077 |
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Al1 0 0 0 .917 |
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Mg1 0 0 0 .053 |
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Al2 1/3 2/3 .0273 .917 |
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Mg2 1/3 2/3 .0273 .053 |
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Al3 1/3 2/3 .1901 .917 |
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Mg3 1/3 2/3 .1901 .053 |
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Al4 .8322 .6644 .1085 .917 |
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Mg4 .8322 .6644 .1085 .053 |
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Al5 0 0 .2419 .458 |
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Mg5 0 0 .2419 .026 |
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O1 .1994 .3632 .25 .47 |
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O2 .1532 .3064 .0533 |
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O3 .5053 .0106 .1515 .94 |
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O4 0 0 .1511 |
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O5 2/3 1/3 .0578 |
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