data_global
_chemical_name_mineral 'Ferro-ferri-fluoro-leakeite'
loop_
_publ_author_name
'Hawthorne F C'
'Ungaretti L'
'Oberti R'
'Bottazzi P'
'Czamanske G K'
_journal_name_full 'American Mineralogist'
_journal_volume 78 
_journal_year 1993
_journal_page_first 733
_journal_page_last 745
_publ_section_title
;
 Li: an important component in igneous alkali amphiboles
 Sample: A(4), ferro-fluor-leakeite
;
_database_code_amcsd 0001589
_chemical_compound_source 'Questa caldera, New Mexico'
_chemical_formula_sum 'O22.4 (F1.6 Si7.8) Al.2 Mg.64 Fe2.92 Mn.66 Ti.07 Zn.07 Li.64 Na2.652 K.239 H.4'
_cell_length_a 9.796
_cell_length_b 17.934
_cell_length_c 5.312
_cell_angle_alpha 90
_cell_angle_beta 103.89
_cell_angle_gamma 90
_cell_volume 905.931
_exptl_crystal_density_diffrn      3.340
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
O1   0.11070   0.09040   0.20930   1.00000   0.00773
O2   0.11970   0.17140   0.73630   1.00000   0.00773
O-H3   0.11230   0.00000   0.70670   0.20000   0.01305
F   0.11230   0.00000   0.70670   0.80000   0.01305
O4   0.36510   0.24980   0.80120   1.00000   0.00988
O5   0.35050   0.12840   0.08340   1.00000   0.00975
O6   0.34200   0.12020   0.58060   1.00000   0.00950
O7   0.33580   0.00000   0.29870   1.00000   0.01064
SiT1   0.27970   0.08580   0.29200   0.97500   0.00532
AlT1   0.27970   0.08580   0.29200   0.02500   0.00532
SiT2   0.29020   0.17070   0.80250   0.97500   0.00519
AlT2   0.29020   0.17070   0.80250   0.02500   0.00519
MgM1   0.00000   0.08880   0.50000   0.30000   0.00747
Fe2+M1   0.00000   0.08880   0.50000   0.53000   0.00747
MnM1   0.00000   0.08880   0.50000   0.17000   0.00747
Fe2+M2   0.00000   0.18100   0.00000   0.03000   0.00608
Fe3+M2   0.00000   0.18100   0.00000   0.90000   0.00608
TiM2   0.00000   0.18100   0.00000   0.03500   0.00608
ZnM2   0.00000   0.18100   0.00000   0.03500   0.00608
LiM3   0.00000   0.00000   0.00000   0.64000   0.00836
MgM3   0.00000   0.00000   0.00000   0.04000   0.00836
MnM3   0.00000   0.00000   0.00000   0.32000   0.00836
NaM4   0.00000   0.27750   0.50000   1.00000   0.01482
KA   0.00000   0.50000   0.00000   0.06500   0.05940
NaA   0.00000   0.50000   0.00000   0.17800   0.05940
KAm   0.04470   0.50000   0.09630   0.08200   0.04116
NaAm   0.04470   0.50000   0.09630   0.22400   0.04116
KA2   0.00000   0.46610   0.00000   0.00500   0.02609
NaA2   0.00000   0.46610   0.00000   0.01300   0.02609