Cuprosklodowskite Rosenzweig A, Ryan R R American Mineralogist 60 (1975) 448-453 Refinement of the crystal structure of cuprosklodowskite, Cu[(UO2)2(SiO3OH)2]*6(H2O) Note: y(U) was changed to reproduce reported bond lengths Locality: Musonoi mine, Kolwezi, Katanga, Zaire CELL PARAMETERS: 7.0520 9.2670 6.6550 109.200 89.800 110.000 SPACE GROUP: P-1 X-RAY WAVELENGTH: 1.541838 MAX. ABS. INTENSITY / VOLUME**2: 90.97406541 2-THETA INTENSITY D-SPACING H K L 10.84 100.00 8.1615 0 1 0 13.46 2.99 6.5765 1 0 0 13.91 2.76 6.3649 -1 1 0 14.20 7.34 6.2372 0 0 1 14.56 40.62 6.0839 0 -1 1 18.33 19.41 4.8407 1 -1 1 18.36 20.48 4.8316 -1 0 1 20.72 9.53 4.2868 0 1 1 20.80 6.02 4.2713 1 0 1 21.32 2.33 4.1667 -1 -1 1 21.42 7.36 4.1487 -1 1 1 21.47 14.13 4.1396 0 -2 1 21.78 44.67 4.0808 0 2 0 21.87 2.16 4.0634 1 -2 1 25.28 31.08 3.5224 -2 1 0 26.81 1.82 3.3254 0 -1 2 27.12 15.89 3.2883 2 0 0 27.78 11.74 3.2112 1 1 1 28.04 13.97 3.1825 -2 2 0 28.56 2.15 3.1252 -1 -2 1 28.70 8.40 3.1100 -1 2 1 28.87 1.39 3.0923 2 -1 1 29.10 6.06 3.0684 -2 0 1 29.42 1.81 3.0362 1 -3 1 29.49 5.32 3.0287 2 -2 1 29.64 1.21 3.0142 1 2 0 29.91 13.65 2.9870 1 -1 2 30.17 15.61 2.9622 -1 0 2 30.31 11.23 2.9485 -1 -1 2 30.48 13.54 2.9327 1 -2 2 30.70 1.14 2.9125 -1 3 0 30.94 8.62 2.8902 0 -3 1 32.30 2.51 2.7717 2 0 1 32.83 6.09 2.7278 2 1 0 32.84 3.26 2.7275 -2 -1 1 32.92 5.28 2.7205 0 3 0 33.27 10.07 2.6927 1 0 2 33.51 2.44 2.6739 -2 2 1 33.89 7.98 2.6451 -1 1 2 33.96 3.12 2.6400 2 -3 1 34.17 2.92 2.6240 0 1 2 34.28 4.27 2.6161 -1 -2 2 34.37 4.12 2.6091 -2 3 0 34.80 2.49 2.5779 1 -3 2 38.04 1.45 2.3656 -1 3 1 39.56 2.84 2.2783 -2 -2 1 39.68 2.52 2.2717 1 1 2 40.54 2.78 2.2254 -1 2 2 40.72 2.95 2.2156 3 -2 1 40.77 4.69 2.2130 -3 1 1 40.88 3.66 2.2073 0 -1 3 41.00 3.45 2.2015 2 2 0 41.09 2.61 2.1967 -1 -3 2 41.17 2.98 2.1928 2 -4 1 41.29 3.24 2.1864 0 -2 3 41.49 3.89 2.1765 0 -4 1 41.66 2.81 2.1682 3 -1 1 41.86 3.65 2.1581 1 -4 2 41.97 1.16 2.1525 -3 0 1 42.66 2.04 2.1196 -3 2 1 42.78 1.35 2.1135 -1 -1 3 42.87 1.08 2.1095 3 -3 1 42.91 3.49 2.1078 -2 4 0 43.53 4.33 2.0791 0 0 3 43.68 2.10 2.0722 1 -1 3 43.73 1.22 2.0698 0 -4 2 44.04 1.25 2.0563 -1 0 3 44.40 6.13 2.0404 0 4 0 44.50 3.20 2.0360 -1 -2 3 44.76 3.83 2.0249 1 -3 3 45.51 3.44 1.9930 3 0 1 46.06 1.03 1.9707 -3 -1 1 47.32 3.42 1.9210 -3 3 1 47.36 3.36 1.9196 1 3 1 47.36 4.42 1.9196 3 -2 2 47.69 5.82 1.9070 -3 0 2 47.88 3.38 1.8999 -3 1 2 48.03 4.79 1.8942 3 -3 2 48.12 3.79 1.8910 1 2 2 48.23 1.96 1.8867 -2 -3 1 48.50 1.03 1.8771 2 -2 3 48.52 2.47 1.8763 -1 4 1 48.83 1.98 1.8652 0 1 3 48.87 1.26 1.8637 -2 0 3 48.94 1.35 1.8613 -1 -3 3 48.94 1.32 1.8611 -2 -1 3 49.14 1.17 1.8542 2 -3 3 49.14 3.25 1.8540 -1 3 2 49.43 4.11 1.8440 3 -1 2 49.46 1.23 1.8429 1 -4 3 49.81 1.34 1.8307 -1 -4 2 50.17 1.58 1.8182 2 -5 1 50.21 1.58 1.8169 -3 -1 2 50.55 2.11 1.8055 2 -1 3 50.59 1.39 1.8044 0 -4 3 50.69 1.91 1.8010 2 3 0 50.76 4.18 1.7986 -3 2 2 51.37 1.30 1.7788 3 -4 2 51.46 2.01 1.7758 -2 1 3 51.72 1.59 1.7674 0 3 2 51.78 1.07 1.7655 3 1 1 51.92 5.34 1.7612 -4 2 0 52.67 1.67 1.7378 -4 1 0 52.79 4.40 1.7342 0 -5 1 52.86 1.57 1.7321 -2 5 0 53.73 1.43 1.7058 -4 3 0 53.98 1.16 1.6986 -4 1 1 54.00 1.45 1.6980 3 0 2 54.45 1.10 1.6850 4 -3 1 55.18 2.30 1.6645 -3 -2 2 55.25 1.19 1.6627 0 -2 4 55.61 2.55 1.6527 -1 -4 3 55.92 2.41 1.6441 4 0 0 56.05 3.09 1.6407 0 -1 4 56.22 1.57 1.6361 0 2 3 56.34 2.52 1.6330 1 -5 3 56.91 2.39 1.6180 0 -3 4 57.03 2.08 1.6150 3 -5 2 57.96 1.72 1.5912 -4 4 0 58.30 2.22 1.5827 -2 -4 1 58.35 1.26 1.5815 -3 -1 3 58.65 1.26 1.5740 1 4 1 58.98 1.30 1.5661 3 -4 3 59.16 1.03 1.5618 -1 4 2 59.90 1.68 1.5441 -1 5 1 59.91 1.26 1.5439 -1 -5 2 59.94 1.70 1.5432 3 2 1 60.48 1.00 1.5307 -4 -1 1 60.50 2.26 1.5303 2 -6 1 60.70 1.96 1.5257 3 1 2 60.99 1.37 1.5192 1 -6 2 61.64 1.20 1.5047 2 -3 4 61.74 1.13 1.5025 -2 -1 4 62.15 1.70 1.4935 2 -2 4 62.73 1.63 1.4811 -2 0 4 62.85 1.03 1.4786 4 -5 1 62.89 1.76 1.4778 -3 5 1 63.06 1.31 1.4743 -2 -2 4 63.31 1.96 1.4690 -3 4 2 63.44 1.00 1.4664 2 -4 4 63.48 1.06 1.4655 -2 3 3 64.08 1.13 1.4532 -1 -5 3 64.65 1.09 1.4417 0 1 4 64.86 1.31 1.4375 0 -6 1 64.99 1.16 1.4351 1 -6 3 65.30 1.09 1.4289 0 3 3 67.00 1.26 1.3967 0 -5 4 67.43 1.37 1.3889 -3 -3 3 68.84 1.05 1.3639 4 2 0 69.38 1.22 1.3545 3 -6 3 69.67 1.19 1.3496 3 3 1 70.89 1.10 1.3293 1 5 1 70.97 1.27 1.3281 -3 -4 2 74.12 1.05 1.2793 -1 -6 3 75.25 1.04 1.2628 -4 -3 1 75.87 1.19 1.2540 0 4 3 77.93 1.10 1.2259 0 -7 1 79.13 1.01 1.2103 4 -7 1 82.08 1.14 1.1741 -6 3 0 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.