data_global
_chemical_name_mineral 'Deerite'
loop_
_publ_author_name
'Fleet M E'
_journal_name_full 'American Mineralogist'
_journal_volume 62 
_journal_year 1977
_journal_page_first 990
_journal_page_last 998
_publ_section_title
;
 The crystal structure of deerite
 Note: sample is from a riebeckite-deerite-garnet schist
 near Panoche, San Benito County, California, USA
;
_database_code_amcsd 0000599
_chemical_formula_sum 'Fe9 Si6 O25 H5'
_cell_length_a 10.786
_cell_length_b 18.880
_cell_length_c 9.564
_cell_angle_alpha 90
_cell_angle_beta 107.45
_cell_angle_gamma 90
_cell_volume 1857.979
_exptl_crystal_density_diffrn      3.847
_symmetry_space_group_name_H-M 'P 1 21/a 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2-y,z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Fe1   0.32090   0.17560   0.02380   0.01393
Fe2   0.32090   0.17560   0.35720   0.01393
Fe3   0.32090   0.17560   0.69050   0.01393
Fe4   0.16690   0.30420   0.13880   0.01393
Fe5   0.16690   0.30420   0.47220   0.01393
Fe6   0.16690   0.30420   0.80550   0.01393
Fe7   0.04430   0.42900   0.26540   0.01267
Fe8   0.04430   0.42900   0.59870   0.01267
Fe9   0.04430   0.42900   0.93210   0.01267
Si1   0.25800   0.53250   0.17000   0.01773
Si2   0.25800   0.53250   0.83600   0.01773
Si3   0.36200   0.41560   0.37100   0.01393
Si4   0.36200   0.41560   0.70500   0.01393
Si5   0.48600   0.30570   0.24500   0.02026
Si6   0.48600   0.30570   0.91100   0.02026
O1   0.25300   0.11800   0.16400   0.01520
O-H2   0.25300   0.11800   0.49700   0.01520
O3   0.25300   0.11800   0.83000   0.01520
O4   0.13200   0.23000   0.29800   0.01520
O-H5   0.13200   0.23000   0.63100   0.01520
O6   0.13200   0.23000   0.96400   0.01520
O7   0.49200   0.13500   0.08000   0.01393
O8   0.49200   0.13500   0.41400   0.01393
O9   0.49200   0.13500   0.74700   0.01393
O10   0.35600   0.25000   0.20300   0.02406
O-H11   0.35600   0.25000   0.53600   0.02406
O12   0.35600   0.25000   0.87000   0.02406
O13   0.22200   0.37400   0.32300   0.01393
O14   0.22200   0.37400   0.65600   0.01393
O-H15   0.22200   0.37400   0.99000   0.01393
O16   0.11000   0.49800   0.12200   0.01267
O-H17   0.11000   0.49800   0.45500   0.01267
O18   0.11000   0.49800   0.78800   0.01267
O19   0.47100   0.34300   0.08300 ?
O20   0.47700   0.37500   0.34600 ?
O21   0.46600   0.36800   0.80100 ?
O22   0.41400   0.43200   0.55100 ?
O23   0.35400   0.49100   0.77500 ?
O24   0.35600   0.49300   0.30300 ?
O25   0.32100   0.51600   0.02300 ?