data_global
_chemical_name_mineral 'Magnetoplumbite'
loop_
_publ_author_name
'Moore P B'
'Sen Gupta P K'
'Le Page Y'
_journal_name_full 'American Mineralogist'
_journal_volume 74 
_journal_year 1989
_journal_page_first 1186
_journal_page_last 1194
_publ_section_title
;
 Magnetoplumbite, PbFe12O19: Refinement and lone-pair splitting
 Note: Symmetry constraints on U(i,j) for Fe5, O4  and O5 were incorrect,
 and likely were refined wrong.
 They have been replaced with their isotropic equivalents.
;
_database_code_amcsd 0001279
_chemical_formula_sum 'Pb1.002 Fe12 O19'
_cell_length_a 5.873
_cell_length_b 5.873
_cell_length_c 23.007
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 687.243
_exptl_crystal_density_diffrn      5.711
_symmetry_space_group_name_H-M 'P 63/m m c'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x,-x+y,1/2+z'
  'x,x-y,1/2-z'
  '-x+y,-x,1/2-z'
  'x-y,x,1/2+z'
  '-y,-x,z'
  'y,x,-z'
  'y,-x+y,-z'
  '-y,x-y,z'
  'x-y,-y,1/2+z'
  '-x+y,y,1/2-z'
  'x,y,1/2-z'
  '-x,-y,1/2+z'
  'x,x-y,z'
  '-x,-x+y,-z'
  'x-y,x,-z'
  '-x+y,-x,z'
  'y,x,1/2+z'
  '-y,-x,1/2-z'
  '-y,x-y,1/2-z'
  'y,-x+y,1/2+z'
  '-x+y,y,z'
  'x-y,-y,-z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Pb   0.72000   0.38400   0.25000   0.16700 ?
Fe1   0.00000   0.00000   0.00000   1.00000 ?
Fe2   0.00000   0.00000   0.25590   0.50000 ?
Fe3   0.33333   0.66667   0.02733   1.00000 ?
Fe4   0.33333   0.66667   0.19019   1.00000 ?
Fe5   0.16870  -0.16870  -0.10881   1.00000   0.00595
O1   0.00000   0.00000   0.15110   1.00000 ?
O2   0.33333   0.66667  -0.05460   1.00000 ?
O3   0.18390  -0.18390   0.25000   1.00000   0.01279
O4   0.15650  -0.15650   0.05240   1.00000   0.00595
O5   0.50350  -0.50350   0.14990   1.00000   0.00646
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Pb 0.02180 0.01150 0.02290 0.00680 0.00000 0.00000
Fe1 0.00700 0.00700 0.00450 0.00350 0.00000 0.00000
Fe2 0.01040 0.01040 0.00260 0.00520 0.00000 0.00000
Fe3 0.00600 0.00600 0.00380 0.00300 0.00000 0.00000
Fe4 0.00760 0.00760 0.00430 0.00380 0.00000 0.00000
O1 0.01130 0.01130 0.00150 0.00565 0.00000 0.00000
O2 0.00560 0.00560 0.00520 0.00280 0.00000 0.00000