data_global
_chemical_name_mineral 'Fluoro-cannilloite'
loop_
_publ_author_name
'Hawthorne F C'
'Oberti R'
'Ungaretti L'
'Grice J D'
_journal_name_full 'American Mineralogist'
_journal_volume 81 
_journal_year 1996
_journal_page_first 995
_journal_page_last 1002
_publ_section_title
;
 A new hyper-calcic amphibole with Ca at the A site: Fluor-cannilloite from
 Pargas, Finland
 Sample: C1
;
_database_code_amcsd 0001823
_chemical_formula_sum 'O22.54 (F1.46 Si6.28) Al2.5 Mg3.79 Fe.45 Ti.02 Ca4.73 Mn.08 Na.7 K.05 H.54'
_cell_length_a 9.816
_cell_length_b 17.899
_cell_length_c 5.297
_cell_angle_alpha 90
_cell_angle_beta 105.35
_cell_angle_gamma 90
_cell_volume 897.465
_exptl_crystal_density_diffrn      3.563
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
O1   0.10570   0.08750   0.21560   1.00000   0.01026
O2   0.11970   0.17300   0.73670   1.00000   0.00887
O-H3   0.10760   0.00000   0.71490   0.27000   0.01241
F3   0.10760   0.00000   0.71490   0.73000   0.01241
O4   0.36740   0.25170   0.78950   1.00000   0.01165
O5   0.35320   0.14130   0.11490   1.00000   0.01279
O6   0.34570   0.11670   0.61420   1.00000   0.01368
O7   0.34510   0.00000   0.27550   1.00000   0.01532
Si1   0.28190   0.08550   0.30440   0.57000   0.00633
Al1   0.28190   0.08550   0.30440   0.43000   0.00633
Si2   0.29190   0.17370   0.81560   1.00000   0.00633
Mg1   0.00000   0.08940   0.50000   0.94000   0.00735
Fe1   0.00000   0.08940   0.50000   0.06000   0.00735
Mg2   0.00000   0.17530   0.00000   0.49000   0.00709
Al2   0.00000   0.17530   0.00000   0.39000   0.00709
Ti2   0.00000   0.17530   0.00000   0.01000   0.00709
Fe2   0.00000   0.17530   0.00000   0.11000   0.00709
Mg3   0.00000   0.00000   0.00000   0.93000   0.00735
Fe3   0.00000   0.00000   0.00000   0.07000   0.00735
Ca4   0.00000   0.27950   0.50000   0.97000   0.00899
Mn4   0.00000   0.27950   0.50000   0.02000   0.00899
Fe4   0.00000   0.27950   0.50000   0.01000   0.00899
Ca4*   0.00000   0.26570   0.50000   0.97000   0.03369
Mn4*   0.00000   0.26570   0.50000   0.02000   0.03369
Fe4*   0.00000   0.26570   0.50000   0.01000   0.03369
NaA   0.00000   0.50000   0.00000   0.14000   0.06206
KA   0.00000   0.50000   0.00000   0.01000   0.06206
CaA   0.00000   0.50000   0.00000   0.17000   0.06206
NaAm   0.05150   0.50000   0.10890   0.14000   0.04762
KAm   0.05150   0.50000   0.10890   0.01000   0.04762
CaAm   0.05150   0.50000   0.10890   0.17000   0.04762
NaA2   0.00000   0.46750   0.00000   0.14000   0.02508
KA2   0.00000   0.46750   0.00000   0.01000   0.02508
CaAm   0.00000   0.46750   0.00000   0.17000   0.02508