data_global
_chemical_name_mineral 'Fluoro-cannilloite'
loop_
_publ_author_name
'Hawthorne F C'
'Oberti R'
'Ungaretti L'
'Grice J D'
_journal_name_full 'American Mineralogist'
_journal_volume 81 
_journal_year 1996
_journal_page_first 995
_journal_page_last 1002
_publ_section_title
;
 A new hyper-calcic amphibole with Ca at the A site: Fluor-cannilloite from
 Pargas, Finland
 Sample: C3
;
_database_code_amcsd 0001825
_chemical_formula_sum 'O22.66 (F1.34 Si5.68) Al3.16 Mg3.66 Fe.48 Ti.02 Ca4.68 Mn.12 Na.6 K.25 H.66'
_cell_length_a 9.836
_cell_length_b 17.921
_cell_length_c 5.306
_cell_angle_alpha 90
_cell_angle_beta 105.40
_cell_angle_gamma 90
_cell_volume 901.712
_exptl_crystal_density_diffrn      3.565
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
O1   0.10530   0.08800   0.21540   1.00000   0.01026
O2   0.11940   0.17330   0.73730   1.00000   0.00887
O-H3   0.10750   0.00000   0.71520   0.33000   0.01178
F3   0.10750   0.00000   0.71520   0.67000   0.01178
O4   0.36750   0.25190   0.78960   1.00000   0.01127
O5   0.35310   0.14140   0.11530   1.00000   0.01178
O6   0.34540   0.11680   0.61560   1.00000   0.01317
O7   0.34440   0.00000   0.27730   1.00000   0.01596
Si1   0.28140   0.08570   0.30500   0.42000   0.00608
Al1   0.28140   0.08570   0.30500   0.58000   0.00608
Si2   0.29190   0.17380   0.81650   1.00000   0.00583
Mg1   0.00000   0.08960   0.50000   0.92000   0.00697
Fe1   0.00000   0.08960   0.50000   0.08000   0.00697
Mg2   0.00000   0.17540   0.00000   0.45000   0.00646
Al2   0.00000   0.17540   0.00000   0.42000   0.00646
Ti2   0.00000   0.17540   0.00000   0.01000   0.00646
Fe2   0.00000   0.17540   0.00000   0.12000   0.00646
Mg3   0.00000   0.00000   0.00000   0.92000   0.00697
Fe3   0.00000   0.00000   0.00000   0.08000   0.00697
Ca4   0.00000   0.28000   0.50000   0.97000   0.00773
Mn4   0.00000   0.28000   0.50000   0.03000   0.00773
Ca4*   0.00000   0.26920   0.50000   0.97000   0.01469
Mn4*   0.00000   0.26920   0.50000   0.03000   0.01469
NaA   0.00000   0.50000   0.00000   0.12000   0.07966
KA   0.00000   0.50000   0.00000   0.05000   0.07966
CaA   0.00000   0.50000   0.00000   0.16000   0.07966
NaAm   0.05210   0.50000   0.11070   0.12000   0.03762
KAm   0.05210   0.50000   0.11070   0.05000   0.03762
CaAm   0.05210   0.50000   0.11070   0.16000   0.03762
NaA2   0.00000   0.46750   0.00000   0.12000   0.02166
KA2   0.00000   0.46750   0.00000   0.05000   0.02166
CaA2   0.00000   0.46750   0.00000   0.16000   0.02166