data_global
_chemical_name_mineral 'Polylithionite'
loop_
_publ_author_name
'Brigatti M F'
'Lugli C'
'Poppi L'
'Foord E E'
'Kile D E'
_journal_name_full 'American Mineralogist'
_journal_volume 85 
_journal_year 2000
_journal_page_first 1275
_journal_page_last 1286
_publ_section_title
;
 Crystal chemical variations in Li- and Fe-rich micas from
 Pikes Peak batholith (central Colorado)
 Sample: 104
;
_database_code_amcsd 0002502
_chemical_formula_sum 'Si3.304 Al1.732 Li.963 Fe.788 Mg.009 Mn.01 Ca.001 Na.02 K.96 O10.394 F1.606 H.244'
_cell_length_a 5.285
_cell_length_b 9.122
_cell_length_c 10.101
_cell_angle_alpha 90
_cell_angle_beta 100.85
_cell_angle_gamma 90
_cell_volume 478.262
_exptl_crystal_density_diffrn      2.959
_symmetry_space_group_name_H-M 'C 1 2 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
SiT1   0.07540   0.16800   0.22841   0.82600
AlT1   0.07540   0.16800   0.22841   0.17400
SiT11   0.58490   0.33100   0.22840   0.82600
AlT11   0.58490   0.33100   0.22840   0.17400
LiM1   0.00000   0.99117   0.50000   0.34500
AlM1   0.00000   0.99117   0.50000   0.05600
FeM1   0.00000   0.99117   0.50000   0.40500
LiM2   0.00000   0.32180   0.50000   0.02000
AlM2   0.00000   0.32180   0.50000   0.98000
LiM3   0.50000   0.16060   0.50000   0.59800
MgM3   0.50000   0.16060   0.50000   0.00900
FeM3   0.50000   0.16060   0.50000   0.38300
MnM3   0.50000   0.16060   0.50000   0.01000
CaA   0.00000   0.50100   0.00000   0.00100
NaA   0.00000   0.50100   0.00000   0.02000
KA   0.00000   0.50100   0.00000   0.96000
O1   0.03560   0.99910   0.17170   1.00000
O2   0.32230   0.23710   0.17290   1.00000
O22   0.81630   0.26010   0.15980   1.00000
O3   0.11810   0.17390   0.39420   1.00000
O33   0.66220   0.32540   0.39260   1.00000
F4   0.10970   0.47160   0.39850   0.80300
O4   0.10970   0.47160   0.39850   0.07500
O-H4   0.10970   0.47160   0.39850   0.12200
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
SiT1 0.00975 0.00418 0.00899 0.00025 0.00114 -0.00013
AlT1 0.00975 0.00418 0.00899 0.00025 0.00114 -0.00013
SiT11 0.01279 0.00469 0.01191 0.00013 0.00253 0.00025
AlT11 0.01279 0.00469 0.01191 0.00013 0.00253 0.00025
LiM1 0.01355 0.00481 0.01355 0.00000 0.00405 0.00000
AlM1 0.01355 0.00481 0.01355 0.00000 0.00405 0.00000
FeM1 0.01355 0.00481 0.01355 0.00000 0.00405 0.00000
LiM2 0.01419 0.00646 0.00963 0.00000 0.00266 0.00000
AlM2 0.01419 0.00646 0.00963 0.00000 0.00266 0.00000
LiM3 0.01241 0.00760 0.01456 0.00000 0.00114 0.00000
MgM3 0.01241 0.00760 0.01456 0.00000 0.00114 0.00000
FeM3 0.01241 0.00760 0.01456 0.00000 0.00114 0.00000
MnM3 0.01241 0.00760 0.01456 0.00000 0.00114 0.00000
CaA 0.03268 0.02330 0.02900 0.00000 0.00456 0.00000
NaA 0.03268 0.02330 0.02900 0.00000 0.00456 0.00000
KA 0.03268 0.02330 0.02900 0.00000 0.00456 0.00000
O1 0.03407 0.01279 0.01862 0.00253 0.00215 -0.00139
O2 0.02609 0.02368 0.01849 -0.00785 0.00557 -0.00165
O22 0.02292 0.02153 0.01748 0.00734 0.00405 0.00177
O3 0.01976 0.00975 0.01178 0.00038 0.00190 -0.00013
O33 0.01976 0.01089 0.01355 0.00013 0.00456 0.00139
F4 0.01216 0.00557 0.01241 -0.00089 0.00190 0.00291
O4 0.01216 0.00557 0.01241 -0.00089 0.00190 0.00291
O-H4 0.01216 0.00557 0.01241 -0.00089 0.00190 0.00291