data_global
_chemical_name_mineral 'Polylithionite'
loop_
_publ_author_name
'Brigatti M F'
'Lugli C'
'Poppi L'
'Foord E E'
'Kile D E'
_journal_name_full 'American Mineralogist'
_journal_volume 85 
_journal_year 2000
_journal_page_first 1275
_journal_page_last 1286
_publ_section_title
;
 Crystal chemical variations in Li- and Fe-rich micas from
 Pikes Peak batholith (central Colorado)
 Sample: 54b
;
_database_code_amcsd 0002503
_chemical_formula_sum 'Si3.308 Al1.72 Li.591 Fe.731 Mg.008 Mn.063 Na.02 Rb.004 K.94 O10.346 F1.654 H.244'
_cell_length_a 5.283
_cell_length_b 9.123
_cell_length_c 10.072
_cell_angle_alpha 90
_cell_angle_beta 100.76
_cell_angle_gamma 90
_cell_volume 476.903
_exptl_crystal_density_diffrn      2.943
_symmetry_space_group_name_H-M 'C 1 2 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
SiT1   0.07530   0.16900   0.22801   0.82700
AlT1   0.07530   0.16900   0.22801   0.17300
SiT11   0.58510   0.33200   0.22782   0.82700
AlT11   0.58510   0.33200   0.22782   0.17300
LiM1   0.00000   0.99110   0.50000   0.39100
AlM1   0.00000   0.99110   0.50000   0.07400
FeM1   0.00000   0.99110   0.50000   0.36300
LiM2   0.00000   0.32240   0.50000   0.04200
AlM2   0.00000   0.32240   0.50000   0.95400
LiM3   0.50000   0.16020   0.50000   0.15800
MgM3   0.50000   0.16020   0.50000   0.00800
FeM3   0.50000   0.16020   0.50000   0.36800
MnM3   0.50000   0.16020   0.50000   0.06300
NaA   0.00000   0.50145   0.00000   0.02000
RbA   0.00000   0.50145   0.00000   0.00400
KA   0.00000   0.50145   0.00000   0.94000
O1   0.04070   0.00040   0.17110   1.00000
O2   0.32010   0.24020   0.17190   1.00000
O22   0.81240   0.25800   0.15850   1.00000
O3   0.11480   0.17510   0.39330   1.00000
O33   0.66400   0.32640   0.39250   1.00000
F4   0.10860   0.47150   0.39780   0.82700
O4   0.10860   0.47150   0.39780   0.05100
O-H4   0.10860   0.47150   0.39780   0.12200
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
SiT1 0.00608 0.00735 0.00291 -0.00012 0.00013 -0.00064
AlT1 0.00608 0.00735 0.00291 -0.00012 0.00013 -0.00064
SiT11 0.00633 0.00659 0.00405 -0.00026 -0.00013 -0.00050
AlT11 0.00633 0.00659 0.00405 -0.00026 -0.00013 -0.00050
LiM1 0.00798 0.00557 0.00621 0.00000 0.00291 0.00000
AlM1 0.00798 0.00557 0.00621 0.00000 0.00291 0.00000
FeM1 0.00798 0.00557 0.00621 0.00000 0.00291 0.00000
LiM2 0.00507 0.00646 0.00139 0.00000 -0.00049 0.00000
AlM2 0.00507 0.00646 0.00139 0.00000 -0.00049 0.00000
LiM3 0.00519 0.00810 0.00633 0.00000 -0.00114 0.00000
MgM3 0.00519 0.00810 0.00633 0.00000 -0.00114 0.00000
FeM3 0.00519 0.00810 0.00633 0.00000 -0.00114 0.00000
MnM3 0.00519 0.00810 0.00633 0.00000 -0.00114 0.00000
NaA 0.02520 0.02444 0.02115 0.00000 0.00265 0.00000
RbA 0.02520 0.02444 0.02115 0.00000 0.00265 0.00000
KA 0.02520 0.02444 0.02115 0.00000 0.00265 0.00000
O1 0.02824 0.01343 0.00925 0.00240 -0.00039 0.00014
O2 0.01697 0.02786 0.01013 -0.00621 0.00177 0.00014
O22 0.01621 0.02064 0.01013 0.00533 0.00216 0.00087
O3 0.01216 0.01520 0.00608 0.00178 -0.00062 -0.00380
O33 0.01039 0.01431 0.00696 0.00062 0.00088 -0.00380
F4 0.00975 0.00798 0.00431 -0.00062 0.00190 0.00201
O4 0.00975 0.00798 0.00431 -0.00062 0.00190 0.00201
O-H4 0.00975 0.00798 0.00431 -0.00062 0.00190 0.00201