data_global
_chemical_name_mineral 'Siderophyllite'
loop_
_publ_author_name
'Brigatti M F'
'Lugli C'
'Poppi L'
'Foord E E'
'Kile D E'
_journal_name_full 'American Mineralogist'
_journal_volume 85 
_journal_year 2000
_journal_page_first 1275
_journal_page_last 1286
_publ_section_title
;
 Crystal chemical variations in Li- and Fe-rich micas from
 Pikes Peak batholith (central Colorado)
 sample: 140(2)
;
_database_code_amcsd 0002506
_chemical_formula_sum 'Si3.236 Al1.743 Li.849 Fe.879 Mg.047 Mn.06 Na.014 K.954 O10.36 F1.64 H.248'
_cell_length_a 5.297
_cell_length_b 9.146
_cell_length_c 10.102
_cell_angle_alpha 90
_cell_angle_beta 100.81
_cell_angle_gamma 90
_cell_volume 480.720
_exptl_crystal_density_diffrn      2.985
_symmetry_space_group_name_H-M 'C 1 2 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
SiT1   0.07481   0.16864   0.22783   0.80900
AlT1   0.07481   0.16864   0.22783   0.19100
SiT11   0.58434   0.33204   0.22770   0.80900
AlT11   0.58434   0.33204   0.22770   0.19100
LiM1   0.00000   0.99230   0.50000   0.33200
FeM1   0.00000   0.99230   0.50000   0.48200
LiM2   0.00000   0.32300   0.50000   0.02100
AlM2   0.00000   0.32300   0.50000   0.97900
LiM3   0.50000   0.16112   0.50000   0.49600
MgM3   0.50000   0.16112   0.50000   0.04700
FeM3   0.50000   0.16112   0.50000   0.39700
MnM3   0.50000   0.16112   0.50000   0.06000
NaA   0.00000   0.50150   0.00000   0.01400
KA   0.00000   0.50150   0.00000   0.95400
O1   0.03630   0.99960   0.17160   1.00000
O2   0.32060   0.23860   0.17200   1.00000
O22   0.81530   0.26020   0.15920   1.00000
O3   0.11600   0.17450   0.39350   1.00000
O33   0.66200   0.32660   0.39250   1.00000
F4   0.11000   0.47290   0.39830   0.82000
O4   0.11000   0.47290   0.39830   0.05600
O-H4   0.11000   0.47290   0.39830   0.12400
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
SiT1 0.00646 0.00848 0.00722 0.00000 0.00115 -0.00023
AlT1 0.00646 0.00848 0.00722 0.00000 0.00115 -0.00023
SiT11 0.00773 0.00785 0.00811 0.00000 0.00139 -0.00014
AlT11 0.00773 0.00785 0.00811 0.00000 0.00139 -0.00014
LiM1 0.00924 0.00823 0.01039 0.00000 0.00343 0.00000
FeM1 0.00924 0.00823 0.01039 0.00000 0.00343 0.00000
LiM2 0.00697 0.00836 0.00633 0.00000 0.00102 0.00000
AlM2 0.00697 0.00836 0.00633 0.00000 0.00102 0.00000
LiM3 0.00722 0.00950 0.01026 0.00000 0.00063 0.00000
MgM3 0.00722 0.00950 0.01026 0.00000 0.00063 0.00000
FeM3 0.00722 0.00950 0.01026 0.00000 0.00063 0.00000
MnM3 0.00722 0.00950 0.01026 0.00000 0.00063 0.00000
NaA 0.02647 0.02622 0.02584 0.00000 0.00405 0.00000
KA 0.02647 0.02622 0.02584 0.00000 0.00405 0.00000
O1 0.02888 0.01482 0.01457 0.00178 0.00102 0.00000
O2 0.01862 0.02862 0.01216 -0.00697 0.00267 -0.00124
O22 0.01710 0.02546 0.01368 0.00771 0.00330 0.00202
O3 0.01267 0.01418 0.00950 0.00051 0.00102 -0.00179
O33 0.01216 0.01444 0.00988 0.00012 0.00228 0.00037
F4 0.00937 0.01051 0.00773 -0.00039 0.00152 0.00179
O4 0.00937 0.01051 0.00773 -0.00039 0.00152 0.00179
O-H4 0.00937 0.01051 0.00773 -0.00039 0.00152 0.00179