data_global
_chemical_name_mineral 'Siderophyllite'
loop_
_publ_author_name
'Brigatti M F'
'Lugli C'
'Poppi L'
'Foord E E'
'Kile D E'
_journal_name_full 'American Mineralogist'
_journal_volume 85 
_journal_year 2000
_journal_page_first 1275
_journal_page_last 1286
_publ_section_title
;
 Crystal chemical variations in Li- and Fe-rich micas from
 Pikes Peak batholith (central Colorado)
 Sample: 24
;
_database_code_amcsd 0002507
_chemical_formula_sum 'Si3.312 Al1.795 Li.764 Fe.828 Mn.078 Na.034 Rb.092 K.82 O10.41 F1.59 H.174'
_cell_length_a 5.295
_cell_length_b 9.139
_cell_length_c 10.077
_cell_angle_alpha 90
_cell_angle_beta 100.83
_cell_angle_gamma 90
_cell_volume 478.951
_exptl_crystal_density_diffrn      3.016
_symmetry_space_group_name_H-M 'C 1 2 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
SiT1   0.07480   0.16790   0.22739   0.82800
AlT1   0.07480   0.16790   0.22739   0.17200
SiT11   0.58470   0.33130   0.22725   0.82800
AlT11   0.58470   0.33130   0.22725   0.17200
LiM1   0.00000   0.99099   0.50000   0.20000
AlM1   0.00000   0.99099   0.50000   0.10700
FeM1   0.00000   0.99099   0.50000   0.47000
AlM2   0.00000   0.32130   0.50000   1.00000
LiM3   0.50000   0.16050   0.50000   0.56400
FeM3   0.50000   0.16050   0.50000   0.35800
MnM3   0.50000   0.16050   0.50000   0.07800
NaA   0.00000   0.50090   0.00000   0.03400
RbA   0.00000   0.50090   0.00000   0.09200
KA   0.00000   0.50090   0.00000   0.82000
O1   0.03450   0.99940   0.17140   1.00000
O2   0.32220   0.23700   0.17300   1.00000
O22   0.81610   0.26070   0.15880   1.00000
O3   0.11460   0.17380   0.39420   1.00000
O33   0.66360   0.32630   0.39320   1.00000
F4   0.10800   0.47120   0.39790   0.79500
O4   0.10800   0.47120   0.39790   0.11800
O-H4   0.10800   0.47120   0.39790   0.08700
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
SiT1 0.00811 0.00925 0.00114 0.00012 0.00050 -0.00037
AlT1 0.00811 0.00925 0.00114 0.00012 0.00050 -0.00037
SiT11 0.00823 0.00861 0.00127 0.00000 -0.00063 -0.00014
AlT11 0.00823 0.00861 0.00127 0.00000 -0.00063 -0.00014
LiM1 0.01178 0.00925 0.00380 0.00000 0.00279 0.00000
AlM1 0.01178 0.00925 0.00380 0.00000 0.00279 0.00000
FeM1 0.01178 0.00925 0.00380 0.00000 0.00279 0.00000
AlM2 0.00823 0.00950 0.00038 0.00000 0.00000 0.00000
LiM3 0.00887 0.01076 0.00355 0.00000 -0.00050 0.00000
FeM3 0.00887 0.01076 0.00355 0.00000 -0.00050 0.00000
MnM3 0.00887 0.01076 0.00355 0.00000 -0.00050 0.00000
NaA 0.02710 0.02786 0.01811 0.00000 0.00253 0.00000
RbA 0.02710 0.02786 0.01811 0.00000 0.00253 0.00000
KA 0.02710 0.02786 0.01811 0.00000 0.00253 0.00000
O1 0.03002 0.01659 0.00646 0.00101 -0.00039 -0.00037
O2 0.01748 0.03040 0.00646 -0.00672 0.00076 -0.00128
O22 0.01824 0.02660 0.00456 0.00797 0.00076 0.00115
O3 0.01355 0.01571 0.00367 0.00128 0.00089 -0.00137
O33 0.01267 0.01558 0.00443 0.00089 0.00013 0.00014
F4 0.01127 0.01001 0.00127 -0.00039 0.00076 0.00280
O4 0.01127 0.01001 0.00127 -0.00039 0.00076 0.00280
O-H4 0.01127 0.01001 0.00127 -0.00039 0.00076 0.00280