data_global
_chemical_name_mineral 'Siderophyllite'
loop_
_publ_author_name
'Brigatti M F'
'Lugli C'
'Poppi L'
'Foord E E'
'Kile D E'
_journal_name_full 'American Mineralogist'
_journal_volume 85 
_journal_year 2000
_journal_page_first 1275
_journal_page_last 1286
_publ_section_title
;
 Crystal chemical variations in Li- and Fe-rich micas from
 Pikes Peak batholith (central Colorado)
 Sample: 47
;
_database_code_amcsd 0002508
_chemical_formula_sum 'Si3.056 Al1.753 Li.416 Fe1.48 Mn.078 Ti.108 Mg.054 (Na.014 K.986) O10.92 F1.08 H.284'
_cell_length_a 5.339
_cell_length_b 9.233
_cell_length_c 10.135
_cell_angle_alpha 90
_cell_angle_beta 100.73
_cell_angle_gamma 90
_cell_volume 490.869
_exptl_crystal_density_diffrn      3.138
_symmetry_space_group_name_H-M 'C 1 2 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
SiT1   0.07480   0.16970   0.22575   0.76400
AlT1   0.07480   0.16970   0.22575   0.23600
SiT11   0.57910   0.33440   0.22520   0.76400
AlT11   0.57910   0.33440   0.22520   0.23600
LiM1   0.00000   0.99970   0.50000   0.13800
AlM1   0.00000   0.99970   0.50000   0.05900
FeM1   0.00000   0.99970   0.50000   0.67400
MnM1   0.00000   0.99970   0.50000   0.07800
LiM2   0.00000   0.33170   0.50000   0.07100
AlM2   0.00000   0.33170   0.50000   0.75000
FeM2   0.00000   0.33170   0.50000   0.07100
TiM2   0.00000   0.33170   0.50000   0.10800
LiM3   0.50000   0.16740   0.50000   0.20700
MgM3   0.50000   0.16740   0.50000   0.05400
FeM3   0.50000   0.16740   0.50000   0.73500
NaA   0.00000   0.50134   0.00000   0.01400
KA   0.00000   0.50134   0.00000   0.98600
O1   0.03890   0.00140   0.16990   1.00000
O2   0.31800   0.24170   0.16890   1.00000
O22   0.80990   0.25850   0.16410   1.00000
O3   0.12890   0.17490   0.39330   1.00000
O33   0.63920   0.33310   0.38850   1.00000
F4   0.11570   0.49530   0.39610   0.54000
O4   0.11570   0.49530   0.39610   0.31800
O-H4   0.11570   0.49530   0.39610   0.14200
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
SiT1 0.00735 0.00671 0.00405 0.00089 0.00177 0.00076
AlT1 0.00735 0.00671 0.00405 0.00089 0.00177 0.00076
SiT11 0.01190 0.01406 0.01317 0.00114 0.00203 0.00114
AlT11 0.01190 0.01406 0.01317 0.00114 0.00203 0.00114
LiM1 0.01013 0.00963 0.00912 0.00000 0.00329 0.00000
AlM1 0.01013 0.00963 0.00912 0.00000 0.00329 0.00000
FeM1 0.01013 0.00963 0.00912 0.00000 0.00329 0.00000
MnM1 0.01013 0.00963 0.00912 0.00000 0.00329 0.00000
LiM2 0.00836 0.01140 0.00633 0.00000 0.00089 0.00000
AlM2 0.00836 0.01140 0.00633 0.00000 0.00089 0.00000
FeM2 0.00836 0.01140 0.00633 0.00000 0.00089 0.00000
TiM2 0.00836 0.01140 0.00633 0.00000 0.00089 0.00000
LiM3 0.00798 0.01292 0.00899 0.00000 0.00063 0.00000
MgM3 0.00798 0.01292 0.00899 0.00000 0.00063 0.00000
FeM3 0.00798 0.01292 0.00899 0.00000 0.00063 0.00000
NaA 0.03065 0.03078 0.03344 0.00000 0.00443 0.00000
KA 0.03065 0.03078 0.03344 0.00000 0.00443 0.00000
O1 0.03154 0.01659 0.01545 0.00127 0.00152 -0.00190
O2 0.02153 0.02913 0.01988 -0.00507 0.00684 -0.00253
O22 0.01634 0.02913 0.01317 0.00899 0.00025 -0.00203
O3 0.02140 0.01241 0.00633 -0.00621 0.00063 -0.00241
O33 0.02660 0.02153 0.01380 -0.00684 0.00557 -0.00393
F4 0.01672 0.04382 0.00874 0.00507 0.00139 0.00127
O4 0.01672 0.04382 0.00874 0.00507 0.00139 0.00127
O-H4 0.01672 0.04382 0.00874 0.00507 0.00139 0.00127