Heulandite-Sr Dobelin N, Armbruster T American Mineralogist 88 (2003) 527-533 Stepwise dehydration of Sr-exchanged heulandite: A single-crystal X-ray study Note: fully hydrated at room temperature CELL PARAMETERS: 17.7140 18.0000 7.4300 90.000 116.627 90.000 SPACE GROUP: Cm X-RAY WAVELENGTH: 1.541838 MAX. ABS. INTENSITY / VOLUME**2: 2.526472087 2-THETA INTENSITY D-SPACING H K L 7.44 37.62 11.8893 1 1 0 9.83 33.38 9.0000 0 2 0 11.18 41.09 7.9177 2 0 0 12.90 29.31 6.8649 -1 1 1 13.00 22.96 6.8082 -2 0 1 13.33 27.37 6.6420 0 0 1 14.90 1.61 5.9447 2 2 0 15.79 9.84 5.6107 1 3 0 16.33 2.07 5.4296 -2 2 1 16.59 28.37 5.3442 0 2 1 16.84 64.51 5.2647 -3 1 1 17.35 53.49 5.1122 1 1 1 17.51 81.38 5.0651 3 1 0 19.02 89.04 4.6670 -1 3 1 19.73 11.63 4.5000 0 4 0 20.33 31.13 4.3691 -4 0 1 20.96 4.53 4.2385 2 0 1 21.91 3.60 4.0566 -3 3 1 22.31 91.55 3.9855 1 3 1 22.43 24.92 3.9631 3 3 0 22.46 30.96 3.9588 4 0 0 22.62 10.27 3.9305 -4 2 1 22.73 58.45 3.9123 2 4 0 23.20 31.78 3.8346 2 2 1 23.70 7.27 3.7541 -2 4 1 23.89 9.45 3.7255 0 4 1 23.97 20.16 3.7131 -2 0 2 24.57 6.00 3.6237 4 2 0 24.95 57.00 3.5688 -3 1 2 25.30 18.05 3.5202 -1 1 2 25.37 2.71 3.5104 1 5 0 25.64 13.59 3.4744 -5 1 1 25.96 49.78 3.4324 -2 2 2 26.18 36.23 3.4041 -4 0 2 26.32 4.78 3.3862 3 1 1 26.85 21.06 3.3210 0 0 2 28.02 63.38 3.1839 -4 2 2 28.47 84.99 3.1347 -4 4 1 28.68 2.71 3.1128 -3 3 2 28.94 3.57 3.0854 2 4 1 28.99 18.04 3.0803 -1 3 2 29.38 11.02 3.0397 -5 1 2 29.65 23.75 3.0130 -3 5 1 29.78 15.27 3.0000 0 6 0 29.89 17.14 2.9894 3 3 1 29.95 87.21 2.9836 1 5 1 30.05 100.00 2.9741 3 5 0 30.06 1.27 2.9723 4 4 0 30.28 29.26 2.9516 1 1 2 30.32 4.56 2.9476 -6 0 1 31.05 13.76 2.8800 4 0 1 31.23 1.73 2.8640 -2 4 2 31.95 18.83 2.8012 -6 2 1 31.95 73.87 2.8008 5 3 0 32.62 15.98 2.7453 -2 6 1 32.65 7.56 2.7430 4 2 1 32.65 13.07 2.7428 -5 3 2 32.76 12.80 2.7341 0 6 1 32.99 2.96 2.7148 -4 4 2 33.47 4.66 2.6776 1 3 2 33.54 13.62 2.6721 0 4 2 33.97 1.28 2.6392 6 0 0 34.06 5.86 2.6324 -6 2 2 35.05 2.86 2.5600 -3 5 2 35.11 13.86 2.5561 2 2 2 35.31 9.74 2.5419 -1 5 2 35.36 4.10 2.5382 1 7 0 35.44 5.11 2.5326 6 2 0 35.56 9.02 2.5245 -5 5 1 36.07 16.49 2.4900 3 5 1 36.10 15.74 2.4883 -7 1 1 36.33 18.18 2.4731 -4 6 1 36.44 9.89 2.4657 -6 4 1 36.56 10.88 2.4578 -4 0 3 36.70 8.76 2.4487 2 6 1 36.85 1.63 2.4393 5 1 1 37.05 5.07 2.4264 -7 1 2 37.06 14.83 2.4257 4 4 1 37.62 6.28 2.3910 4 6 0 37.84 1.96 2.3779 5 5 0 37.95 20.96 2.3709 -4 2 3 38.07 6.79 2.3639 -5 1 3 38.27 10.63 2.3519 3 1 2 38.31 18.84 2.3494 -2 2 3 38.33 6.46 2.3482 -6 4 2 38.44 5.28 2.3421 -5 5 2 38.58 1.33 2.3335 -2 6 2 38.65 3.91 2.3298 -3 7 1 38.86 2.34 2.3175 -7 3 1 38.88 3.98 2.3161 1 7 1 38.96 11.50 2.3117 3 7 0 39.28 11.42 2.2936 2 4 2 39.57 3.46 2.2777 5 3 1 39.59 9.46 2.2766 6 4 0 39.72 1.22 2.2694 -6 0 3 39.76 5.39 2.2672 -7 3 2 40.06 3.36 2.2507 -4 6 2 40.07 6.62 2.2500 0 8 0 40.18 6.21 2.2445 7 1 0 40.52 4.72 2.2262 0 6 2 40.75 1.26 2.2140 0 0 3 40.91 9.04 2.2061 3 3 2 41.02 6.18 2.2005 -6 2 3 41.35 1.92 2.1837 -8 0 1 41.88 5.03 2.1570 -4 4 3 42.13 1.34 2.1449 6 0 1 42.21 10.90 2.1407 -2 4 3 42.31 2.13 2.1364 -2 8 1 42.42 2.47 2.1310 0 8 1 42.59 2.68 2.1229 -8 2 2 42.60 1.44 2.1221 -8 2 1 42.66 4.88 2.1193 4 0 2 42.72 6.62 2.1167 7 3 0 42.75 7.39 2.1151 -7 1 3 43.06 4.58 2.1004 -3 7 2 43.28 1.60 2.0904 -1 7 2 43.37 21.29 2.0864 6 2 1 43.56 6.74 2.0776 4 6 1 43.93 1.27 2.0613 3 7 1 43.95 5.19 2.0603 -7 5 1 44.05 3.96 2.0556 1 1 3 44.41 2.89 2.0397 -3 5 3 44.59 2.16 2.0322 5 5 1 44.72 8.93 2.0263 -6 4 3 44.76 4.59 2.0247 -7 5 2 45.17 2.13 2.0071 -7 3 3 45.34 5.07 2.0003 -4 8 1 45.43 3.01 1.9963 5 7 0 45.52 2.69 1.9928 2 6 2 45.65 1.72 1.9873 2 8 1 45.73 2.48 1.9842 1 9 0 45.79 5.29 1.9816 6 6 0 45.95 7.34 1.9750 -5 7 2 46.19 9.46 1.9652 -8 4 2 46.21 2.96 1.9646 -8 4 1 46.26 26.02 1.9627 -1 5 3 46.42 2.54 1.9561 1 3 3 46.61 5.88 1.9486 -9 1 2 46.93 10.11 1.9362 6 4 1 46.95 5.39 1.9351 -8 2 3 47.00 1.14 1.9332 8 2 0 47.06 6.17 1.9312 -1 9 1 47.23 2.83 1.9243 -2 8 2 47.33 1.77 1.9206 2 0 3 47.42 1.08 1.9171 -9 1 1 48.46 1.14 1.8783 2 2 3 48.50 2.13 1.8770 -4 8 2 48.88 2.93 1.8632 -9 3 2 48.90 2.33 1.8627 0 8 2 49.07 3.79 1.8565 -4 0 4 49.74 8.11 1.8331 -7 5 3 49.90 6.70 1.8276 -3 1 4 50.11 3.50 1.8206 -6 0 4 50.25 6.11 1.8156 5 3 2 50.72 12.43 1.8000 0 10 0 50.88 1.60 1.7947 -2 0 4 50.90 1.43 1.7940 1 5 3 51.07 1.15 1.7885 -6 8 1 51.23 1.91 1.7833 -3 7 3 51.29 3.84 1.7814 0 6 3 51.38 3.51 1.7783 5 7 1 51.54 17.33 1.7733 -7 7 2 51.54 3.76 1.7731 4 8 1 51.62 5.78 1.7705 -10 0 2 51.68 1.47 1.7686 3 1 3 51.69 2.15 1.7686 -5 3 4 51.77 2.22 1.7660 -8 6 2 51.93 1.45 1.7608 -7 1 4 51.95 3.49 1.7601 -2 2 4 52.06 5.55 1.7566 -3 3 4 52.18 5.81 1.7530 -3 9 2 52.24 1.58 1.7511 9 1 0 52.32 2.34 1.7485 -5 7 3 52.37 1.08 1.7471 -1 9 2 52.69 7.14 1.7373 0 10 1 52.69 3.61 1.7372 -10 2 2 52.93 7.82 1.7300 3 9 1 53.28 4.42 1.7194 2 8 2 53.80 2.64 1.7041 3 3 3 53.86 1.45 1.7020 -8 0 4 53.94 1.19 1.6999 8 0 1 53.95 4.68 1.6997 -9 5 1 53.99 3.67 1.6985 7 7 0 54.03 5.51 1.6973 -10 0 3 54.24 2.30 1.6910 5 9 0 54.36 1.34 1.6877 -6 4 4 54.90 9.43 1.6724 -8 2 4 55.09 1.34 1.6670 -2 4 4 55.13 4.37 1.6658 -1 3 4 55.19 2.57 1.6643 -4 10 1 55.46 2.39 1.6568 2 10 1 55.63 4.20 1.6522 8 6 0 55.63 5.97 1.6521 -2 8 3 55.86 3.02 1.6460 -5 5 4 56.07 3.30 1.6403 -7 7 3 56.13 2.89 1.6386 4 10 0 56.34 1.22 1.6329 0 2 4 56.93 11.71 1.6175 2 6 3 57.14 1.35 1.6121 1 7 3 57.20 2.10 1.6104 -10 4 1 57.70 3.97 1.5978 -6 8 3 57.86 8.89 1.5936 3 5 3 58.00 1.89 1.5902 8 4 1 58.27 1.89 1.5835 10 0 0 58.67 1.14 1.5736 1 1 4 58.88 1.39 1.5685 -3 11 1 58.94 3.81 1.5670 -8 8 1 59.03 2.28 1.5648 -7 9 1 59.04 3.21 1.5646 7 1 2 59.11 1.91 1.5630 3 11 0 59.25 2.81 1.5596 10 2 0 59.44 1.25 1.5551 -11 3 2 59.55 4.87 1.5525 6 8 1 59.96 1.13 1.5427 4 8 2 59.97 2.54 1.5426 -9 7 1 60.38 1.03 1.5331 9 1 1 60.41 2.13 1.5324 -5 9 3 60.48 1.17 1.5306 5 7 2 60.55 3.85 1.5291 3 9 2 60.67 3.53 1.5264 4 10 1 60.97 1.26 1.5195 -11 3 3 61.09 2.52 1.5168 5 1 3 61.85 4.71 1.5000 0 12 0 61.93 2.85 1.4984 7 9 0 62.14 1.19 1.4938 -9 7 3 62.20 1.07 1.4926 -3 11 2 62.30 5.26 1.4904 9 3 1 62.45 1.61 1.4870 -8 8 3 62.49 5.93 1.4862 8 8 0 62.63 1.28 1.4832 -6 0 5 62.83 1.32 1.4790 8 6 1 63.00 2.08 1.4755 5 3 3 63.59 1.44 1.4632 0 12 1 63.84 1.64 1.4580 -7 9 3 63.92 1.21 1.4564 -12 0 3 63.99 1.40 1.4550 -4 2 5 64.02 4.01 1.4544 -12 2 2 64.10 2.41 1.4528 0 6 4 64.13 1.08 1.4522 -4 10 3 64.13 2.42 1.4521 9 7 0 64.46 3.84 1.4455 -5 11 2 64.64 2.16 1.4418 -8 0 5 64.75 3.63 1.4397 -11 5 3 64.84 7.22 1.4380 1 9 3 64.85 1.05 1.4377 -12 2 3 64.85 1.36 1.4377 -1 7 4 64.96 3.48 1.4357 1 11 2 65.22 3.34 1.4306 -11 5 1 65.44 1.22 1.4263 -7 3 5 65.66 2.91 1.4219 8 2 2 65.67 4.27 1.4218 -12 0 1 65.78 1.35 1.4196 2 4 4 65.83 1.30 1.4187 -4 12 1 65.87 3.78 1.4179 -2 0 5 65.92 8.06 1.4170 -11 3 4 66.25 1.01 1.4107 -3 3 5 66.76 2.31 1.4013 -9 1 5 66.77 2.56 1.4011 -4 4 5 66.83 1.23 1.3999 -9 9 2 67.05 1.93 1.3957 6 2 3 67.29 1.95 1.3914 -10 8 2 67.43 4.10 1.3889 -8 10 1 67.48 3.08 1.3880 10 2 1 68.32 4.49 1.3730 -5 5 5 68.38 2.62 1.3719 4 10 2 68.42 2.49 1.3712 -7 11 1 68.56 1.84 1.3687 -10 8 1 68.77 1.93 1.3651 -3 11 3 68.90 1.02 1.3628 5 11 1 68.97 1.65 1.3616 -10 0 5 69.03 3.16 1.3605 -7 11 2 69.09 5.78 1.3596 -7 5 5 69.15 1.48 1.3584 -5 9 4 69.21 2.27 1.3574 -8 8 4 69.46 1.56 1.3532 -13 1 2 69.83 1.53 1.3470 3 11 2 69.88 2.43 1.3461 -3 5 5 69.89 1.29 1.3460 1 7 4 70.17 2.08 1.3412 -1 11 3 70.22 1.91 1.3404 -11 7 3 70.22 2.03 1.3404 7 7 2 70.66 1.86 1.3331 -11 7 1 70.67 2.11 1.3329 4 0 4 70.88 1.92 1.3296 -6 6 5 71.30 2.38 1.3228 -12 6 2 71.43 1.28 1.3206 -13 3 3 72.09 1.27 1.3102 -12 6 3 72.10 2.17 1.3099 5 7 3 72.27 5.69 1.3073 2 12 2 72.48 1.20 1.3041 6 12 0 73.43 1.62 1.2895 -5 13 1 73.70 1.88 1.2854 -1 5 5 73.77 1.11 1.2844 7 3 3 73.92 1.05 1.2822 -11 3 5 73.94 2.19 1.2819 -2 6 5 74.04 6.72 1.2804 -4 12 3 74.30 1.64 1.2766 -13 3 1 74.47 1.00 1.2740 0 4 5 74.49 2.52 1.2737 1 1 5 74.69 5.57 1.2709 -2 10 4 74.81 1.87 1.2691 2 14 0 74.84 3.11 1.2687 5 13 0 75.22 1.21 1.2632 11 3 1 75.29 1.88 1.2622 -10 10 2 75.69 1.08 1.2566 1 13 2 75.72 4.03 1.2562 -9 11 2 75.87 2.09 1.2540 5 1 4 76.45 1.04 1.2459 9 5 2 76.75 1.61 1.2418 0 12 3 76.89 1.32 1.2399 -10 6 5 77.05 1.14 1.2377 -6 0 6 77.15 1.74 1.2364 -8 12 1 77.23 1.92 1.2352 7 9 2 77.37 1.96 1.2334 -4 14 1 77.41 3.68 1.2329 -12 8 2 77.68 3.62 1.2292 6 12 1 77.76 2.06 1.2281 -13 5 1 77.77 1.17 1.2280 -5 1 6 78.10 1.26 1.2236 2 0 5 78.34 1.45 1.2205 0 10 4 78.41 1.01 1.2196 10 2 2 78.68 1.79 1.2162 11 5 1 79.05 1.01 1.2113 5 9 3 79.08 1.92 1.2110 -9 1 6 79.28 1.01 1.2084 -3 13 3 79.72 1.42 1.2028 -4 14 2 80.16 1.09 1.1974 -5 13 3 80.23 1.66 1.1965 6 8 3 80.62 1.08 1.1916 10 8 1 81.13 1.00 1.1855 12 2 1 81.33 1.63 1.1831 -13 3 5 81.47 1.27 1.1814 -14 4 4 81.50 1.06 1.1810 7 13 0 81.73 3.34 1.1783 -11 9 4 82.14 1.41 1.1734 -3 3 6 82.34 1.73 1.1710 -10 10 4 82.37 1.43 1.1707 1 15 1 82.88 1.13 1.1648 -13 7 1 83.13 1.49 1.1619 -12 6 5 84.47 1.26 1.1470 6 4 4 84.73 1.91 1.1440 -14 2 5 85.43 1.03 1.1365 -5 15 1 86.16 2.81 1.1287 9 3 3 86.99 1.35 1.1200 5 13 2 87.60 1.56 1.1138 -2 10 5 88.18 1.18 1.1080 -10 6 6 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.