Wakabayashilite Bonazzi P, Lampronti G I, Bindi L, Zandari S American Mineralogist 90 (2005) 1108-1114 Wakabayashilite, [(As,Sb)6S9][As4S5]: crystal structure, psuedosymmetry, twinning, and revised chemical formula Sample: White Caps Mine, Nevada CELL PARAMETERS: 25.2620 14.5630 6.4920 90.000 90.000 90.000 SPACE GROUP: Pna2_1 X-RAY WAVELENGTH: 1.541838 MAX. ABS. INTENSITY / VOLUME**2: 9.332522331 2-THETA INTENSITY D-SPACING H K L 7.00 12.00 12.6310 2 0 0 7.01 5.80 12.6167 1 1 0 9.27 1.14 9.5420 2 1 0 12.65 7.14 6.9967 1 2 0 14.02 54.36 6.3155 4 0 0 14.04 100.00 6.3083 2 2 0 15.29 5.75 5.7941 4 1 0 15.35 21.36 5.7740 2 0 1 15.35 47.90 5.7726 1 1 1 16.09 16.40 5.5079 3 2 0 18.59 22.14 4.7733 5 1 0 18.60 18.80 4.7710 4 2 0 18.61 26.31 4.7671 1 3 0 19.59 23.56 4.5312 2 3 0 19.61 5.87 4.5268 4 0 1 19.62 11.29 4.5242 2 2 1 20.55 4.48 4.3228 4 1 1 21.10 1.22 4.2103 6 0 0 21.13 3.68 4.2056 3 3 0 21.15 2.80 4.2000 3 2 1 21.41 2.12 4.1510 5 2 0 21.98 25.73 4.0447 6 1 0 22.87 11.06 3.8877 0 3 1 23.11 26.64 3.8488 4 3 0 23.13 17.62 3.8457 5 1 1 23.14 16.55 3.8445 4 2 1 23.15 16.37 3.8424 1 3 1 23.95 8.19 3.7157 2 3 1 24.42 1.60 3.6449 6 2 0 24.71 9.88 3.6035 1 4 0 25.21 13.95 3.5325 6 0 1 25.23 21.72 3.5297 3 3 1 25.43 25.71 3.5029 7 1 0 25.45 18.46 3.5005 5 3 0 25.46 20.93 3.4983 2 4 0 25.47 22.76 3.4972 5 2 1 25.95 18.45 3.4329 6 1 1 26.68 22.08 3.3418 3 4 0 26.93 8.66 3.3107 4 3 1 27.48 91.16 3.2460 0 0 2 27.59 2.11 3.2335 7 2 0 28.05 26.35 3.1807 6 3 0 28.26 2.19 3.1577 8 0 0 28.29 1.43 3.1542 4 4 0 28.33 7.91 3.1507 1 4 1 28.39 10.98 3.1438 2 0 2 28.39 11.11 3.1436 1 1 2 28.93 33.05 3.0860 8 1 0 28.96 23.17 3.0828 7 1 1 28.98 26.10 3.0811 5 3 1 28.99 24.59 3.0797 2 4 1 29.06 1.23 3.0731 2 1 2 30.08 4.88 2.9712 3 4 1 30.14 8.07 2.9653 3 1 2 30.14 7.29 2.9648 0 2 2 30.26 4.20 2.9538 5 4 0 30.36 7.96 2.9445 1 2 2 30.87 2.62 2.8971 8 2 0 30.90 1.15 2.8934 1 5 0 30.98 17.89 2.8870 4 0 2 30.98 22.74 2.8863 2 2 2 31.51 9.73 2.8396 8 0 1 31.52 20.29 2.8381 2 5 0 31.53 24.89 2.8370 4 4 1 31.59 4.49 2.8319 4 1 2 32.00 9.09 2.7965 3 2 2 32.11 3.67 2.7872 8 1 1 32.49 4.69 2.7562 9 1 0 32.51 8.00 2.7539 6 4 0 32.53 7.16 2.7526 3 5 0 33.33 1.71 2.6886 5 4 1 33.38 2.11 2.6842 5 1 2 33.39 4.51 2.6837 4 2 2 33.40 6.70 2.6831 1 3 2 33.73 6.16 2.6574 0 5 1 33.88 8.26 2.6456 8 2 1 33.89 9.22 2.6449 7 3 1 33.92 10.29 2.6428 1 5 1 33.97 4.37 2.6388 2 3 2 34.24 3.69 2.6190 9 2 0 34.90 20.36 2.5707 6 0 2 34.92 28.93 2.5696 3 3 2 35.01 4.82 2.5630 7 4 0 35.09 1.34 2.5570 5 2 2 35.38 19.25 2.5370 9 1 1 35.41 17.54 2.5353 6 4 1 35.42 16.62 2.5342 3 5 1 35.46 6.23 2.5316 6 1 2 35.58 1.22 2.5233 5 5 0 36.20 4.78 2.4813 4 3 2 36.66 22.17 2.4511 8 3 1 36.99 13.11 2.4299 9 3 0 37.01 7.17 2.4288 9 2 1 37.04 5.72 2.4272 0 6 0 37.09 14.85 2.4241 6 2 2 37.11 14.30 2.4229 0 4 2 37.28 10.64 2.4118 1 4 2 37.55 1.46 2.3953 6 5 0 37.78 4.09 2.3809 7 1 2 37.80 3.00 2.3801 5 3 2 37.81 3.16 2.3795 2 4 2 38.67 8.78 2.3284 3 4 2 39.33 4.20 2.2908 7 2 2 39.67 28.43 2.2718 6 3 2 39.81 15.30 2.2643 1 6 1 39.83 1.00 2.2634 8 0 2 40.26 9.29 2.2401 10 2 1 40.28 11.09 2.2391 8 4 1 40.31 10.07 2.2375 2 6 1 40.33 24.39 2.2366 8 1 2 41.33 2.59 2.1846 5 4 2 41.80 1.29 2.1610 7 3 2 42.20 7.15 2.1415 11 1 1 42.23 8.63 2.1399 7 5 1 42.25 9.30 2.1391 4 6 1 42.30 16.65 2.1366 2 5 2 42.38 2.57 2.1329 2 0 3 42.38 4.85 2.1329 1 1 3 42.68 2.81 2.1183 10 3 1 42.85 1.75 2.1104 2 1 3 43.01 4.03 2.1031 9 4 1 43.05 2.78 2.1010 9 1 2 43.07 1.82 2.1000 6 4 2 43.09 3.48 2.0994 3 5 2 43.60 2.52 2.0760 11 3 0 43.61 1.34 2.0755 10 4 0 43.65 1.98 2.0734 1 7 0 44.45 1.34 2.0383 9 2 2 44.82 3.65 2.0223 12 2 0 44.85 3.37 2.0211 9 5 0 44.88 2.33 2.0197 3 7 0 45.07 3.84 2.0116 7 4 2 45.33 2.09 2.0005 6 6 1 45.53 1.18 1.9922 5 5 2 45.80 1.96 1.9812 0 7 1 45.89 1.23 1.9773 11 3 1 45.91 3.07 1.9765 0 3 3 45.93 1.15 1.9760 4 7 0 46.05 1.38 1.9709 5 1 3 46.06 1.82 1.9708 4 2 3 46.70 6.17 1.9453 9 3 2 46.73 1.91 1.9438 0 6 2 47.05 1.06 1.9314 12 3 0 47.06 2.59 1.9308 12 2 1 47.12 1.20 1.9285 3 7 1 47.15 1.72 1.9274 6 5 2 47.22 1.15 1.9247 6 0 3 47.24 3.75 1.9242 3 3 3 47.29 2.14 1.9222 8 4 2 47.31 1.03 1.9212 2 6 2 47.38 8.29 1.9189 5 2 3 47.66 1.87 1.9081 6 1 3 48.25 1.17 1.8863 4 3 3 48.95 8.07 1.8609 11 4 1 49.02 1.54 1.8583 7 5 2 49.11 1.13 1.8552 1 4 3 49.22 3.92 1.8512 12 3 1 49.35 13.96 1.8466 13 1 1 49.40 10.06 1.8450 8 6 1 49.41 10.39 1.8444 5 7 1 49.51 4.37 1.8410 7 1 3 49.52 3.05 1.8407 5 3 3 49.53 3.10 1.8404 2 4 3 49.71 1.13 1.8341 9 4 2 49.80 2.78 1.8309 10 5 1 50.05 5.13 1.8224 12 4 0 50.11 2.26 1.8204 0 8 0 50.23 1.64 1.8164 3 4 3 50.25 1.97 1.8156 11 2 2 50.77 2.05 1.7984 7 2 3 51.17 1.55 1.7851 8 0 3 51.19 2.78 1.7844 4 4 3 51.58 1.40 1.7718 8 1 3 51.74 3.37 1.7667 9 6 1 51.76 2.23 1.7662 12 0 2 51.80 8.42 1.7648 6 6 2 52.17 2.24 1.7534 12 1 2 52.31 3.08 1.7489 11 3 2 52.32 1.13 1.7486 10 4 2 52.32 4.36 1.7486 1 8 1 52.36 2.54 1.7474 1 7 2 52.41 1.02 1.7456 5 4 3 52.65 4.42 1.7385 14 0 1 52.66 1.02 1.7382 13 3 1 52.68 2.09 1.7376 11 5 1 52.69 1.17 1.7370 0 5 3 52.71 9.25 1.7367 7 7 1 52.72 1.32 1.7361 2 8 1 52.76 2.08 1.7350 2 7 2 52.80 1.33 1.7337 8 2 3 52.81 1.46 1.7335 7 3 3 53.05 3.72 1.7263 14 1 1 53.38 10.22 1.7165 12 2 2 53.39 3.81 1.7160 3 8 1 53.40 7.25 1.7157 9 5 2 53.43 7.94 1.7148 3 7 2 53.86 8.62 1.7021 9 1 3 53.88 6.94 1.7015 6 4 3 53.89 7.68 1.7012 3 5 3 54.35 3.87 1.6878 4 7 2 54.79 3.70 1.6754 8 3 3 54.88 3.22 1.6730 15 1 0 54.93 2.62 1.6714 9 7 0 54.95 3.04 1.6709 6 8 0 55.05 2.31 1.6682 9 2 3 55.43 2.53 1.6575 13 4 1 55.47 1.63 1.6565 13 1 2 55.49 4.23 1.6560 5 8 1 55.51 1.78 1.6553 8 6 2 56.20 1.69 1.6367 14 3 1 56.63 1.24 1.6252 13 2 2 56.72 11.65 1.6230 0 0 4 56.83 1.16 1.6201 15 1 1 56.89 1.57 1.6186 9 7 1 56.90 1.59 1.6182 6 8 1 56.96 1.03 1.6168 14 4 0 56.97 1.19 1.6165 13 5 0 57.00 1.03 1.6157 11 6 1 57.03 1.06 1.6148 1 9 0 57.14 3.29 1.6119 1 6 3 57.23 1.05 1.6098 2 0 4 57.23 3.05 1.6097 1 1 4 57.49 1.53 1.6031 10 2 3 57.50 1.25 1.6028 8 4 3 57.52 2.26 1.6022 2 6 3 57.69 1.76 1.5980 9 6 2 57.96 7.19 1.5911 15 3 0 57.99 8.27 1.5903 12 6 0 58.04 5.63 1.5891 12 4 2 58.04 7.30 1.5890 3 9 0 58.10 2.51 1.5877 0 8 2 58.24 1.11 1.5842 3 1 4 58.53 3.18 1.5771 14 0 2 58.58 4.60 1.5758 7 7 2 58.74 2.04 1.5719 4 0 4 58.74 4.61 1.5718 2 2 4 58.99 1.20 1.5658 11 1 3 59.02 1.38 1.5652 7 5 3 59.03 1.18 1.5649 4 6 3 59.28 1.14 1.5589 10 7 1 59.37 1.78 1.5567 10 3 3 60.33 1.78 1.5342 16 0 1 60.40 1.96 1.5325 8 8 1 60.60 1.34 1.5279 2 3 4 61.21 1.30 1.5142 3 3 4 61.57 3.26 1.5063 6 1 4 61.94 1.28 1.4981 11 3 3 61.95 1.31 1.4979 10 4 3 61.99 1.13 1.4971 1 7 3 62.06 1.98 1.4955 4 3 4 62.18 1.41 1.4928 14 5 1 62.42 1.71 1.4878 15 4 1 62.79 1.71 1.4798 1 4 4 63.75 1.10 1.4599 3 4 4 64.45 2.37 1.4457 6 3 4 64.46 2.22 1.4455 11 4 3 64.66 1.52 1.4414 17 1 1 64.69 2.10 1.4409 12 3 3 64.73 1.25 1.4401 10 8 1 64.73 1.01 1.4401 8 9 0 64.80 2.09 1.4388 13 1 3 64.84 2.51 1.4380 8 6 3 64.85 2.04 1.4378 5 7 3 64.92 1.99 1.4365 8 1 4 65.18 1.06 1.4313 10 5 3 65.83 3.91 1.4187 1 10 1 66.35 1.76 1.4089 2 5 4 66.82 1.09 1.4000 9 6 3 67.32 1.97 1.3909 1 8 3 67.52 1.04 1.3873 13 7 1 67.60 2.06 1.3859 14 0 3 67.65 3.33 1.3849 7 7 3 67.94 1.26 1.3796 14 1 3 68.24 1.32 1.3743 13 6 2 68.90 1.10 1.3627 16 3 2 69.21 3.32 1.3574 16 5 1 69.45 1.35 1.3533 15 6 1 71.25 1.37 1.3236 15 1 3 71.30 1.53 1.3228 9 7 3 71.31 1.50 1.3225 6 8 3 79.41 1.57 1.2068 1 10 3 79.46 1.65 1.2061 7 7 4 82.17 1.17 1.1731 16 8 1 82.57 1.09 1.1684 16 5 3 85.30 1.03 1.1379 18 6 2 85.46 2.07 1.1362 15 3 4 85.48 1.84 1.1359 12 6 4 85.53 1.96 1.1354 3 9 4 89.12 1.02 1.0987 21 3 2 89.25 1.11 1.0974 6 12 2 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.