Birnessite Lopano C L, Heaney P J, Post J E American Mineralogist 94 (2009) 816-826 Cs-exchange in birnessite: Reaction mechanisms inferred from time-resolved X-ray diffraction and transmission electron microscopy Note: Solution concentration 0.001 M Note: Occupancies of the Oint sites are undetermined, O is used only as a scatterer _database_code_amcsd 0004947 CELL PARAMETERS: 5.1342 2.8469 7.4815 90.310 101.559 89.944 SPACE GROUP: C-1 X-RAY WAVELENGTH: 1.541838 Cell Volume: 107.134 Density (g/cm3): 3.713 MAX. ABS. INTENSITY / VOLUME**2: 40.11310027 RIR: 3.518 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 12.07 100.00 7.3297 0 0 1 2 24.29 75.52 3.6648 0 0 2 2 35.33 5.84 2.5403 -2 0 1 2 35.70 7.67 2.5150 2 0 0 2 36.26 4.83 2.4777 -1 1 0 2 36.26 4.31 2.4775 1 1 0 2 37.08 6.37 2.4242 -1 -1 1 2 37.20 7.02 2.4172 -1 1 1 2 40.17 16.36 2.2448 2 0 1 2 41.85 12.74 2.1586 -1 -1 2 2 42.05 13.92 2.1485 -1 1 2 2 46.11 2.46 1.9685 1 -1 2 2 46.31 2.91 1.9606 1 1 2 2 46.33 2.73 1.9597 -2 0 3 2 47.79 7.04 1.9034 2 0 2 2 49.62 6.34 1.8371 -1 -1 3 2 49.76 3.26 1.8324 0 0 4 2 49.89 5.54 1.8278 -1 1 3 2 55.23 1.75 1.6632 1 -1 3 2 55.48 1.81 1.6561 1 1 3 2 55.84 1.53 1.6463 -2 0 4 2 57.63 2.87 1.5996 2 0 3 2 59.57 2.57 1.5519 -1 -1 4 2 59.89 2.74 1.5444 -1 1 4 2 63.40 3.26 1.4670 -3 -1 1 2 63.47 1.39 1.4656 -3 1 1 2 64.50 2.81 1.4448 -3 1 0 2 64.50 1.05 1.4447 3 1 0 2 65.12 1.14 1.4324 -3 -1 2 2 65.27 2.58 1.4296 -3 1 2 2 65.58 2.27 1.4234 0 2 0 2 66.23 2.11 1.4112 1 -1 4 2 66.53 2.22 1.4054 1 1 4 2 66.89 1.39 1.3987 0 -2 1 2 67.04 1.16 1.3959 0 2 1 2 67.16 2.05 1.3938 -2 0 5 2 68.35 1.02 1.3725 3 1 1 2 69.55 1.16 1.3517 -3 -1 3 2 78.26 1.16 1.2216 0 0 6 2 79.85 1.31 1.2012 2 2 1 2 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.