data_global
_chemical_name_mineral 'Aravaipaite'
loop_
_publ_author_name
'Kampf A R'
'Yang H'
'Downs R T'
'Pinch W W'
_journal_name_full 'American Mineralogist'
_journal_volume 96 
_journal_year 2011
_journal_page_first 402
_journal_page_last 407
_publ_section_title
;
 The crystal structures and Raman spectra of aravaipaite and calcioaravaipaite
;
_database_code_amcsd 0018320
_chemical_compound_source 'Grand Reef mine, Aravaipa mining district, Arizona, USA'
_chemical_formula_sum 'Pb3 Al F9 O H2'
_cell_length_a 5.6637
_cell_length_b 5.8659
_cell_length_c 12.7041
_cell_angle_alpha 98.725
_cell_angle_beta 94.020
_cell_angle_gamma 90.683
_cell_volume 416.045
_exptl_crystal_density_diffrn      6.686
_symmetry_space_group_name_H-M 'P -1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Pb1   0.30470   0.11693   0.36471   0.01512
Pb2   0.76753   0.04754   0.11751   0.02400
Pb3   0.27468   0.51132   0.11789   0.01756
Al   0.79400   0.61810   0.30820   0.01240
F1   0.04860   0.77450   0.27400   0.02650
F2   0.73690   0.50940   0.16610   0.02490
F3   0.84880   0.71990   0.44550   0.02900
F4   0.51920   0.47520   0.33060   0.02570
F5   0.61580   0.86760   0.28630   0.02650
F6   0.95870   0.36350   0.31700   0.03940
F7   0.49960   0.24300   0.99240   0.01880
F8   0.00070   0.24750   0.99530   0.01760
F9   0.29420   0.12830   0.17100   0.04070
OW   0.66210   0.22570   0.51280   0.02000
H1   0.59700   0.33800   0.55500   0.05000
H2   0.81400   0.25300   0.50900   0.05000
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Pb1 0.01590 0.01373 0.01576 0.00132 0.00129 0.00219
Pb2 0.03650 0.01645 0.01900 -0.00141 0.00197 0.00279
Pb3 0.01676 0.01772 0.01790 0.00000 0.00200 0.00137
Al 0.00980 0.01290 0.01450 0.00120 0.00010 0.00220
F1 0.02500 0.02600 0.02700 -0.00700 0.01300 -0.00600
F2 0.02700 0.03300 0.01400 -0.00200 -0.00100 0.00000
F3 0.02400 0.04700 0.01500 0.00000 0.00200 0.00100
F4 0.02200 0.02500 0.03100 -0.00900 0.00100 0.00700
F5 0.03000 0.01900 0.03400 0.01300 0.01300 0.00900
F6 0.03500 0.03200 0.05200 0.01600 -0.00500 0.01100
F7 0.02000 0.01700 0.01900 0.00150 0.00000 0.00300
F8 0.01900 0.02000 0.01300 0.00150 -0.00280 0.00190
F9 0.08300 0.02500 0.01400 0.00000 0.00000 0.00400
OW 0.01300 0.02000 0.02700 0.00000 0.00500 0.00000