data_global
_chemical_name_mineral 'Adamite'
loop_
_publ_author_name
'Hawthorne F C'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 14 
_journal_year 1976
_journal_page_first 143
_journal_page_last 148
_publ_section_title
;
 A refinement of the crystal structure of adamite
;
_database_code_amcsd 0005122
_chemical_formula_sum 'Zn2 As O5 H'
_cell_length_a 8.304
_cell_length_b 8.530
_cell_length_c 6.047
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 428.328
_exptl_crystal_density_diffrn      4.446
_symmetry_space_group_name_H-M 'P n n m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2-y,1/2+z'
  '1/2-x,1/2+y,1/2-z'
  '1/2-x,1/2+y,1/2+z'
  '1/2+x,1/2-y,1/2-z'
  'x,y,-z'
  '-x,-y,z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Zn1   0.36530   0.36420   0.50000
Zn2   0.50000   0.00000   0.25260
As   0.24980   0.24380   0.00000
O1   0.10440   0.10410   0.00000
O2   0.42370   0.14780   0.00000
O3   0.23120   0.36030   0.22330
O-H   0.39330   0.12740   0.50000
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Zn1 0.00370 0.00440 0.00740 0.00010 0.00000 0.00000
Zn2 0.00620 0.00570 0.00650 0.00160 0.00000 0.00000
As 0.00320 0.00380 0.00600 0.00020 0.00000 0.00000
O1 0.00270 0.00370 0.01870 -0.00010 0.00000 0.00000
O2 0.00530 0.00530 0.00910 0.00040 0.00000 0.00000
O3 0.00510 0.00460 0.00750 -0.00010 0.00000 0.00000
O-H 0.00310 0.00600 0.01100 0.00090 -0.00050 -0.00280