data_global _chemical_name_mineral 'Galkhaite' loop_ _publ_author_name 'Chen T T' 'Szymanski J T' _journal_name_full 'The Canadian Mineralogist' _journal_volume 19 _journal_year 1981 _journal_page_first 571 _journal_page_last 581 _publ_section_title ; The structure and chemistry of galkhaite, a mercury sulfosalt containing Cs and Tl ; _database_code_amcsd 0005182 _chemical_compound_source 'Getchell mine, Humboldt County, Nevada, USA' _chemical_formula_sum 'Hg4.224 Cu.864 Zn.528 Tl.304 Fe.03 Cs.595 (As3.932 Sb.068) S12' _cell_length_a 10.365 _cell_length_b 10.365 _cell_length_c 10.365 _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_volume 1113.545 _exptl_crystal_density_diffrn 5.271 _symmetry_space_group_name_H-M 'I -4 3 m' loop_ _space_group_symop_operation_xyz 'x,y,z' '1/2+x,1/2+y,1/2+z' '-z,x,-y' '1/2-z,1/2+x,1/2-y' '-y,z,-x' '1/2-y,1/2+z,1/2-x' '-x,y,-z' '1/2-x,1/2+y,1/2-z' 'x,-z,-y' '1/2+x,1/2-z,1/2-y' 'z,-y,-x' '1/2+z,1/2-y,1/2-x' 'y,-x,-z' '1/2+y,1/2-x,1/2-z' 'x,z,y' '1/2+x,1/2+z,1/2+y' 'z,y,x' '1/2+z,1/2+y,1/2+x' 'y,x,z' '1/2+y,1/2+x,1/2+z' '-z,-x,y' '1/2-z,1/2-x,1/2+y' '-y,-z,x' '1/2-y,1/2-z,1/2+x' '-x,-y,z' '1/2-x,1/2-y,1/2+z' 'z,-x,-y' '1/2+z,1/2-x,1/2-y' 'y,-z,-x' '1/2+y,1/2-z,1/2-x' 'x,-y,-z' '1/2+x,1/2-y,1/2-z' '-x,z,-y' '1/2-x,1/2+z,1/2-y' '-z,y,-x' '1/2-z,1/2+y,1/2-x' '-y,x,-z' '1/2-y,1/2+x,1/2-z' '-x,-z,y' '1/2-x,1/2-z,1/2+y' '-z,-y,x' '1/2-z,1/2-y,1/2+x' '-y,-x,z' '1/2-y,1/2-x,1/2+z' 'z,x,y' '1/2+z,1/2+x,1/2+y' 'y,z,x' '1/2+y,1/2+z,1/2+x' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy Hg 0.25000 0.50000 0.00000 0.70400 Cu 0.25000 0.50000 0.00000 0.14400 Zn 0.25000 0.50000 0.00000 0.08800 Tl 0.25000 0.50000 0.00000 0.01400 Fe 0.25000 0.50000 0.00000 0.00500 Cs 0.00000 0.00000 0.00000 0.59500 Tl 0.00000 0.00000 0.00000 0.22000 As 0.24530 0.24530 0.24530 0.98300 Sb 0.24530 0.24530 0.24530 0.01700 S 0.38830 0.38830 0.16250 1.00000 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Hg 0.06010 0.02290 0.02290 0.00000 0.00000 0.00000 Cu 0.06010 0.02290 0.02290 0.00000 0.00000 0.00000 Zn 0.06010 0.02290 0.02290 0.00000 0.00000 0.00000 Tl 0.06010 0.02290 0.02290 0.00000 0.00000 0.00000 Fe 0.06010 0.02290 0.02290 0.00000 0.00000 0.00000 Cs 0.04820 0.04820 0.04820 0.00000 0.00000 0.00000 Tl 0.04820 0.04820 0.04820 0.00000 0.00000 0.00000 As 0.01950 0.01950 0.01950 -0.00260 -0.00260 -0.00260 Sb 0.01950 0.01950 0.01950 -0.00260 -0.00260 -0.00260 S 0.02870 0.02870 0.02320 -0.01000 0.00110 0.00110