data_global
_chemical_name_mineral 'Manganpyrosmalite'
loop_
_publ_author_name
'Kato T'
'Takeuchi Y'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 21 
_journal_year 1983
_journal_page_first 1
_journal_page_last 6
_publ_section_title
;
 The pyrosmalite group of minerals I. Structure refinement of
 Manganpyrosmalite
 Sample 1: Iron-rich manganpyrosmalite, Kyurazawa mine, Japan
;
_database_code_amcsd 0005189
_chemical_formula_sum 'Mn4.48 Fe3.7 Si5.82 O23.35 Cl1.65 H8.35'
_cell_length_a 13.391
_cell_length_b 13.391
_cell_length_c 7.139
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 1108.649
_exptl_crystal_density_diffrn      3.165
_symmetry_space_group_name_H-M 'P -3 m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-y,-x,z'
  'y,-x+y,-z'
  '-x,-x+y,-z'
  '-x+y,-x,z'
  '-x+y,y,z'
  '-x,-y,-z'
  'y,x,-z'
  '-y,x-y,z'
  'x,x-y,z'
  'x-y,x,-z'
  'x-y,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
MnM1   0.00000   0.00000   0.00000   0.56000   0.01482
FeM1   0.00000   0.00000   0.00000   0.44000   0.01482
MnM2   0.25490   0.00000   0.00000   0.56000   0.01064
FeM2   0.25490   0.00000   0.00000   0.44000   0.01064
MnM3   0.50000   0.00000   0.00000   0.56000   0.00925
FeM3   0.50000   0.00000   0.00000   0.44000   0.00925
MnM4   0.50260   0.25130   0.02220   0.56000   0.00811
FeM4   0.50260   0.25130   0.02220   0.44000   0.00811
Si   0.43750   0.10460   0.62450   0.97000   0.00684
Fe   0.43750   0.10460   0.62450   0.03000   0.00684
O1   0.34130   0.00000   0.50000   1.00000   0.01406
O2   0.56400   0.12800   0.55820   1.00000   0.01241
O3   0.43160   0.21580   0.55510   1.00000   0.01102
O4   0.41990   0.08410   0.84910   1.00000   0.00861
Cl1   0.16800   0.08400   0.77560   0.55000   0.02647
O-H1   0.16800   0.08400   0.77560   0.45000   0.02647
O-H2   0.33660   0.16830   0.13300   1.00000   0.01153
O-H3   0.58090   0.16180   0.14500   1.00000   0.01127
O-H4   0.33333   0.66667   0.12180   1.00000   0.00507