data_global
_chemical_name_mineral 'Zenzenite'
loop_
_publ_author_name
'Holtstam D'
'Linqvist B'
'Johnsson M'
'Norrestam R'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 29 
_journal_year 1991
_journal_page_first 347
_journal_page_last 354
_publ_section_title
;
 Zenzenite: Pb3(Fe,Mn)4Mn3O15, a new mineral species
 from Langban, Filipstad, Sweden, and its crystal structure
;
_database_code_amcsd 0005262
_chemical_compound_source 'Langban, Filipstad, Sweden'
_chemical_formula_sum 'Pb3 Mn4.55 Fe2.45 O15'
_cell_length_a 10.008
_cell_length_b 10.008
_cell_length_c 13.672
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 1185.925
_exptl_crystal_density_diffrn      6.992
_symmetry_space_group_name_H-M 'P 63/m c m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x,-x+y,z'
  'x,x-y,-z'
  '-x+y,-x,1/2-z'
  'x-y,x,1/2+z'
  '-y,-x,1/2+z'
  'y,x,1/2-z'
  'y,-x+y,-z'
  '-y,x-y,z'
  'x-y,-y,z'
  '-x+y,y,-z'
  'x,y,1/2-z'
  '-x,-y,1/2+z'
  'x,x-y,1/2+z'
  '-x,-x+y,1/2-z'
  'x-y,x,-z'
  '-x+y,-x,z'
  'y,x,z'
  '-y,-x,-z'
  '-y,x-y,1/2-z'
  'y,-x+y,1/2+z'
  '-x+y,y,1/2+z'
  'x-y,-y,1/2-z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Pb1   0.61360   0.61360   0.75000   1.00000   0.01540
Pb2   0.26780   0.26780   0.75000   1.00000   0.01230
Mn1   0.83180   0.16830   0.50000   0.91000   0.00880
Fe1   0.83180   0.16830   0.50000   0.09000   0.00880
Fe2   0.33333   0.66667   0.14620   1.00000   0.00610
Mn3   0.50000   0.50000   0.50000   0.91000   0.00840
Fe3   0.50000   0.50000   0.50000   0.09000   0.00840
Mn4   0.00000   0.00000   0.00000   0.91000   0.01060
Fe4   0.00000   0.00000   0.00000   0.09000   0.01060
O1   0.48820   0.32710   0.08020   1.00000   0.01250
O2   0.52540   0.17270   0.25000   1.00000   0.00860
O3   0.16450   0.16450   0.07300   1.00000   0.01220
O4   0.67090   0.67090   0.07340   1.00000   0.01020