data_global
_chemical_name_mineral 'Phlogopite'
loop_
_publ_author_name
'Russell R L'
'Guggenheim S'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 37 
_journal_year 1999
_journal_page_first 711
_journal_page_last 720
_publ_section_title
;
 The crystal structures of near-end-member phlogopite at high temperatures
 and heat-treated Fe-rich phlogopite: The influence of the O,OH,F site
 Sample: heat-treated at 904 degrees C for 24 hours, Fe-rich phlogopite
;
_database_code_amcsd 0005598
_chemical_compound_source 'Silver Crater mine, Ontario, Canada'
_chemical_formula_sum 'K.92 Na.04 Mg1.56 Fe1.17 Ti.144 Mn.06 Si2.972 Al1.004 O11.06 (F.94 H1.06)'
_cell_length_a 5.3099
_cell_length_b 9.185
_cell_length_c 10.093
_cell_angle_alpha 90
_cell_angle_beta 100.07
_cell_angle_gamma 90
_cell_volume 484.667
_exptl_crystal_density_diffrn      3.130
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
K   0.00000   0.50000   0.00000   0.92000   0.03270
Na   0.00000   0.50000   0.00000   0.04000   0.03270
Mg1   0.00000   0.00000   0.50000   0.52000   0.01810
Fe1   0.00000   0.00000   0.50000   0.39000   0.01810
Ti1   0.00000   0.00000   0.50000   0.04000   0.01810
Mn1   0.00000   0.00000   0.50000   0.02000   0.01810
Mg2   0.00000   0.34200   0.50000   0.52000   0.01450
Fe2   0.00000   0.34200   0.50000   0.39000   0.01450
Ti2   0.00000   0.34200   0.50000   0.04000   0.01450
Mn2   0.00000   0.34200   0.50000   0.02000   0.01450
Si   0.07340   0.16740   0.22320   0.74300   0.01120
Al   0.07340   0.16740   0.22320   0.25100   0.01120
Ti   0.07340   0.16740   0.22320   0.00600   0.01120
O1   0.03100   0.00000   0.16610   1.00000   0.02000
O2   0.31550   0.23800   0.16450   1.00000   0.02160
O3   0.12950   0.16940   0.38960   1.00000   0.01280
O-H4   0.13590   0.50000   0.40100   0.53000   0.01600
F4   0.13590   0.50000   0.40100   0.47000   0.01600
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
K 0.03100 0.02900 0.03900 0.00000 0.00700 0.00000
Na 0.03100 0.02900 0.03900 0.00000 0.00700 0.00000
Mg1 0.01440 0.01320 0.02800 0.00000 0.00580 0.00000
Fe1 0.01440 0.01320 0.02800 0.00000 0.00580 0.00000
Ti1 0.01440 0.01320 0.02800 0.00000 0.00580 0.00000
Mn1 0.01440 0.01320 0.02800 0.00000 0.00580 0.00000
Mg2 0.00860 0.01310 0.02160 0.00000 0.00220 0.00000
Fe2 0.00860 0.01310 0.02160 0.00000 0.00220 0.00000
Ti2 0.00860 0.01310 0.02160 0.00000 0.00220 0.00000
Mn2 0.00860 0.01310 0.02160 0.00000 0.00220 0.00000
Si 0.00810 0.00780 0.01770 0.00000 0.00250 0.00010
Al 0.00810 0.00780 0.01770 0.00000 0.00250 0.00010
Ti 0.00810 0.00780 0.01770 0.00000 0.00250 0.00010
O1 0.02800 0.01100 0.02100 0.00000 0.00300 0.00000
O2 0.01600 0.02500 0.02400 -0.00500 0.00500 -0.00200
O3 0.01000 0.01100 0.01700 0.00100 0.00200 0.00100
O-H4 0.01400 0.01200 0.02300 0.00000 0.00400 0.00000
F4 0.01400 0.01200 0.02300 0.00000 0.00400 0.00000