Krupkaite Topa D, Makovicky E, Balic-Zunic T The Canadian Mineralogist 40 (2002) 1147-1159 The structural role of excess Cu and Pb in gladite and krupkaite based on new refinements of their structure Sample: bd50 _database_code_amcsd 0005783 CELL PARAMETERS: 4.0145 11.2020 11.5600 90.000 90.000 90.000 SPACE GROUP: Pmc2_1 X-RAY WAVELENGTH: 1.541838 Cell Volume: 519.858 Density (g/cm3): 6.963 MAX. ABS. INTENSITY / VOLUME**2: 78.67445286 RIR: 3.679 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 7.89 1.90 11.2020 0 1 0 2 11.00 2.87 8.0446 0 1 1 2 15.33 12.38 5.7800 0 0 2 1 15.82 1.75 5.6010 0 2 0 2 17.26 19.10 5.1365 0 1 2 2 22.10 51.93 4.0223 0 2 2 2 22.14 1.13 4.0145 1 0 0 2 23.54 24.62 3.7791 1 1 0 4 23.83 11.28 3.7340 0 3 0 2 24.43 100.00 3.6438 0 1 3 2 24.79 52.46 3.5921 1 1 1 4 25.06 84.38 3.5532 0 3 1 2 27.04 21.07 3.2972 1 0 2 2 28.11 11.55 3.1746 0 2 3 2 28.21 63.00 3.1631 1 1 2 4 28.42 89.42 3.1402 1 2 1 4 28.46 5.98 3.1364 0 3 2 2 30.94 4.60 2.8900 0 0 4 1 31.48 90.49 2.8414 1 2 2 4 31.96 4.59 2.8005 0 4 0 2 31.98 2.78 2.7984 0 1 4 2 32.75 17.11 2.7341 1 3 0 4 32.91 4.27 2.7218 0 4 1 2 33.42 2.50 2.6815 0 3 3 2 33.68 38.81 2.6607 1 3 1 4 34.94 47.50 2.5683 0 2 4 2 35.62 16.20 2.5203 0 4 2 2 36.07 20.96 2.4901 1 2 3 4 36.35 4.69 2.4716 1 3 2 4 38.38 26.72 2.3455 1 0 4 2 39.24 25.78 2.2957 1 1 4 4 39.43 2.74 2.2854 0 3 4 2 39.79 5.67 2.2654 0 4 3 2 39.81 1.07 2.2643 0 1 5 2 40.02 23.57 2.2528 1 4 1 4 40.45 7.12 2.2298 1 3 3 4 41.04 3.23 2.1995 0 5 1 2 41.75 10.52 2.1634 1 2 4 4 42.29 7.74 2.1371 0 2 5 2 42.34 20.87 2.1345 1 4 2 4 43.31 4.31 2.0890 0 5 2 2 45.08 3.23 2.0111 0 4 4 2 45.17 35.37 2.0073 2 0 0 2 45.68 1.72 1.9861 1 3 4 4 46.00 33.29 1.9729 1 4 3 4 46.02 9.70 1.9722 1 1 5 4 46.18 10.96 1.9657 0 3 5 2 46.41 13.25 1.9564 1 5 0 4 46.91 22.61 1.9368 0 5 3 2 47.11 4.35 1.9289 1 5 1 4 47.17 10.08 1.9267 0 0 6 1 47.91 1.71 1.8988 0 1 6 2 47.98 1.21 1.8962 2 0 2 2 48.24 9.59 1.8864 1 2 5 4 48.71 1.91 1.8696 2 1 2 4 48.78 7.83 1.8670 0 6 0 2 49.17 4.72 1.8531 1 5 2 4 49.45 2.68 1.8431 0 6 1 2 50.07 2.69 1.8219 0 2 6 2 50.77 1.62 1.7981 1 4 4 4 50.84 9.09 1.7960 2 2 2 4 51.43 2.62 1.7766 0 6 2 2 51.62 3.27 1.7707 0 5 4 2 51.70 2.04 1.7680 2 3 0 4 51.78 12.00 1.7654 1 3 5 4 52.01 19.71 1.7581 2 1 3 4 52.35 17.94 1.7477 2 3 1 4 52.45 4.83 1.7444 1 5 3 4 52.70 9.85 1.7370 1 0 6 2 53.38 5.33 1.7165 1 1 6 4 53.52 2.00 1.7122 0 3 6 2 54.05 2.60 1.6966 2 2 3 4 54.18 1.31 1.6929 1 6 0 4 54.26 1.38 1.6907 2 3 2 4 54.81 4.98 1.6750 1 6 1 4 55.38 2.46 1.6590 1 2 6 4 55.76 1.30 1.6486 2 0 4 2 56.40 1.31 1.6315 2 4 0 4 56.47 5.03 1.6294 1 4 5 4 57.01 1.41 1.6155 2 4 1 4 58.11 1.42 1.5873 0 4 6 2 58.20 2.53 1.5852 0 7 1 2 58.25 1.06 1.5840 0 2 7 2 58.35 15.48 1.5815 2 2 4 4 58.62 2.71 1.5749 1 3 6 4 58.81 5.35 1.5701 2 4 2 4 58.89 2.76 1.5682 0 6 4 2 59.98 2.67 1.5423 0 7 2 2 61.25 8.74 1.5133 1 1 7 4 61.39 5.77 1.5103 0 3 7 2 61.48 1.07 1.5082 2 3 4 4 61.75 2.31 1.5024 2 4 3 4 62.16 1.83 1.4934 1 5 5 4 62.66 1.44 1.4826 2 5 1 4 63.05 2.50 1.4744 1 7 1 4 63.09 2.67 1.4735 1 2 7 4 63.59 3.38 1.4631 2 2 5 4 63.71 1.52 1.4608 0 5 6 2 63.71 4.28 1.4607 1 6 4 4 64.11 1.04 1.4525 0 6 5 2 64.37 1.93 1.4474 2 5 2 4 64.75 7.38 1.4397 1 7 2 4 65.09 1.50 1.4331 0 1 8 2 65.63 2.71 1.4225 0 4 7 2 65.73 1.55 1.4207 2 4 4 4 66.59 5.51 1.4044 2 3 5 4 66.87 1.21 1.3992 0 2 8 2 67.16 11.22 1.3938 2 5 3 4 67.37 5.18 1.3900 2 0 6 2 67.54 3.56 1.3869 1 7 3 4 68.33 3.20 1.3727 1 5 6 4 68.66 4.14 1.3671 2 6 0 4 68.72 2.14 1.3659 1 6 5 4 69.01 1.75 1.3609 0 8 2 2 69.20 1.47 1.3576 2 6 1 4 69.70 1.36 1.3491 2 2 6 4 70.19 1.15 1.3408 1 4 7 4 70.20 2.62 1.3408 0 6 6 2 70.83 1.51 1.3304 2 6 2 4 70.98 1.87 1.3279 2 5 4 4 71.34 1.11 1.3221 1 8 0 4 71.35 7.41 1.3219 1 7 4 4 71.39 4.28 1.3212 1 2 8 4 71.47 1.58 1.3200 3 1 1 4 71.72 1.06 1.3161 0 8 3 2 71.87 1.77 1.3136 1 8 1 4 72.57 1.22 1.3026 2 3 6 4 73.07 2.44 1.2949 3 1 2 4 73.18 3.35 1.2934 3 2 1 4 74.33 2.36 1.2761 0 1 9 2 74.63 1.57 1.2717 1 6 6 4 74.77 3.87 1.2697 3 2 2 4 75.31 4.45 1.2619 1 5 7 4 75.44 1.46 1.2601 0 8 4 2 75.99 1.81 1.2523 3 3 1 4 76.59 1.59 1.2440 2 7 1 4 77.06 1.46 1.2375 0 9 1 2 77.19 1.87 1.2358 2 6 4 4 77.39 1.27 1.2331 3 2 3 4 78.15 2.74 1.2231 1 4 8 4 78.16 1.84 1.2230 2 7 2 4 78.82 1.79 1.2143 3 0 4 2 79.37 1.93 1.2072 3 1 4 4 79.40 4.05 1.2068 2 3 7 4 79.88 1.79 1.2009 3 4 1 4 80.85 1.53 1.1888 1 9 0 4 81.37 1.15 1.1826 1 9 1 4 81.41 1.16 1.1821 1 6 7 4 81.43 1.62 1.1819 3 4 2 4 81.49 1.12 1.1811 2 5 6 4 82.65 1.31 1.1675 0 4 9 2 82.75 1.12 1.1664 2 1 8 4 83.08 1.34 1.1626 1 3 9 4 83.10 1.50 1.1623 1 5 8 4 83.25 2.15 1.1606 2 4 7 4 84.00 3.28 1.1522 3 4 3 4 84.29 1.30 1.1488 3 5 0 4 85.64 1.03 1.1342 3 2 5 4 86.38 1.43 1.1264 2 8 2 4 86.89 1.44 1.1211 1 4 9 4 87.49 2.20 1.1149 2 6 6 4 87.89 2.43 1.1109 1 0 10 2 88.36 1.48 1.1062 3 3 5 4 89.08 1.26 1.0991 3 0 6 2 89.41 1.18 1.0959 0 9 5 2 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.