Krupkaite Topa D, Makovicky E, Balic-Zunic T The Canadian Mineralogist 40 (2002) 1147-1159 The structural role of excess Cu and Pb in gladite and krupkaite based on new refinements of their structure Sample: bd59, split Bi3 site _database_code_amcsd 0005785 CELL PARAMETERS: 4.0212 11.2320 11.5810 90.000 90.000 90.000 SPACE GROUP: Pmc2_1 X-RAY WAVELENGTH: 1.541838 Cell Volume: 523.069 Density (g/cm3): 6.967 MAX. ABS. INTENSITY / VOLUME**2: 76.64896989 RIR: 3.583 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 7.87 1.51 11.2320 0 1 0 2 10.97 2.58 8.0628 0 1 1 2 15.30 10.00 5.7905 0 0 2 1 15.78 1.26 5.6160 0 2 0 2 17.23 17.84 5.1468 0 1 2 2 22.05 54.08 4.0314 0 2 2 2 23.50 24.28 3.7859 1 1 0 4 23.77 8.60 3.7440 0 3 0 2 24.38 100.00 3.6507 0 1 3 2 24.74 52.36 3.5985 1 1 1 4 25.00 83.97 3.5625 0 3 1 2 27.00 19.24 3.3029 1 0 2 2 28.05 10.76 3.1813 0 2 3 2 28.16 65.62 3.1687 1 1 2 4 28.36 85.37 3.1465 1 2 1 4 28.39 5.17 3.1440 0 3 2 2 30.88 5.78 2.8953 0 0 4 1 31.42 90.38 2.8470 1 2 2 4 31.87 5.50 2.8080 0 4 0 2 31.92 2.52 2.8036 0 1 4 2 32.68 16.14 2.7402 1 3 0 4 32.82 4.08 2.7289 0 4 1 2 33.34 1.84 2.6876 0 3 3 2 33.61 41.97 2.6665 1 3 1 4 34.86 46.36 2.5734 0 2 4 2 35.53 16.80 2.5266 0 4 2 2 36.00 21.88 2.4949 1 2 3 4 36.27 4.55 2.4768 1 3 2 4 38.31 25.86 2.3496 1 0 4 2 39.17 23.88 2.2998 1 1 4 4 39.34 2.61 2.2903 0 3 4 2 39.69 4.26 2.2708 0 4 3 2 39.73 1.41 2.2685 0 1 5 2 39.93 25.11 2.2581 1 4 1 4 40.37 8.34 2.2345 1 3 3 4 40.92 3.13 2.2053 0 5 1 2 41.67 10.93 2.1675 1 2 4 4 42.20 7.30 2.1412 0 2 5 2 42.24 19.32 2.1394 1 4 2 4 43.20 3.55 2.0943 0 5 2 2 44.97 2.78 2.0157 0 4 4 2 45.09 35.24 2.0106 2 0 0 2 45.58 1.15 1.9902 1 3 4 4 45.89 31.44 1.9773 1 4 3 4 45.93 8.60 1.9758 1 1 5 4 46.08 11.45 1.9697 0 3 5 2 46.29 12.07 1.9611 1 5 0 4 46.79 24.38 1.9416 0 5 3 2 46.99 4.15 1.9336 1 5 1 4 47.08 9.53 1.9302 0 0 6 1 47.81 1.62 1.9023 0 1 6 2 48.15 9.72 1.8900 1 2 5 4 48.62 1.74 1.8728 2 1 2 4 48.64 8.47 1.8720 0 6 0 2 49.04 3.65 1.8575 1 5 2 4 49.31 1.87 1.8480 0 6 1 2 49.96 2.32 1.8254 0 2 6 2 50.66 1.96 1.8020 1 4 4 4 50.74 9.09 1.7992 2 2 2 4 51.29 2.16 1.7812 0 6 2 2 51.49 2.52 1.7748 0 5 4 2 51.60 1.49 1.7713 2 3 0 4 51.67 10.88 1.7689 1 3 5 4 51.92 18.87 1.7612 2 1 3 4 52.24 17.31 1.7510 2 3 1 4 52.32 4.71 1.7484 1 5 3 4 52.60 8.88 1.7401 1 0 6 2 53.27 5.69 1.7196 1 1 6 4 53.41 1.58 1.7156 0 3 6 2 53.95 2.32 1.6996 2 2 3 4 54.15 1.12 1.6939 2 3 2 4 54.66 4.44 1.6792 1 6 1 4 55.27 3.04 1.6621 1 2 6 4 55.66 1.61 1.6514 2 0 4 2 56.27 1.49 1.6347 2 4 0 4 56.35 4.47 1.6328 1 4 5 4 56.88 1.26 1.6187 2 4 1 4 57.98 1.30 1.5906 0 4 6 2 58.03 2.14 1.5894 0 7 1 2 58.23 14.60 1.5844 2 2 4 4 58.49 2.38 1.5780 1 3 6 4 58.68 5.32 1.5733 2 4 2 4 58.73 2.48 1.5720 0 6 4 2 59.81 2.40 1.5463 0 7 2 2 61.13 8.39 1.5160 1 1 7 4 61.25 5.25 1.5133 0 3 7 2 61.61 1.67 1.5053 2 4 3 4 62.01 1.37 1.4967 1 5 5 4 62.51 1.39 1.4858 2 5 1 4 62.87 3.01 1.4781 1 7 1 4 62.96 2.31 1.4762 1 2 7 4 63.47 3.06 1.4657 2 2 5 4 63.54 4.67 1.4641 1 6 4 4 63.55 1.18 1.4640 0 5 6 2 64.22 1.50 1.4504 2 5 2 4 64.57 7.25 1.4433 1 7 2 4 64.95 1.41 1.4357 0 1 8 2 65.48 2.50 1.4254 0 4 7 2 65.58 1.29 1.4235 2 4 4 4 66.45 5.54 1.4070 2 3 5 4 66.73 1.27 1.4018 0 2 8 2 67.00 11.66 1.3967 2 5 3 4 67.24 4.71 1.3924 2 0 6 2 67.35 2.66 1.3903 1 7 3 4 68.17 2.70 1.3757 1 5 6 4 68.48 4.31 1.3701 2 6 0 4 68.55 1.92 1.3690 1 6 5 4 68.80 1.76 1.3645 0 8 2 2 69.56 1.09 1.3515 2 2 6 4 70.02 2.70 1.3438 0 6 6 2 70.03 1.20 1.3435 1 4 7 4 70.65 1.24 1.3333 2 6 2 4 70.81 1.38 1.3306 2 5 4 4 71.15 6.59 1.3251 1 7 4 4 71.24 3.50 1.3237 1 2 8 4 71.33 1.41 1.3223 3 1 1 4 71.66 1.52 1.3169 1 8 1 4 72.93 2.38 1.2971 3 1 2 4 73.03 2.99 1.2956 3 2 1 4 74.17 2.03 1.2784 0 1 9 2 74.44 1.25 1.2745 1 6 6 4 74.62 3.53 1.2719 3 2 2 4 75.13 4.67 1.2646 1 5 7 4 75.21 1.37 1.2633 0 8 4 2 75.83 1.78 1.2545 3 3 1 4 76.38 1.31 1.2469 2 7 1 4 76.82 1.41 1.2408 0 9 1 2 77.00 1.65 1.2384 2 6 4 4 77.23 1.27 1.2352 3 2 3 4 77.95 1.58 1.2257 2 7 2 4 77.96 2.31 1.2255 1 4 8 4 78.66 1.58 1.2164 3 0 4 2 79.21 1.71 1.2093 3 1 4 4 79.23 3.57 1.2091 2 3 7 4 79.70 1.80 1.2031 3 4 1 4 80.60 1.54 1.1919 1 9 0 4 81.24 1.37 1.1841 3 4 2 4 82.45 1.14 1.1698 0 4 9 2 82.57 1.01 1.1684 2 1 8 4 82.89 1.43 1.1647 1 3 9 4 82.89 1.06 1.1647 1 5 8 4 83.05 1.91 1.1628 2 4 7 4 83.80 2.90 1.1543 3 4 3 4 84.09 1.09 1.1511 3 5 0 4 86.13 1.40 1.1290 2 8 2 4 86.68 1.24 1.1232 1 4 9 4 87.26 2.18 1.1172 2 6 6 4 87.69 2.30 1.1129 1 0 10 2 88.16 1.25 1.1082 3 3 5 4 88.89 1.07 1.1010 3 0 6 2 89.75 1.85 1.0927 1 8 6 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.