Kupletskite
Piilonen P C, McDonald A M, Lalonde A E
The Canadian Mineralogist 41 (2003) 27-54
Insights into astrophyllite-group minerals II: Crystal chemistry
Note: sample MSH2
Locality: nepheline syenite pegmatite at Mont Saint-Hilaire, Quebec, Canada
_database_code_amcsd 0005810
5.3982 11.9534 11.7433 112.9903 94.8413 103.0664 P-1
atom       x      y      z  occ  Uiso U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3)
Mn(1) .84974 .20565 .47864 .891 .0105  .0098  .0099  .0123  .0026  .0026  .0051
Na(1) .84974 .20565 .47864 .109 .0105  .0098  .0099  .0123  .0026  .0026  .0051
Mn(2) .27981 .06664 .48689 .994 .0117  .0109  .0113  .0141  .0033  .0038  .0062
Mn(3) .42217 .35146 .48358 .985 .0118  .0110  .0112  .0148  .0038  .0041  .0064
Mn(4)      0     .5     .5 .477 .0107  .0102  .0090  .0121  .0023  .0017  .0039
Mg(4)      0     .5     .5 .023 .0107  .0102  .0090  .0121  .0023  .0017  .0039
Ti    .07888 .08599 .19615 .910 .0093  .0080  .0091  .0106  .0022  .0020  .0042
Nb    .07888 .08599 .19615 .090 .0093  .0080  .0091  .0106  .0022  .0020  .0042
Si(1)  .6782 .27155 .22990      .0091  .0096  .0078  .0086  .0015  .0012  .0028
Si(2)  .8119 .54638 .25308      .0103  .0110  .0083  .0113  .0019  .0019  .0043
Si(3)  .3770 .67531 .25548      .0103  .0111  .0093  .0114  .0023  .0025  .0053
Si(4)  .5080 .93132 .23431      .0090  .0097  .0086  .0085  .0018  .0015  .0037
K      .1320  .2634  .9950  .84 .0444  .0564  .0429  .0279  .0102  .0049  .0115
Na     .1320  .2634  .9950  .16 .0444  .0564  .0429  .0279  .0102  .0049  .0115
Na        .5      0      0 .309 .0132  .0190  .0112  .0080  .0026  .0013  .0037
Ca        .5      0      0 .191 .0132  .0190  .0112  .0080  .0026  .0013  .0037
O(1)   .7280  .3176  .3818      .0118  .0130  .0126  .0090  .0029  .0015  .0043
O(2)   .1461  .1589  .3666      .0121  .0135  .0121  .0092  .0025  .0010  .0039
O(3)   .1289  .3924  .5947      .0119  .0117  .0115  .0114  .0024  .0016  .0041
OH(4)  .2977  .4629  .3974      .0142  .0149  .0136  .0138  .0038  .0017  .0057
OH(5)  .9924  .1188  .5944      .0139  .0132  .0136  .0134  .0028  .0017  .0049
O(6)   .5586  .2572  .5914      .0115  .0140  .0105  .0098  .0032  .0020  .0043
O(7)   .5757  .0140  .3864      .0111  .0134  .0119  .0077  .0030  .0014  .0044
O(8)   .0709  .5928  .2012      .0187  .0152  .0214  .0151 -.0009  .0043  .0063
O(9)   .2472  .0414  .8297      .0220  .0174  .0240  .0139 -.0059  .0066  .0028
O(10)  .4330  .4149  .7989      .0187  .0218  .0209  .0156  .0116  .0026  .0071
O(11)  .1288  .8091  .8335      .0224  .0333  .0281  .0143  .0230  .0082  .0091
O(12)  .2642  .9571  .1705      .0223  .0274  .0242  .0144  .0162 -.0032  .0039
O(13)  .2658  .6068  .8068      .0188  .0300  .0109  .0136  .0022  .0026  .0054
O(14)  .5721  .2214  .8029      .0185  .0293  .0104  .0149  .0024  .0040  .0064
O(15)  .3811  .1910  .1664      .0219  .0131  .0283  .0166 -.0078 -.0023  .0101
F(16)      0      0      0  .50 .0143  .0180  .0137  .0095  .0036  .0015  .0038