data_global _chemical_name_mineral 'Goldquarryite' loop_ _publ_author_name 'Cooper M A' 'Hawthorne F C' _journal_name_full 'The Canadian Mineralogist' _journal_volume 42 _journal_year 2004 _journal_page_first 753 _journal_page_last 761 _publ_section_title ; The crystal structure of goldquarryite, (Cu,_)(Cd,Ca)2Al2(PO4)4F2(H2O)10{(H2O),F}2, a secondary phosphate from the Gold Quarry Mine, Eureka County, Nevada, U.S.A. ; _database_code_amcsd 0005937 _chemical_compound_source 'Gold Quarry Mine, Carlin, Eureka County, Nevada, USA' _chemical_formula_sum 'Cu.7 (Cd1.68 Ca.32) P4 Al3 F2.4 O27.6 H23.2' _cell_length_a 6.787 _cell_length_b 9.082 _cell_length_c 10.113 _cell_angle_alpha 101.40 _cell_angle_beta 104.27 _cell_angle_gamma 102.51 _cell_volume 568.643 _exptl_crystal_density_diffrn 2.808 _symmetry_space_group_name_H-M 'P -1' loop_ _space_group_symop_operation_xyz 'x,y,z' '-x,-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy _atom_site_U_iso_or_equiv Cu2+ 0.00000 0.00000 0.00000 0.70000 0.01890 Cd 0.27682 0.51849 0.55938 0.84000 0.01080 Ca 0.27682 0.51849 0.55938 0.16000 0.01080 P1 0.23890 0.18570 0.32880 1.00000 0.00980 P2 0.10770 0.71240 0.32640 1.00000 0.00990 Al1 0.50000 0.00000 0.50000 1.00000 0.00870 Al2 0.00000 0.00000 0.50000 1.00000 0.00970 Al3 0.00000 0.50000 0.00000 1.00000 0.01330 F1 0.28420 0.02320 0.57810 1.00000 0.01900 O1 0.36780 0.35630 0.39820 1.00000 0.01300 O2 0.37920 0.07360 0.34670 1.00000 0.01300 O3 0.14270 0.16770 0.17030 1.00000 0.01700 O4 0.06100 0.14590 0.39560 1.00000 0.01200 O5 -0.01780 0.83320 0.34680 1.00000 0.01200 O6 0.34730 0.79230 0.39680 1.00000 0.01300 O7 0.03930 0.58150 0.39520 1.00000 0.01600 O8 0.06470 0.64840 0.16780 1.00000 0.02000 Wat1 0.41870 0.37690 0.71460 1.00000 0.01800 Wat2 0.18330 0.63750 -0.05440 0.80000 0.01600 F2 0.18330 0.63750 -0.05440 0.20000 0.01600 Wat3 0.23190 0.41930 0.07840 1.00000 0.01700 Wat4 0.27340 0.73780 0.72350 1.00000 0.02400 Wat5 0.17860 0.10970 -0.09620 1.00000 0.03900 Wat6 0.40900 -0.07510 0.09050 0.70000 0.04800 Wat7 0.26300 -0.08200 0.06600 0.30000 0.03600 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Cu2+ 0.03420 0.00960 0.00750 0.00060 0.00240 0.00130 Cd 0.00790 0.01270 0.01310 0.00360 0.00450 0.00390 Ca 0.00790 0.01270 0.01310 0.00360 0.00450 0.00390 P1 0.00910 0.00820 0.01300 0.00240 0.00480 0.00310 P2 0.00940 0.00880 0.01160 0.00200 0.00400 0.00280 Al1 0.00630 0.00900 0.01100 0.00200 0.00260 0.00220 Al2 0.00940 0.00900 0.01000 0.00210 0.00340 0.00300 Al3 0.01600 0.01400 0.01100 0.00650 0.00570 0.00150 F1 0.01600 0.02100 0.01800 0.00400 0.00700 -0.00100 O1 0.01000 0.00700 0.01700 -0.00400 0.00500 -0.00100 O2 0.00900 0.01500 0.02100 0.00900 0.00700 0.00800 O3 0.02000 0.01800 0.01000 -0.00200 0.00000 0.00700 O4 0.01200 0.01500 0.01700 0.00800 0.01000 0.01100 O5 0.00800 0.01500 0.01500 0.00400 0.00400 0.00600 O6 0.00700 0.01100 0.01800 0.00100 -0.00100 0.00200 O7 0.01400 0.01600 0.02300 0.00500 0.00900 0.01300 O8 0.02000 0.02300 0.01700 0.00600 0.00800 0.00200 Wat1 0.01100 0.01700 0.02200 -0.00200 0.00200 0.00600 Wat2 0.02100 0.01700 0.01500 0.00800 0.01000 0.00400 F2 0.02100 0.01700 0.01500 0.00800 0.01000 0.00400 Wat3 0.02000 0.01900 0.01100 0.00900 0.00300 0.00300 Wat4 0.01800 0.01500 0.03600 -0.00100 0.01500 0.00000 Wat5 0.04700 0.04200 0.02300 0.00700 0.00900 0.00300