data_global _chemical_name_mineral 'Oxykinoshitalite' loop_ _publ_author_name 'Kogarko L N' 'Uvarova Y A' 'Sokolova E' 'Hawthorne F C' 'Ottolini L' 'Grice J D' _journal_name_full 'The Canadian Mineralogist' _journal_volume 43 _journal_year 2005 _journal_page_first 1501 _journal_page_last 1510 _publ_section_title ; Oxykinoshitalite, a new species of mica from Fernando-do-Noronha island, Brazil: Occurrence and crystal structure ; _database_code_amcsd 0006061 _chemical_compound_source 'Fernando-do-Noronha island, Brazil' _chemical_formula_sum 'Ba.47 K.42 Na.06 Ca.01 Mg1.36 Fe.88 Ti.75 Mn.01 Si2.312 Al1.56 O11.75 F.25 H.31' _cell_length_a 5.3516 _cell_length_b 9.2817 _cell_length_c 10.0475 _cell_angle_alpha 90 _cell_angle_beta 100.337 _cell_angle_gamma 90 _cell_volume 490.978 _exptl_crystal_density_diffrn 3.392 _symmetry_space_group_name_H-M 'C 1 2/m 1' loop_ _space_group_symop_operation_xyz 'x,y,z' '1/2+x,1/2+y,z' 'x,-y,z' '1/2+x,1/2-y,z' '-x,y,-z' '1/2-x,1/2+y,-z' '-x,-y,-z' '1/2-x,1/2-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy _atom_site_U_iso_or_equiv BaI 0.00000 0.00000 0.00000 0.47000 0.02290 KI 0.00000 0.00000 0.00000 0.42000 0.02290 NaI 0.00000 0.00000 0.00000 0.06000 0.02290 CaI 0.00000 0.00000 0.00000 0.01000 0.02290 MgM1 0.00000 0.50000 0.50000 0.52000 0.01020 Fe2+M1 0.00000 0.50000 0.50000 0.13000 0.01020 Fe3+M1 0.00000 0.50000 0.50000 0.27000 0.01020 Ti4+M1 0.00000 0.50000 0.50000 0.08000 0.01020 MgM2 0.00000 0.15509 0.50000 0.42000 0.01270 Ti4+M2 0.00000 0.15509 0.50000 0.33500 0.01270 Fe3+M2 0.00000 0.15509 0.50000 0.16500 0.01270 Fe2+M2 0.00000 0.15509 0.50000 0.07500 0.01270 MnM2 0.00000 0.15509 0.50000 0.00500 0.01270 SiT 0.57360 0.16750 0.22032 0.57800 0.01110 AlT 0.57360 0.16750 0.22032 0.39000 0.01110 O1 0.81790 0.23540 0.15860 1.00000 0.02270 O2 0.63140 0.17090 0.39030 1.00000 0.01350 O3 0.52230 0.00000 0.16030 1.00000 0.02020 O4 0.12570 0.00000 0.39640 0.72000 0.01600 O-H4 0.12570 0.00000 0.39640 0.15500 0.01600 F4 0.12570 0.00000 0.39640 0.12500 0.01600 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 BaI 0.01970 0.02050 0.02850 0.00000 0.00460 0.00000 KI 0.01970 0.02050 0.02850 0.00000 0.00460 0.00000 NaI 0.01970 0.02050 0.02850 0.00000 0.00460 0.00000 CaI 0.01970 0.02050 0.02850 0.00000 0.00460 0.00000 MgM1 0.00820 0.00650 0.01670 0.00000 0.00430 0.00000 Fe2+M1 0.00820 0.00650 0.01670 0.00000 0.00430 0.00000 Fe3+M1 0.00820 0.00650 0.01670 0.00000 0.00430 0.00000 Ti4+M1 0.00820 0.00650 0.01670 0.00000 0.00430 0.00000 MgM2 0.00670 0.01750 0.01390 0.00000 0.00140 0.00000 Ti4+M2 0.00670 0.01750 0.01390 0.00000 0.00140 0.00000 Fe3+M2 0.00670 0.01750 0.01390 0.00000 0.00140 0.00000 Fe2+M2 0.00670 0.01750 0.01390 0.00000 0.00140 0.00000 MnM2 0.00670 0.01750 0.01390 0.00000 0.00140 0.00000 SiT 0.00830 0.01060 0.01450 -0.00050 0.00240 0.00010 AlT 0.00830 0.01060 0.01450 -0.00050 0.00240 0.00010 O1 0.01920 0.02870 0.02100 -0.00750 0.00600 -0.00300 O2 0.01200 0.01070 0.01800 -0.00070 0.00310 0.00070 O3 0.02900 0.01630 0.01300 0.00000 -0.00120 0.00000 O4 0.00930 0.02300 0.01600 0.00000 0.00310 0.00000 O-H4 0.00930 0.02300 0.01600 0.00000 0.00310 0.00000 F4 0.00930 0.02300 0.01600 0.00000 0.00310 0.00000