data_global
_chemical_name_mineral 'Fluoro-edenite'
loop_
_publ_author_name
'Gianfagna A'
'Andreozzi G B'
'Ballirano P'
'Mazziotti-Tagliani S'
'Bruni B M'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 45 
_journal_year 2007
_journal_page_first 249
_journal_page_last 262
_publ_section_title
;
 Structural and chemical contrasts between prismatic and fibrous fluoro-edenite
 from Biancavilla, Sicily, Italy
;
_database_code_amcsd 0006136
_chemical_compound_source 'Biancavilla, Mt. Etna, Sicily, Italy'
_chemical_formula_sum 'K.157 Na.802 Ca1.506 Al.64 Ti.062 Mg4.255 Fe.497 Mn.062 Si7.464 O22 F1.97 Cl.02'
_cell_length_a 9.8125
_cell_length_b 18.0188
_cell_length_c 5.2781
_cell_angle_alpha 90
_cell_angle_beta 104.620
_cell_angle_gamma 90
_cell_volume 903.002
_exptl_crystal_density_diffrn      3.088
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
KA   0.00000   0.50000   0.00000   0.15700   0.02000
NaAm   0.07400   0.50000   0.06700   0.15400   0.03000
CaM4   0.00000   0.27610   0.50000   0.75300   0.01100
NaM4   0.00000   0.27610   0.50000   0.24700   0.01100
AlM1   0.00000   0.08860   0.50000   0.05200   0.00600
TiM1   0.00000   0.08860   0.50000   0.03100   0.00600
MgM1   0.00000   0.08860   0.50000   0.91700   0.00600
Fe3+M2   0.00000   0.17670   0.00000   0.16700   0.00600
Fe2+M2   0.00000   0.17670   0.00000   0.06300   0.00600
MnM2   0.00000   0.17670   0.00000   0.03100   0.00600
MgM2   0.00000   0.17670   0.00000   0.72900   0.00600
Fe2+M3   0.00000   0.00000   0.00000   0.03700   0.00600
MgM3   0.00000   0.00000   0.00000   0.96300   0.00600
SiT1   0.28070   0.08380   0.29610   0.93300   0.00500
AlT1   0.28070   0.08380   0.29610   0.06700   0.00500
SiT2   0.29130   0.17090   0.80470   0.93300   0.00500
AlT2   0.29130   0.17090   0.80470   0.06700   0.00500
O1   0.11150   0.08510   0.22190   1.00000   0.01000
O2   0.11910   0.17270   0.72170   1.00000   0.01000
F3   0.10280   0.00000   0.70770   0.98500   0.01000
Cl3   0.10280   0.00000   0.70770   0.01000   0.01000
O4   0.36700   0.24870   0.79030   1.00000   0.01000
O5   0.34630   0.13440   0.09860   1.00000   0.01000
O6   0.34530   0.11680   0.59590   1.00000   0.01000
O7   0.34250   0.00000   0.29170   1.00000   0.01000