Makovickyite Topa D, Makovicky E, Balic-Zunic T The Canadian Mineralogist 46 (2008) 515-523 What is the reason for the doubled unit-cell volumes of copper-lead-rich pavonite homologues? The crystal structures of cupromakovickyite and makovickyite Locality: Felbertal, Austria _database_code_amcsd 0006188 CELL PARAMETERS: 13.2390 4.0547 14.6670 90.000 99.397 90.000 SPACE GROUP: C2/m X-RAY WAVELENGTH: 1.541838 Cell Volume: 776.762 Density (g/cm3): 6.839 MAX. ABS. INTENSITY / VOLUME**2: 111.9364162 RIR: 5.330 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 6.11 7.25 14.4702 0 0 1 2 12.23 1.75 7.2351 0 0 2 2 13.56 2.01 6.5307 2 0 0 2 13.94 2.48 6.3542 -2 0 1 2 15.77 14.98 5.6185 2 0 1 2 16.74 2.33 5.2971 -2 0 2 2 19.74 13.05 4.4964 2 0 2 2 21.03 5.14 4.2234 -2 0 3 2 22.97 3.90 3.8724 1 1 0 4 24.61 6.49 3.6175 0 0 4 2 24.67 57.44 3.6085 2 0 3 2 25.56 100.00 3.4850 -1 1 2 4 26.14 63.68 3.4092 -2 0 4 2 26.63 5.70 3.3474 1 1 2 4 26.99 35.64 3.3032 -4 0 1 2 27.31 2.02 3.2653 4 0 0 2 28.09 9.25 3.1771 -4 0 2 2 28.86 3.88 3.0936 -1 1 3 4 30.06 11.71 2.9725 -3 1 1 4 30.12 39.70 2.9672 3 1 0 4 30.29 11.15 2.9507 1 1 3 4 30.90 7.16 2.8940 0 0 5 2 31.28 5.42 2.8593 -3 1 2 4 31.44 90.15 2.8451 3 1 1 4 31.71 14.17 2.8220 -2 0 5 2 33.66 10.30 2.6630 -3 1 3 4 34.75 1.21 2.5819 1 1 4 4 35.94 4.80 2.4991 2 0 5 2 36.98 4.28 2.4306 -3 1 4 4 37.59 2.60 2.3929 -2 0 6 2 38.03 2.35 2.3661 -4 0 5 2 39.78 34.26 2.2662 1 1 5 4 40.11 3.47 2.2482 4 0 4 2 41.07 2.33 2.1976 -3 1 5 4 41.29 4.33 2.1864 -5 1 2 4 41.45 1.22 2.1784 3 1 4 4 42.00 2.30 2.1511 2 0 6 2 42.84 18.68 2.1108 -5 1 3 4 43.02 10.72 2.1028 6 0 1 2 43.22 8.78 2.0931 -1 1 6 4 43.79 9.67 2.0672 0 0 7 2 44.70 23.28 2.0273 0 2 0 2 44.74 4.93 2.0255 5 1 2 4 44.96 5.34 2.0163 -6 0 4 2 45.13 3.16 2.0091 4 0 5 2 45.25 5.25 2.0041 1 1 6 4 45.27 19.48 2.0031 -5 1 4 4 45.43 10.05 1.9966 6 0 2 2 45.77 14.36 1.9826 -3 1 6 4 46.19 1.69 1.9653 3 1 5 4 47.69 2.56 1.9070 2 2 1 4 47.81 14.84 1.9025 5 1 3 4 48.02 5.59 1.8946 -6 0 5 2 48.10 1.82 1.8918 -4 0 7 2 48.93 5.24 1.8614 -1 1 7 4 49.31 2.99 1.8482 2 2 2 4 50.08 2.86 1.8213 -2 0 8 2 50.59 4.63 1.8043 4 0 6 2 50.95 2.22 1.7923 -3 1 7 4 51.08 3.74 1.7880 1 1 7 4 51.42 6.08 1.7772 3 1 6 4 51.57 2.97 1.7724 5 1 4 4 51.69 2.15 1.7686 0 2 4 4 51.72 10.73 1.7675 2 2 3 4 51.78 1.88 1.7657 -6 0 6 2 52.52 12.68 1.7425 -2 2 4 4 53.00 7.59 1.7279 -4 2 1 4 53.49 7.97 1.7131 -7 1 1 4 53.63 3.80 1.7090 -4 2 2 4 53.78 3.42 1.7046 -4 0 8 2 54.11 3.08 1.6950 7 1 0 4 54.83 1.16 1.6742 2 0 8 2 55.33 3.02 1.6605 0 2 5 4 55.65 1.43 1.6516 -8 0 2 2 55.84 5.33 1.6465 -2 2 5 4 56.44 1.36 1.6304 4 0 7 2 56.48 6.91 1.6294 -8 0 3 2 56.82 2.26 1.6203 -5 1 7 4 56.93 1.40 1.6174 6 0 5 2 57.06 1.77 1.6140 3 1 7 4 57.30 1.42 1.6078 0 0 9 2 58.64 1.21 1.5744 2 2 5 4 60.10 1.45 1.5395 -4 2 5 4 60.52 1.19 1.5298 7 1 3 4 61.35 1.93 1.5110 -1 1 9 4 61.60 2.06 1.5056 4 2 4 4 62.08 1.82 1.4950 -7 1 6 4 63.10 2.68 1.4733 3 1 8 4 63.74 1.54 1.4601 1 1 9 4 63.77 6.07 1.4595 6 2 1 4 64.36 4.10 1.4474 0 2 7 4 65.26 2.15 1.4296 -6 2 4 4 65.40 2.08 1.4271 4 2 5 4 65.63 4.44 1.4225 6 2 2 4 66.20 1.31 1.4116 5 1 7 4 66.23 2.37 1.4110 -4 0 10 2 66.58 2.10 1.4046 8 0 4 2 67.29 1.43 1.3915 -5 1 9 4 67.69 2.59 1.3842 -6 2 5 4 68.06 1.22 1.3775 -1 1 10 4 68.97 1.93 1.3617 -3 1 10 4 69.36 2.03 1.3549 -2 2 8 4 69.78 2.34 1.3478 4 2 6 4 70.25 2.41 1.3400 -7 1 8 4 70.58 1.06 1.3345 1 1 10 4 70.76 1.50 1.3315 -6 2 6 4 71.11 4.15 1.3258 -1 3 2 4 71.71 3.82 1.3162 -9 1 5 4 72.32 5.45 1.3065 9 1 2 4 72.35 1.83 1.3061 10 0 0 2 72.44 1.84 1.3047 -4 2 8 4 72.80 2.20 1.2991 7 1 6 4 73.35 1.62 1.2908 3 3 0 4 74.05 4.99 1.2802 3 3 1 4 74.71 1.16 1.2705 4 2 7 4 74.75 5.23 1.2700 -8 2 3 4 75.12 1.01 1.2647 9 1 3 4 75.14 3.04 1.2643 -1 1 11 4 76.37 1.07 1.2471 3 1 10 4 79.04 3.13 1.2115 1 3 5 4 80.65 1.47 1.1912 -7 1 10 4 81.09 1.98 1.1859 -5 3 3 4 82.80 1.88 1.1658 -5 3 4 4 83.15 1.75 1.1617 -3 3 6 4 83.47 1.79 1.1581 -4 2 10 4 83.78 1.97 1.1546 8 2 4 4 83.80 1.46 1.1543 7 1 8 4 83.85 4.06 1.1538 -11 1 2 4 83.95 1.28 1.1527 2 0 12 2 84.65 1.59 1.1449 5 3 3 4 89.05 1.10 1.0994 -7 3 1 4 89.19 1.91 1.0980 10 2 0 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.