Cannizzarite Topa D, Makovicky E, Dittrich H The Canadian Mineralogist 48 (2010) 483-495 The crystal structure of 7H:12Q cannizzarite from Vulcano, Italy Locality: Vulcano, Italy _database_code_amcsd 0006281 38.86 4.090 39.83 90 102.30 90 P2_1/m atom x y z occ Uiso U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3) PbMe1 .0318 .75 .2191 .023 .018 .020 .027 0 -.002 0 PbMe2 .0098 .25 .3147 .027 .042 .020 .016 0 -.001 0 BiMe3 .1050 .75 .3093 .020 .021 .017 .020 0 .001 0 BiMe4 .1027 .25 .3970 .020 .024 .027 .008 0 .001 0 PbMe5 .1962 .75 .3929 .028 .033 .029 .024 0 .010 0 PbMe6 .1749 .25 .4883 .030 .025 .032 .035 0 .012 0 BiMe7 .2681 .75 .4830 .025 .017 .027 .030 0 .005 0 PbMe8 .2633 .25 .5737 .031 .031 .028 .034 0 .004 0 PbMe9 .3643 .75 .5541 .034 .046 .034 .019 0 .002 0 BiMe10 .3508 .25 .6447 .030 .047 .023 .019 0 .004 0 PbMe11 .4450 .75 .6420 .5 .035 .043 .031 .026 0 -.002 0 BiMe11 .4450 .75 .6420 .5 .035 .043 .031 .026 0 -.002 0 PbMe12 .4252 .25 .7344 .026 .026 .027 .018 0 -.011 0 PbMe13 .4751 .25 .2800 .5 .031 .027 .025 .033 0 -.011 0 BiMe13 .4751 .25 .2800 .5 .031 .027 .025 .033 0 -.011 0 BiMe14 .4793 .75 .1903 .022 .023 .018 .026 0 .007 0 PbMe15 .3869 .25 .1963 .026 .016 .024 .037 0 .002 0 PbMe16 .4070 .75 .1001 .027 .031 .017 .031 0 .004 0 BiMe17 .3134 .25 .1056 .020 .017 .013 .030 0 .003 0 BiMe18 .3158 .75 .0172 .027 .030 .011 .037 0 .002 0 PbMe19 .2195 .25 .0253 .028 .037 .019 .031 0 .014 0 PbMe20 .2410 .75 .9318 .021 .015 .013 .033 0 -.001 0 BiMe21 .1474 .25 .9349 .019 .020 .010 .027 0 .005 0 PbMe22 .1566 .75 .8439 .027 .028 .016 .035 0 .001 0 PbMe23 .0550 .25 .8664 .023 .032 .017 .015 0 -.010 0 BiMe24 .0617 .75 .7755 .020 .020 .019 .018 0 -.002 0 PbMe25 .0415 .25 .9811 .014 .011 .006 .021 0 -.007 0 BiMe26 .0304 .25 .0867 .014 .010 .012 .015 0 -.007 0 BiMe27 .1176 .75 .0504 .014 .013 .006 .018 0 -.008 0 PbMe28 .1036 .75 .1552 .5 .018 .016 .007 .025 0 -.011 0 BiMe28 .1036 .75 .1552 .5 .018 .016 .007 .025 0 -.011 0 PbMe29 .1869 .25 .1244 .5 .015 .016 .008 .019 0 -.001 0 BiMe29 .1869 .25 .1244 .5 .015 .016 .008 .019 0 -.001 0 PbMe30 .1701 .25 .2290 .5 .020 .016 .011 .029 0 -.004 0 BiMe30 .1701 .25 .2290 .5 .020 .016 .011 .029 0 -.004 0 PbMe31 .2593 .75 .1974 .5 .016 .021 .008 .016 0 -.002 0 BiMe31 .2593 .75 .1974 .5 .016 .021 .008 .016 0 -.002 0 PbMe32 .2406 .75 .3019 .017 .012 .016 .018 0 -.004 0 BiMe33 .3253 .25 .2724 .017 .011 .011 .024 0 -.005 0 PbMe34 .3089 .25 .3767 .5 .014 .005 .019 .013 0 -.008 0 BiMe34 .3089 .25 .3767 .5 .014 .005 .019 .013 0 -.008 0 PbMe35 .3969 .75 .3424 .016 .009 .019 .015 0 -.006 0 PbMe36 .3847 .75 .4474 .5 .016 .019 .022 .005 0 .002 0 BiMe36 .3847 .75 .4474 .5 .016 .019 .022 .005 0 .002 0 PbMe37 .4679 .25 .4122 .019 .015 .016 .021 0 -.007 0 BiMe38 .4567 .25 .5173 .017 .013 .028 .006 0 -.006 0 BiMe39 .4572 .75 .0147 .020 .022 .015 .022 0 .006 0 BiMe40 .4751 .75 .9101 .024 .029 .015 .025 0 .001 0 PbMe41 .3868 .25 .9428 .5 .021 .025 .017 .024 0 .008 0 BiMe41 .3868 .25 .9428 .5 .021 .025 .017 .024 0 .008 0 PbMe42 .4012 .25 .8375 .5 .023 .024 .018 .026 0 -.001 0 BiMe42 .4012 .25 .8375 .5 .023 .024 .018 .026 0 -.001 0 PbMe43 .3180 .75 .8708 .5 .019 .025 .019 .015 0 .009 0 BiMe43 .3180 .75 .8708 .5 .019 .025 .019 .015 0 .009 0 BiMe44 .3301 .75 .7655 .022 .027 .016 .024 0 .009 0 BiMe45 .2443 .25 .8012 .020 .020 .019 .027 0 .005 0 PbMe46 .2545 .25 .6940 .5 .024 .032 .028 .014 0 .007 0 BiMe46 .2545 .25 .6940 .5 .024 .032 .028 .014 0 .007 0 PbMe47 .1720 .75 .7329 .028 .024 .028 .031 0 .001 0 BiMe48 .1827 .75 .6275 .027 .025 .031 .027 0 .006 0 BiMe49 .0951 .25 .6638 .030 .031 .028 .037 0 .016 0 BiMe50 .1098 .25 .5594 .024 .026 .038 .013 0 .013 0 PbMe51 .0261 .75 .5893 .032 .030 .039 .027 0 .009 0 BiMe52 .0448 .75 .4855 .032 .033 .042 .024 0 .012 0 S1 .0616 .25 .2743 .041 S2 .0624 .75 .3544 .013 S3 .1465 .25 .3532 .017 S4 .1460 .75 .4334 .000 S5 .2260 .25 .4450 .019 S6 .2243 .75 .5250 .020 S7 .3067 .25 .5241 .021 S8 .3178 .75 .5999 .008 S9 .3969 .25 .6044 .013 S10 .3958 .75 .6831 .015 S11 .4751 .25 .6912 .036 S12 .5175 .25 .2343 .009 S13 .4351 .75 .2332 .004 S14 .4365 .25 .1543 .018 S15 .3564 .75 .1430 .015 S16 .3578 .25 .0608 .008 S17 .2736 .75 .0645 .013 S18 .2720 .25 .9862 .023 S19 .1924 .75 .9734 .000 S20 .1956 .25 .8945 .000 S21 .1138 .75 .8923 .014 S22 .0988 .25 .8173 .020 S23 .0192 .75 .8194 .002 S24 .9833 .75 .2601 .020 S25 .0398 .75 .9300 .57 .024 Se25 .0398 .75 .9300 .43 .024 S26 .0359 .75 .0338 .020 S27 .0291 .75 .1336 .86 .014 Se27 .0291 .75 .1336 .14 .014 S28 .1193 .25 .0029 .69 .020 Se28 .1193 .25 .0029 .31 .020 S29 .1126 .25 .1014 .008 S30 .0965 .25 .2016 .62 .022 Se30 .0965 .25 .2016 .38 .022 S31 .1876 .75 .0742 .77 .027 Se31 .1876 .75 .0742 .23 .027 S32 .1793 .75 .1765 .013 S33 .1668 .75 .2745 .90 .016 Se33 .1668 .75 .2745 .10 .016 S34 .2624 .25 .1523 .012 S35 .2479 .25 .2497 .005 S36 .2367 .25 .3512 .73 .023 Se36 .2367 .25 .3512 .27 .023 S37 .3303 .75 .2251 .67 .025 Se37 .3303 .75 .2251 .33 .025 S38 .3160 .75 .3239 .008 S39 .3085 .75 .4246 .76 .025 Se39 .3085 .75 .4246 .24 .025 S40 .3971 .25 .2946 .001 S41 .3893 .25 .3946 .89 .021 Se41 .3893 .25 .3946 .11 .021 S42 .3858 .25 .4976 .006 S43 .4719 .75 .3637 .44 .031 Se43 .4719 .75 .3637 .56 .031 S44 .4606 .75 .4665 .007 S45 .4546 .75 .5645 .015 S46 .4546 .25 .0622 .003 S47 .4637 .25 .9639 .022 S48 .4772 .25 .8628 .023 S49 .3859 .75 .9904 .009 S50 .3960 .75 .8891 .031 S51 .4001 .75 .7877 .009 S52 .3134 .25 .9189 .82 .012 Se52 .3134 .25 .9189 .18 .012 S53 .3238 .25 .8201 .029 S54 .3307 .25 .7193 .007 S55 .2444 .75 .8478 .004 S56 .2481 .75 .7461 .019 S57 .2554 .75 .6449 .004 S58 .1728 .25 .7844 .031 S59 .1770 .25 .6795 .026 S60 .1820 .25 .5802 .78 .034 Se60 .1820 .25 .5802 .22 .034 S61 .0928 .75 .7101 .89 .015 Se61 .0928 .75 .7101 .11 .015 S62 .1058 .75 .6107 .041 S63 .1157 .75 .5157 .015 S64 .0271 .25 .6402 .035 S65 .0315 .25 .5394 .057 S66 .0485 .25 .4401 .026