U4Cs2Se5O25 Wylie E M, Burns P C The Canadian Mineralogist 50 (2012) 147-157 Crystal structures of six new uranyl selenate and selenite compounds and their relationship with uranyl mineral structures Note: Compound 6 Locality: synthetic _database_code_amcsd 0019090 CELL PARAMETERS: 10.9130 12.4270 18.4480 90.000 90.393 90.000 SPACE GROUP: P2_1/n X-RAY WAVELENGTH: 1.541838 Cell Volume: 2501.782 Density (g/cm3): 5.365 MAX. ABS. INTENSITY / VOLUME**2: 43.24606282 RIR: 2.625 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 8.58 41.82 10.3066 0 1 1 4 9.44 11.26 9.3643 1 0 1 2 9.59 1.14 9.2238 0 0 2 2 14.25 100.00 6.2135 0 2 0 2 14.42 3.08 6.1441 -1 1 2 4 14.49 7.02 6.1127 1 1 2 4 15.05 15.93 5.8885 0 2 1 4 16.24 3.96 5.4564 2 0 0 2 16.42 15.95 5.3996 1 2 0 4 16.50 2.24 5.3730 -1 0 3 2 16.60 3.06 5.3416 1 0 3 2 17.13 9.11 5.1774 1 2 1 4 17.21 2.06 5.1533 0 2 2 4 17.75 17.48 4.9960 2 1 0 4 17.99 16.20 4.9318 -1 1 3 4 18.08 21.03 4.9074 1 1 3 4 18.43 11.15 4.8147 2 1 1 4 18.84 2.22 4.7104 -2 0 2 2 18.95 18.46 4.6822 2 0 2 2 19.02 8.35 4.6668 -1 2 2 4 19.07 1.99 4.6530 1 2 2 4 19.25 6.75 4.6119 0 0 4 2 20.16 14.42 4.4046 -2 1 2 4 20.27 7.17 4.3815 2 1 2 4 20.32 2.37 4.3707 0 2 3 4 21.68 12.18 4.0999 2 2 0 4 21.87 1.93 4.0642 -1 2 3 4 21.94 8.60 4.0506 1 2 3 4 21.99 98.21 4.0417 0 3 1 4 22.06 1.35 4.0286 -1 1 4 4 22.16 1.55 4.0109 1 1 4 4 22.19 14.72 4.0067 -2 2 1 4 22.86 10.37 3.8895 -2 1 3 4 22.96 1.44 3.8727 1 3 0 4 23.01 4.49 3.8657 2 1 3 4 23.46 5.94 3.7920 -1 3 1 4 23.54 50.35 3.7788 0 3 2 4 23.70 11.94 3.7537 -2 2 2 4 23.80 4.78 3.7394 2 2 2 4 24.03 47.31 3.7033 0 2 4 4 24.91 1.63 3.5739 -1 3 2 4 24.92 3.52 3.5735 -3 0 1 2 24.96 1.71 3.5677 1 3 2 4 24.98 6.67 3.5642 3 0 1 2 25.18 21.34 3.5369 0 1 5 4 25.20 8.69 3.5342 -2 0 4 2 25.36 1.10 3.5127 -1 2 4 4 25.43 14.07 3.5025 -1 0 5 2 25.51 7.74 3.4911 3 1 0 4 26.01 2.88 3.4261 3 1 1 4 26.22 17.57 3.3994 -2 1 4 4 26.38 8.65 3.3782 2 1 4 4 26.44 8.78 3.3711 -1 1 5 4 26.54 3.99 3.3581 1 1 5 4 27.03 6.34 3.2993 2 3 0 4 27.24 6.34 3.2734 1 3 3 4 27.38 6.75 3.2580 3 1 2 4 27.48 1.12 3.2454 2 3 1 4 28.13 9.56 3.1724 0 2 5 4 28.42 4.90 3.1403 -3 0 3 2 28.43 6.34 3.1392 3 2 0 4 28.60 44.93 3.1214 3 0 3 2 28.70 9.14 3.1106 -2 3 2 4 28.74 3.01 3.1068 0 4 0 2 28.78 4.98 3.1025 2 3 2 4 28.82 45.11 3.0977 -3 2 1 4 28.97 18.49 3.0818 0 3 4 4 29.04 37.19 3.0746 0 0 6 2 29.34 64.78 3.0446 -3 1 3 4 29.37 7.70 3.0415 1 2 5 4 29.51 40.88 3.0274 3 1 3 4 29.94 15.68 2.9846 0 1 6 4 30.01 10.03 2.9772 -3 2 2 4 30.02 3.04 2.9769 -2 1 5 4 30.10 4.19 2.9693 -1 3 4 4 30.13 7.34 2.9664 3 2 2 4 30.29 3.07 2.9505 -1 4 1 4 30.31 8.77 2.9487 1 4 1 4 30.81 3.26 2.9022 2 3 3 4 31.01 1.08 2.8838 -1 1 6 4 31.12 1.15 2.8740 1 1 6 4 31.45 2.81 2.8442 -1 4 2 4 31.49 1.07 2.8410 1 4 2 4 32.05 2.74 2.7924 -3 1 4 4 32.09 3.67 2.7893 3 2 3 4 32.26 3.41 2.7747 3 1 4 4 32.49 15.42 2.7557 0 2 6 4 32.50 12.30 2.7551 0 3 5 4 32.74 6.75 2.7355 2 2 5 4 33.16 2.34 2.7018 3 3 1 4 33.31 2.31 2.6895 -1 4 3 4 33.33 5.33 2.6886 -2 3 4 4 33.35 1.25 2.6865 -2 0 6 2 33.36 1.54 2.6855 1 4 3 4 33.49 2.02 2.6757 -1 2 6 4 33.56 1.77 2.6700 2 4 1 4 33.59 4.73 2.6681 1 3 5 4 34.15 2.11 2.6258 -2 1 6 4 34.21 13.08 2.6210 -4 0 2 2 34.27 19.82 2.6170 3 3 2 4 34.34 1.64 2.6113 4 0 2 2 34.34 3.38 2.6112 2 1 6 4 34.47 3.93 2.6022 -3 2 4 4 34.51 5.36 2.5993 -3 0 5 2 34.65 1.28 2.5887 2 4 2 4 34.75 1.31 2.5815 3 0 5 2 34.97 1.11 2.5657 -1 0 7 2 35.08 1.32 2.5577 1 0 7 2 35.28 2.81 2.5442 -3 1 5 4 35.52 4.48 2.5275 3 1 5 4 35.73 1.11 2.5127 -1 1 7 4 35.84 12.47 2.5052 1 1 7 4 36.03 2.55 2.4929 3 3 3 4 36.30 4.08 2.4751 -2 4 3 4 36.39 4.15 2.4689 2 4 3 4 36.39 1.68 2.4688 0 3 6 4 36.44 2.04 2.4659 -2 2 6 4 36.48 3.27 2.4631 0 5 1 4 37.35 1.23 2.4073 4 2 2 4 37.39 1.67 2.4051 1 3 6 4 37.44 6.12 2.4022 1 5 1 4 37.48 2.73 2.3998 0 5 2 4 37.51 1.45 2.3979 -3 2 5 4 37.74 3.30 2.3839 3 2 5 4 37.86 2.13 2.3765 0 4 5 4 38.05 2.37 2.3652 1 2 7 4 38.19 5.77 2.3567 -3 3 4 4 38.37 7.95 2.3461 3 3 4 4 38.39 9.12 2.3446 -3 4 1 4 38.44 9.66 2.3420 3 4 1 4 38.58 1.18 2.3334 -2 4 4 4 39.09 8.39 2.3043 0 5 3 4 39.17 3.08 2.2998 3 1 6 4 39.33 7.05 2.2910 -3 4 2 4 40.17 5.71 2.2447 2 3 6 4 40.57 4.93 2.2235 0 3 7 4 40.60 3.31 2.2221 -2 2 7 4 40.80 3.46 2.2117 2 2 7 4 40.99 3.22 2.2020 3 4 3 4 41.06 2.02 2.1982 -2 5 2 4 41.12 4.44 2.1953 2 5 2 4 41.20 1.88 2.1909 3 3 5 4 41.22 5.74 2.1901 3 2 6 4 41.26 3.72 2.1879 0 5 4 4 41.37 5.14 2.1823 -2 4 5 4 41.40 4.57 2.1812 -1 3 7 4 41.49 2.34 2.1763 1 3 7 4 41.51 2.22 2.1753 2 4 5 4 41.64 1.47 2.1692 -5 0 1 2 41.71 1.20 2.1657 5 0 1 2 42.03 1.91 2.1496 5 1 0 4 42.09 1.13 2.1466 -1 5 4 4 42.22 5.43 2.1405 -4 3 3 4 42.30 10.59 2.1369 -5 1 1 4 42.36 9.97 2.1335 5 1 1 4 42.45 1.46 2.1293 -2 0 8 2 42.50 3.31 2.1272 3 0 7 2 42.58 2.34 2.1233 -1 2 8 4 42.67 1.84 2.1188 2 0 8 2 42.69 1.00 2.1181 1 2 8 4 42.86 11.95 2.1100 -3 1 7 4 42.94 1.57 2.1064 -3 4 4 4 43.10 1.48 2.0988 3 4 4 4 43.10 9.38 2.0987 -2 1 8 4 43.14 1.09 2.0967 3 1 7 4 43.32 1.54 2.0887 2 1 8 4 43.92 8.58 2.0613 0 5 5 4 43.97 4.37 2.0592 5 2 0 4 43.99 11.70 2.0582 0 6 1 4 44.13 3.04 2.0521 3 5 0 4 44.23 1.60 2.0480 -5 2 1 4 44.24 3.27 2.0474 -4 3 4 4 44.46 1.47 2.0376 3 3 6 4 44.53 1.34 2.0348 1 6 0 4 44.57 6.33 2.0330 -2 5 4 4 44.67 1.67 2.0285 2 5 4 4 44.71 1.79 2.0269 -1 5 5 4 44.75 3.31 2.0253 2 4 6 4 44.77 1.73 2.0243 -3 2 7 4 44.80 5.16 2.0229 -1 6 1 4 44.85 2.68 2.0208 0 6 2 4 45.05 4.17 2.0125 3 2 7 4 45.06 1.17 2.0120 1 0 9 2 45.11 2.49 2.0097 0 4 7 4 45.21 2.43 2.0055 2 2 8 4 45.23 7.04 2.0048 -3 5 2 4 45.69 3.54 1.9855 3 4 5 4 45.74 1.81 1.9834 -1 3 8 4 46.49 1.72 1.9534 -5 1 4 4 46.60 1.81 1.9488 5 2 3 4 46.66 1.77 1.9465 0 2 9 4 46.71 3.70 1.9448 -4 2 6 4 47.01 2.02 1.9329 0 5 6 4 47.02 1.81 1.9326 -1 6 3 4 47.06 1.20 1.9311 1 6 3 4 47.06 1.30 1.9309 5 3 0 4 47.18 2.38 1.9263 -2 6 1 4 47.21 8.34 1.9253 2 6 1 4 47.30 1.48 1.9216 -5 3 1 4 47.37 2.74 1.9192 5 3 1 4 47.39 3.94 1.9183 3 1 8 4 47.50 1.56 1.9141 1 2 9 4 47.82 1.19 1.9021 -3 3 7 4 47.83 2.03 1.9018 1 5 6 4 48.04 10.96 1.8938 -2 3 8 4 48.08 2.55 1.8923 3 3 7 4 48.09 1.36 1.8922 2 1 9 4 48.17 3.45 1.8891 -2 4 7 4 48.21 1.63 1.8877 5 3 2 4 48.29 1.01 1.8848 -5 2 4 4 48.42 1.77 1.8801 -4 1 7 4 48.61 1.72 1.8729 5 0 5 2 48.63 6.41 1.8722 3 5 4 4 48.87 5.39 1.8637 -3 2 8 4 48.89 7.26 1.8629 -5 1 5 4 48.95 3.48 1.8608 1 6 4 4 49.20 7.95 1.8519 5 1 5 4 49.30 5.69 1.8482 -2 6 3 4 49.40 3.67 1.8448 0 0 10 2 49.57 2.64 1.8390 5 3 3 4 49.96 3.28 1.8256 4 3 6 4 49.98 3.09 1.8248 0 1 10 4 50.01 3.89 1.8239 1 4 8 4 50.14 2.65 1.8195 2 5 6 4 50.16 2.83 1.8188 6 0 0 2 50.16 1.05 1.8187 -4 2 7 4 50.32 2.08 1.8135 -1 3 9 4 50.54 1.16 1.8061 0 6 5 4 50.63 2.66 1.8031 -5 2 5 4 50.66 3.15 1.8018 -1 1 10 4 50.71 1.33 1.8003 4 5 2 4 50.72 1.44 1.7999 3 6 0 4 50.73 2.54 1.7996 6 1 0 4 50.96 2.46 1.7919 -3 6 1 4 51.00 2.75 1.7908 3 6 1 4 51.12 4.81 1.7868 -6 0 2 2 51.15 5.05 1.7859 5 4 0 4 51.25 2.45 1.7825 1 5 7 4 51.26 1.91 1.7821 6 0 2 2 51.31 3.57 1.7805 3 0 9 2 51.37 3.78 1.7785 -5 4 1 4 51.41 1.15 1.7773 5 3 4 4 51.56 2.85 1.7727 -3 1 9 4 51.69 3.59 1.7685 0 2 10 4 51.73 1.84 1.7671 0 7 1 4 51.73 2.85 1.7671 -4 0 8 2 51.78 2.66 1.7654 3 6 2 4 51.83 1.03 1.7641 6 1 2 4 51.86 5.10 1.7630 -3 4 7 4 52.02 3.52 1.7580 3 3 8 4 52.11 2.34 1.7552 3 4 7 4 52.11 2.33 1.7552 -5 4 2 4 52.24 3.46 1.7512 -2 0 10 2 52.29 3.09 1.7495 -4 1 8 4 52.42 1.87 1.7455 6 2 0 4 52.64 3.87 1.7389 -6 2 1 4 52.66 1.25 1.7380 4 1 8 4 52.91 1.27 1.7303 -6 1 3 4 52.98 1.14 1.7285 -4 3 7 4 53.02 4.66 1.7270 2 1 10 4 53.12 4.00 1.7240 6 1 3 4 53.22 2.30 1.7211 1 7 2 4 53.35 2.07 1.7172 -6 2 2 4 53.38 1.19 1.7163 -2 6 5 4 53.42 3.24 1.7151 -5 3 5 4 53.46 2.60 1.7139 2 5 7 4 53.49 4.49 1.7130 6 2 2 4 53.50 1.07 1.7129 2 6 5 4 53.54 6.34 1.7116 3 2 9 4 53.60 1.35 1.7099 -3 5 6 4 53.61 1.46 1.7096 -4 5 4 4 53.71 2.39 1.7065 5 3 5 4 53.74 1.48 1.7058 5 2 6 4 53.74 2.23 1.7056 0 7 3 4 53.80 1.17 1.7038 3 5 6 4 54.01 1.94 1.6979 -1 6 6 4 54.08 4.01 1.6959 1 6 6 4 54.22 1.18 1.6917 -1 4 9 4 54.32 1.32 1.6888 1 4 9 4 54.62 1.07 1.6804 -6 1 4 4 54.80 1.12 1.6753 5 0 7 2 55.09 1.44 1.6670 -1 3 10 4 55.20 2.43 1.6639 1 3 10 4 55.26 2.59 1.6623 5 4 4 4 55.37 2.25 1.6593 -1 0 11 2 55.57 2.46 1.6538 -3 4 8 4 55.94 1.36 1.6437 -4 6 1 4 56.05 1.02 1.6406 -6 3 2 4 56.13 1.94 1.6386 -1 7 4 4 56.19 2.84 1.6370 6 3 2 4 56.51 2.64 1.6284 0 6 7 4 56.75 1.04 1.6221 -4 4 7 4 56.76 1.50 1.6218 -6 1 5 4 57.22 2.26 1.6100 -6 3 3 4 57.42 1.77 1.6049 6 3 3 4 57.49 1.19 1.6031 -1 2 11 4 57.62 1.64 1.5997 0 7 5 4 57.79 1.16 1.5954 3 7 0 4 57.81 1.08 1.5950 -4 6 3 4 58.01 1.07 1.5899 -3 7 1 4 58.16 1.47 1.5862 0 4 10 4 58.35 1.79 1.5813 0 5 9 4 58.39 1.22 1.5804 -4 5 6 4 58.65 1.56 1.5740 4 5 6 4 58.66 2.20 1.5739 6 2 5 4 58.70 2.91 1.5729 -3 7 2 4 58.84 2.35 1.5695 -6 3 4 4 58.98 2.10 1.5662 -1 5 9 4 59.10 1.09 1.5632 6 3 4 4 59.10 1.90 1.5632 6 4 1 4 59.14 1.32 1.5622 -2 6 7 4 59.29 1.93 1.5586 2 6 7 4 59.42 1.09 1.5556 -3 6 6 4 59.46 2.00 1.5545 0 3 11 4 59.54 1.48 1.5525 7 0 1 2 59.68 1.35 1.5494 2 2 11 4 59.71 2.21 1.5486 6 1 6 4 59.87 1.51 1.5448 3 4 9 4 60.06 2.68 1.5405 5 4 6 4 60.18 3.04 1.5376 1 3 11 4 60.34 1.18 1.5339 2 7 5 4 60.43 3.03 1.5318 0 8 2 4 60.51 2.30 1.5301 3 5 8 4 60.59 1.97 1.5282 -4 3 9 4 60.71 1.29 1.5254 3 3 10 4 60.88 1.40 1.5215 -4 1 10 4 61.10 1.06 1.5167 1 8 2 4 61.31 1.37 1.5120 4 1 10 4 61.38 1.67 1.5104 -4 5 7 4 61.56 4.86 1.5064 3 7 4 4 61.75 1.32 1.5024 5 6 0 4 61.97 1.23 1.4975 -2 3 11 4 62.00 1.30 1.4968 5 6 1 4 62.13 2.55 1.4940 2 8 0 4 62.24 1.52 1.4916 1 8 3 4 62.37 3.87 1.4889 2 8 1 4 62.39 1.46 1.4885 -5 1 9 4 62.65 1.07 1.4829 -3 2 11 4 62.68 1.09 1.4823 -5 4 7 4 62.70 4.33 1.4817 5 6 2 4 62.73 2.16 1.4811 -2 7 6 4 62.81 1.47 1.4795 4 2 10 4 62.97 1.03 1.4760 5 3 8 4 62.98 1.14 1.4758 0 4 11 4 63.17 2.41 1.4719 -2 1 12 4 63.23 2.51 1.4706 -7 2 3 4 63.45 2.05 1.4660 -3 7 5 4 63.61 2.84 1.4628 3 7 5 4 63.72 1.56 1.4605 6 3 6 4 63.75 1.06 1.4599 -1 7 7 4 63.76 1.47 1.4597 -6 2 7 4 63.79 1.66 1.4591 7 3 0 4 64.12 1.23 1.4524 -2 8 3 4 64.20 1.60 1.4508 -6 5 2 4 64.23 1.78 1.4501 -5 5 6 4 64.32 1.83 1.4483 6 5 2 4 64.58 1.16 1.4432 1 6 9 4 64.73 1.81 1.4402 -4 5 8 4 65.22 2.32 1.4305 -5 6 4 4 65.24 2.10 1.4300 -7 1 5 4 65.43 3.60 1.4265 5 6 4 4 65.59 2.33 1.4233 6 0 8 2 65.87 2.11 1.4179 -3 7 6 4 66.33 4.75 1.4093 -2 6 9 4 66.50 1.10 1.4060 1 0 13 2 66.62 1.04 1.4038 6 3 7 4 66.76 3.35 1.4013 5 3 9 4 66.78 1.94 1.4009 -6 5 4 4 66.98 1.31 1.3971 1 1 13 4 67.02 2.41 1.3964 6 5 4 4 67.06 1.55 1.3957 4 6 7 4 67.51 1.19 1.3874 6 2 8 4 67.61 2.23 1.3857 -2 8 5 4 67.92 2.96 1.3800 -1 5 11 4 68.10 1.12 1.3769 0 9 1 4 68.21 1.06 1.3749 1 8 6 4 68.27 1.20 1.3738 -5 7 1 4 68.28 1.68 1.3736 -1 2 13 4 68.53 2.52 1.3693 3 5 10 4 68.73 1.16 1.3658 1 6 10 4 68.89 1.86 1.3630 -5 7 2 4 68.92 1.29 1.3624 6 6 1 4 69.60 1.04 1.3509 6 6 2 4 69.60 1.17 1.3508 -8 0 2 2 69.78 1.05 1.3478 6 1 9 4 69.89 2.42 1.3458 -7 0 7 2 70.08 1.43 1.3428 2 8 6 4 70.13 1.78 1.3419 0 7 9 4 70.33 2.38 1.3386 2 9 0 4 70.43 1.46 1.3370 3 3 12 4 70.48 1.20 1.3361 -7 4 4 4 70.61 3.04 1.3340 2 4 12 4 70.78 1.18 1.3312 1 7 9 4 71.01 1.18 1.3274 -6 5 6 4 71.38 1.86 1.3214 -7 3 6 4 71.47 1.57 1.3199 -8 2 2 4 71.53 1.50 1.3190 3 0 13 2 71.62 1.26 1.3176 -3 1 13 4 71.63 1.18 1.3174 8 2 2 4 71.91 1.62 1.3129 -4 2 12 4 72.45 1.38 1.3045 -5 2 11 4 72.45 1.15 1.3045 -2 7 9 4 73.19 2.10 1.2932 0 9 5 4 73.51 1.14 1.2883 0 8 8 4 73.56 1.60 1.2875 3 9 1 4 73.81 1.94 1.2838 1 9 5 4 74.10 1.01 1.2795 5 4 10 4 74.14 1.27 1.2789 -3 9 2 4 74.25 1.37 1.2773 5 5 9 4 75.02 1.70 1.2661 8 3 3 4 75.52 1.57 1.2589 -5 7 6 4 75.60 1.33 1.2579 -2 4 13 4 75.72 1.39 1.2561 5 6 8 4 76.50 1.16 1.2452 8 3 4 4 76.71 1.18 1.2423 3 9 4 4 77.40 1.24 1.2329 -4 4 12 4 77.51 1.72 1.2316 0 10 2 4 77.93 1.42 1.2260 -5 4 11 4 77.94 2.50 1.2258 1 6 12 4 77.97 1.05 1.2254 -2 3 14 4 78.43 1.24 1.2194 -3 9 5 4 79.44 1.24 1.2064 0 2 15 4 80.57 1.20 1.1923 -7 3 9 4 80.88 1.27 1.1885 2 7 11 4 81.11 1.52 1.1858 -2 4 14 4 81.11 1.12 1.1857 -9 1 3 4 82.83 2.85 1.1654 8 1 8 4 83.10 1.40 1.1622 5 6 10 4 84.37 1.25 1.1480 0 1 16 4 84.44 1.45 1.1472 -5 9 3 4 84.58 3.14 1.1456 5 9 3 4 85.34 1.51 1.1374 -8 6 1 4 86.24 1.21 1.1279 -9 4 1 4 86.81 1.07 1.1219 2 1 16 4 87.47 1.26 1.1151 -4 7 11 4 88.25 1.09 1.1073 7 5 9 4 89.15 1.11 1.0984 -7 6 8 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.