data_global
_chemical_name_mineral 'Billwiseite'
loop_
_publ_author_name
'Hawthorne F C'
'Cooper M A'
'Ball N A'
'Abdu Y A'
'Cerny P'
'Camara F'
'Laurs B M'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 50 
_journal_year 2012
_journal_page_first 805
_journal_page_last 814
_publ_section_title
;
 Billwiseite, ideally Sb3+5(Nb,Ta)3WO18, a new oxide mineral species
 from the Stak Nala Pegmatite, Nanga Parbat - Haramosh Massif, Pakistan:
 description and crystal structure
;
_database_code_amcsd 0019765
_chemical_compound_source 'the Stak Nala Pegmatite, Nanga Parbat - Haramosh Massif, Pakistan'
_chemical_formula_sum 'Sb5 (Nb1.32 Ta1.28 Ti.16 W1.24) O18'
_cell_length_a 54.116
_cell_length_b 4.9143
_cell_length_c 5.5482
_cell_angle_alpha 90
_cell_angle_beta 90.425
_cell_angle_gamma 90
_cell_volume 1475.460
_exptl_crystal_density_diffrn      6.692
_symmetry_space_group_name_H-M 'C 1 2/c 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
  '-x,y,1/2-z'
  '1/2-x,1/2+y,1/2-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Sb1   0.00000   0.19830   0.75000   1.00000   0.01390
Sb2   0.22152  -0.20656   0.32554   1.00000   0.01320
Sb3   0.10997   0.29999   0.72606   1.00000   0.01290
NbM1   0.05480   0.25442   0.13172   0.33000   0.00840
TaM1   0.05480   0.25442   0.13172   0.32000   0.00840
TiM1   0.05480   0.25442   0.13172   0.04000   0.00840
WM1   0.05480   0.25442   0.13172   0.31000   0.00840
NbM2   0.16463   0.23919   0.37332   0.33000   0.00750
TaM2   0.16463   0.23919   0.37332   0.32000   0.00750
TiM2   0.16463   0.23919   0.37332   0.04000   0.00750
WM2   0.16463   0.23919   0.37332   0.31000   0.00750
O1   0.12890   0.41300   0.40890   1.00000   0.01200
O2   0.02086   0.08700   0.08670   1.00000   0.01100
O3   0.06472   0.01300   0.36650   1.00000   0.01300
O4   0.23860   0.06800   0.12630   1.00000   0.01200
O5   0.08747   0.41300   0.07940   1.00000   0.01000
O6   0.15095   0.03560   0.66760   1.00000   0.01100
O7   0.19594   0.08500   0.42440   1.00000   0.01300
O8   0.17287   0.52100   0.63110   1.00000   0.01600
O9   0.04268   0.47700   0.83720   1.00000   0.01300
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Sb1 0.01150 0.00870 0.02140 0.00000 0.00620 0.00000
Sb2 0.01610 0.01030 0.01330 -0.00560 0.00350 -0.00120
Sb3 0.01260 0.00960 0.01630 -0.00350 -0.00490 0.00140
NbM1 0.00600 0.00740 0.01160 -0.00060 0.00030 -0.00030
TaM1 0.00600 0.00740 0.01160 -0.00060 0.00030 -0.00030
TiM1 0.00600 0.00740 0.01160 -0.00060 0.00030 -0.00030
WM1 0.00600 0.00740 0.01160 -0.00060 0.00030 -0.00030
NbM2 0.00620 0.00690 0.00930 0.00070 -0.00038 0.00030
TaM2 0.00620 0.00690 0.00930 0.00070 -0.00038 0.00030
TiM2 0.00620 0.00690 0.00930 0.00070 -0.00038 0.00030
WM2 0.00620 0.00690 0.00930 0.00070 -0.00038 0.00030
O1 0.00200 0.01300 0.02000 0.00100 -0.00200 0.00100
O2 0.00500 0.01400 0.01500 -0.00200 -0.00200 -0.00200
O3 0.00800 0.01300 0.01700 0.00000 0.00200 0.01000
O4 0.00500 0.01700 0.01300 -0.00600 -0.00400 0.00100
O5 0.00600 0.00800 0.01500 -0.00500 0.00200 0.00200
O6 0.01100 0.00600 0.01700 0.00000 -0.00300 0.00200
O7 0.01200 0.01200 0.01500 0.00100 0.00100 -0.00200
O8 0.01200 0.01600 0.02000 0.00000 -0.00200 -0.00600
O9 0.00800 0.01700 0.01500 0.00200 -0.00200 0.00700