Protochabourneite Orlandi P, Biagioni C, Moelo Y, Bonaccorsi E, Paar W H The Canadian Mineralogist 51 (2013) 475-494 Lead-antimony sulfosalts from Tuscany (Italy). XIII. Protochabourneite, ~Tl2Pb(Sb9-8As1-2)S10S17, from the Monte Arsiccio mine: occurrence, crystal structure, and relationship with chabourneite Locality: Monte Arsiccio mine, Apuan Alps, Tuscany, Italy _database_code_amcsd 0020049 CELL PARAMETERS: 8.1500 8.7160 21.5790 85.180 96.940 88.600 SPACE GROUP: P-1 X-RAY WAVELENGTH: 1.541838 Cell Volume: 1515.333 Density (g/cm3): 5.178 MAX. ABS. INTENSITY / VOLUME**2: 16.33599474 RIR: 1.027 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 4.14 2.07 21.3385 0 0 1 2 8.29 6.28 10.6692 0 0 2 2 10.19 2.26 8.6799 0 1 0 2 10.66 2.08 8.2980 0 1 1 2 10.94 1.74 8.0853 1 0 0 2 11.34 2.10 7.8049 0 -1 1 2 12.18 6.96 7.2695 1 0 1 2 12.44 10.54 7.1128 0 0 3 2 12.57 2.34 7.0421 0 1 2 2 14.54 30.41 6.0924 1 0 2 2 14.71 2.85 6.0222 1 1 0 2 15.16 1.09 5.8434 -1 -1 1 2 15.23 12.64 5.8157 -1 1 0 2 15.41 3.04 5.7493 1 1 1 2 15.54 10.01 5.7005 -1 0 3 2 16.25 9.30 5.4556 -1 1 2 2 16.38 2.50 5.4122 1 -1 1 2 16.68 8.66 5.3156 -1 -1 2 2 17.59 2.96 5.0410 1 0 3 2 18.22 2.08 4.8677 -1 1 3 2 18.42 1.48 4.8166 1 -1 2 2 18.75 3.96 4.7337 0 1 4 2 19.01 10.39 4.6682 -1 -1 3 2 19.61 8.85 4.5272 1 1 3 2 20.29 6.72 4.3770 0 -1 4 2 20.46 2.21 4.3399 0 2 0 2 20.52 15.23 4.3276 0 2 1 2 20.81 15.31 4.2677 0 0 5 2 20.87 1.95 4.2563 -1 1 4 2 21.05 58.41 4.2199 1 0 4 2 21.25 32.79 4.1819 0 -2 1 2 21.42 7.77 4.1490 0 2 2 2 21.87 1.04 4.0648 -2 0 1 2 21.91 3.48 4.0562 -1 -1 4 2 21.99 24.91 4.0427 2 0 0 2 22.32 58.55 3.9824 -1 0 5 2 22.54 50.52 3.9451 -2 0 2 2 23.05 14.44 3.8582 0 2 3 2 23.22 6.44 3.8312 1 2 1 2 23.38 13.93 3.8054 -1 -2 1 2 23.60 6.06 3.7694 -1 2 0 2 23.94 5.47 3.7171 -2 0 3 2 23.96 2.92 3.7134 -1 2 2 2 24.00 4.10 3.7075 -2 -1 1 2 24.25 2.28 3.6708 1 -1 4 2 24.25 67.99 3.6697 1 2 2 2 24.35 4.04 3.6553 -2 1 1 2 24.49 31.61 3.6347 2 0 2 2 24.52 32.53 3.6297 1 -2 1 2 24.56 47.26 3.6248 -1 -2 2 2 24.62 5.35 3.6166 -2 1 0 2 24.64 2.19 3.6137 2 1 1 2 24.76 100.00 3.5955 1 0 5 2 24.81 1.00 3.5892 -2 1 2 2 24.95 36.39 3.5683 0 -2 3 2 25.20 4.36 3.5342 -1 -1 5 2 25.22 45.74 3.5316 -1 2 3 2 25.29 12.97 3.5210 0 2 4 2 25.58 1.15 3.4825 2 -1 1 2 25.94 15.77 3.4345 1 2 3 2 25.96 28.66 3.4323 -2 0 4 2 25.99 2.70 3.4284 2 1 2 2 26.10 49.80 3.4143 -1 0 6 2 26.10 28.97 3.4137 1 -2 2 2 26.21 9.42 3.4002 -2 -1 3 2 26.23 1.12 3.3970 0 1 6 2 26.37 8.65 3.3796 -1 -2 3 2 26.67 48.96 3.3420 2 0 3 2 27.08 51.54 3.2928 -1 2 4 2 27.40 1.46 3.2552 -1 1 6 2 27.93 3.08 3.1948 2 1 3 2 28.17 5.24 3.1673 1 2 4 2 28.21 4.30 3.1630 -2 -1 4 2 28.24 2.22 3.1604 1 -2 3 2 28.48 23.55 3.1343 -2 0 5 2 28.64 9.12 3.1168 1 0 6 2 28.70 28.13 3.1100 -1 -2 4 2 28.75 8.73 3.1048 -1 -1 6 2 29.30 9.84 3.0484 0 0 7 2 29.32 16.68 3.0462 2 0 4 2 29.45 27.74 3.0335 -1 2 5 2 29.67 21.93 3.0111 2 2 0 2 29.84 4.55 2.9944 -2 -2 1 2 30.03 20.10 2.9761 -1 0 7 2 30.10 1.06 2.9688 2 2 1 2 30.21 1.01 2.9583 0 1 7 2 30.41 27.62 2.9398 -2 2 1 2 30.60 20.53 2.9217 -2 -2 2 2 30.64 4.23 2.9178 0 -2 5 2 30.65 3.36 2.9167 -2 2 2 2 30.75 14.04 2.9078 -2 2 0 2 30.82 12.45 2.9011 1 -2 4 2 30.84 12.80 2.8990 1 2 5 2 31.05 4.67 2.8802 -1 1 7 2 31.08 3.43 2.8772 0 2 6 2 31.11 53.60 2.8746 2 2 2 2 31.38 16.22 2.8503 -2 0 6 2 31.45 10.33 2.8442 -1 -2 5 2 31.47 38.99 2.8424 -2 2 3 2 31.57 3.50 2.8342 0 -3 1 2 31.66 85.50 2.8260 2 -2 1 2 31.91 67.08 2.8043 -2 -2 3 2 32.33 6.96 2.7693 2 0 5 2 32.50 1.74 2.7549 1 3 0 2 32.51 18.55 2.7545 -1 -1 7 2 32.60 5.68 2.7467 1 3 1 2 32.65 6.27 2.7429 1 0 7 2 32.65 32.44 2.7424 2 2 3 2 32.77 1.12 2.7326 0 -3 2 2 32.83 36.99 2.7278 -2 2 4 2 32.99 1.60 2.7149 -1 3 1 2 33.10 21.54 2.7061 2 -2 2 2 33.24 6.59 2.6951 3 0 0 2 33.25 7.53 2.6945 1 3 2 2 33.27 13.20 2.6931 -3 0 2 2 33.35 1.23 2.6863 1 1 7 2 33.72 6.93 2.6578 -2 -2 4 2 33.76 3.62 2.6546 1 -2 5 2 34.04 16.25 2.6338 3 0 1 2 34.07 7.00 2.6314 -1 0 8 2 34.09 11.07 2.6300 -3 0 3 2 34.36 1.37 2.6099 -3 -1 1 2 34.42 6.71 2.6055 1 3 3 2 34.60 10.50 2.5925 -2 0 7 2 34.66 12.85 2.5880 2 2 4 2 34.79 4.09 2.5786 2 -1 5 2 34.85 1.97 2.5743 -3 1 1 2 35.01 1.03 2.5629 -3 1 2 2 35.02 3.70 2.5625 2 -2 3 2 35.21 4.11 2.5488 -3 1 0 2 35.62 3.07 2.5204 -2 1 7 2 35.65 1.64 2.5182 -3 -1 3 2 36.07 2.31 2.4902 1 3 4 2 36.32 3.74 2.4736 3 1 2 2 36.41 3.00 2.4673 -1 -1 8 2 36.76 22.38 2.4449 1 0 8 2 36.85 2.24 2.4388 -3 1 4 2 37.00 9.36 2.4298 1 -2 6 2 37.10 11.79 2.4232 3 0 3 2 37.15 16.59 2.4199 1 2 7 2 37.19 3.70 2.4174 -3 0 5 2 37.43 1.50 2.4029 3 -1 2 2 37.51 40.83 2.3976 0 -2 7 2 37.95 2.70 2.3709 0 0 9 2 38.02 53.65 2.3669 0 2 8 2 38.06 3.32 2.3645 -2 0 8 2 38.22 6.76 2.3549 -1 0 9 2 38.35 1.11 2.3474 0 3 6 2 38.66 2.23 2.3290 -1 2 8 2 38.71 1.49 2.3263 3 2 0 2 39.12 1.43 2.3029 0 -3 5 2 39.14 3.42 2.3013 2 0 7 2 39.27 5.68 2.2943 3 0 4 2 39.38 3.78 2.2882 -3 0 6 2 39.61 1.87 2.2753 -3 2 2 2 39.64 1.12 2.2735 2 1 7 2 39.96 1.82 2.2561 3 1 4 2 40.06 1.96 2.2510 -3 -2 3 2 40.09 1.72 2.2489 -2 -1 8 2 40.12 1.15 2.2476 -3 2 3 2 40.30 1.33 2.2378 0 -1 9 2 40.45 2.90 2.2299 -1 -1 9 2 40.47 9.82 2.2291 1 -2 7 2 40.50 7.17 2.2273 -3 1 6 2 40.68 2.09 2.2181 1 2 8 2 40.97 4.02 2.2029 1 0 9 2 41.41 6.09 2.1804 -3 -2 4 2 41.44 16.64 2.1788 -1 -2 8 2 41.46 62.96 2.1781 0 4 1 2 41.56 1.59 2.1732 3 2 3 2 41.62 11.27 2.1700 0 4 0 2 41.69 1.06 2.1666 -2 3 5 2 41.74 5.93 2.1638 0 4 2 2 41.78 6.52 2.1619 0 2 9 2 41.91 13.45 2.1554 -3 0 7 2 42.23 14.99 2.1400 -1 2 9 2 42.35 2.44 2.1341 3 1 5 2 42.41 3.41 2.1316 -2 1 9 2 42.47 2.69 2.1285 -3 2 5 2 42.74 1.57 2.1156 0 1 10 2 42.87 1.43 2.1097 2 2 7 2 43.17 2.06 2.0954 1 4 2 2 43.27 1.80 2.0909 0 -4 2 2 43.35 1.08 2.0874 3 2 4 2 43.36 1.27 2.0866 2 3 5 2 43.61 1.38 2.0754 -3 -1 7 2 44.25 4.09 2.0467 -3 2 6 2 44.29 1.13 2.0452 1 -4 1 2 44.58 3.89 2.0324 -4 0 2 2 44.61 2.80 2.0313 -1 -1 10 2 44.68 1.75 2.0281 -2 -2 8 2 44.76 6.71 2.0248 -3 0 8 2 44.84 1.42 2.0213 4 0 0 2 45.17 2.26 2.0074 3 3 0 2 45.20 1.72 2.0062 -1 -2 9 2 45.27 1.87 2.0031 1 0 10 2 45.29 6.94 2.0021 -3 -2 6 2 45.43 1.20 1.9965 1 -4 2 2 45.50 13.69 1.9933 3 2 5 2 45.60 3.40 1.9894 4 0 1 2 45.66 1.47 1.9870 -4 -1 2 2 45.69 1.32 1.9857 -2 -3 6 2 45.97 8.01 1.9741 3 -2 4 2 46.01 4.77 1.9725 -4 0 4 2 46.06 1.70 1.9705 -4 1 1 2 46.25 1.91 1.9631 -4 -1 3 2 46.28 1.09 1.9617 3 3 2 2 46.34 2.28 1.9594 -1 4 5 2 46.40 5.33 1.9571 -3 2 7 2 46.46 1.79 1.9545 -3 -1 8 2 46.54 1.55 1.9512 0 -4 4 2 46.63 7.78 1.9478 -3 -3 3 2 46.75 16.92 1.9432 2 0 9 2 46.79 2.03 1.9414 -1 0 11 2 46.82 3.93 1.9404 2 4 0 2 46.83 9.97 1.9399 0 0 11 2 46.94 1.25 1.9358 2 4 1 2 46.96 7.53 1.9350 1 -4 3 2 47.07 1.64 1.9308 -1 -4 4 2 47.11 2.97 1.9291 -2 -4 1 2 47.11 1.12 1.9291 0 4 6 2 47.46 1.65 1.9156 2 4 2 2 47.71 1.84 1.9061 1 -3 7 2 47.72 1.85 1.9058 3 0 7 2 47.80 1.67 1.9027 -2 -4 2 2 47.88 1.15 1.9000 -2 4 2 2 47.88 1.06 1.8998 -2 4 1 2 47.92 2.92 1.8983 -3 -3 4 2 47.98 1.70 1.8960 1 -2 9 2 47.99 7.03 1.8958 3 2 6 2 48.10 8.98 1.8918 -1 4 6 2 48.10 5.58 1.8916 -2 -2 9 2 48.27 3.06 1.8853 -2 4 3 2 48.28 4.88 1.8852 1 2 10 2 48.29 1.10 1.8847 -2 4 0 2 48.30 3.75 1.8842 4 0 3 2 48.38 19.37 1.8812 3 -2 5 2 48.39 3.05 1.8812 2 4 3 2 48.48 1.18 1.8778 -4 1 5 2 48.53 1.72 1.8760 4 -1 2 2 48.64 2.20 1.8720 -3 3 5 2 48.85 2.94 1.8645 1 -4 4 2 48.86 6.97 1.8639 -3 2 8 2 48.90 9.46 1.8626 -4 -2 1 2 48.93 15.28 1.8614 1 4 6 2 48.98 1.42 1.8597 3 -3 2 2 49.01 1.21 1.8588 0 -1 11 2 49.01 4.64 1.8586 -4 0 6 2 49.05 7.70 1.8574 4 2 0 2 49.09 8.17 1.8558 -2 2 10 2 49.09 13.20 1.8558 -1 -4 5 2 49.15 2.02 1.8538 -4 -2 2 2 49.21 3.84 1.8517 0 -2 10 2 49.37 1.25 1.8459 0 4 7 2 49.55 10.79 1.8397 -2 0 11 2 49.58 9.18 1.8386 -3 -3 5 2 49.67 1.46 1.8354 2 -2 8 2 49.69 4.88 1.8349 2 4 4 2 49.78 2.44 1.8318 0 2 11 2 49.90 4.26 1.8277 -4 2 2 2 49.98 1.15 1.8248 -2 1 11 2 49.99 7.33 1.8245 -4 2 1 2 50.05 3.00 1.8225 -4 1 6 2 50.20 7.12 1.8175 -4 2 3 2 50.20 6.33 1.8174 4 0 4 2 50.27 6.84 1.8149 2 -4 2 2 50.47 1.82 1.8083 -4 2 0 2 50.50 1.73 1.8073 -3 -2 8 2 50.60 1.16 1.8041 3 -3 3 2 50.77 6.93 1.7984 3 2 7 2 50.88 4.57 1.7946 -4 2 4 2 51.05 2.98 1.7890 1 -3 8 2 51.06 4.66 1.7887 3 0 8 2 51.07 2.00 1.7885 1 -4 5 2 51.09 2.69 1.7877 3 -2 6 2 51.22 1.69 1.7835 -1 0 12 2 51.25 1.58 1.7827 -1 3 10 2 51.28 6.86 1.7816 -2 -3 8 2 51.30 1.19 1.7810 3 1 8 2 51.55 1.69 1.7728 0 1 12 2 51.73 1.73 1.7671 -2 -2 10 2 51.77 5.16 1.7658 -2 4 6 2 51.82 2.60 1.7644 2 -4 3 2 51.94 1.21 1.7605 0 4 8 2 51.99 3.15 1.7589 1 -2 10 2 52.04 1.55 1.7573 -3 3 7 2 52.32 2.22 1.7486 1 2 11 2 52.42 1.29 1.7454 -4 -1 7 2 52.42 4.12 1.7454 4 0 5 2 52.61 3.42 1.7395 -1 4 8 2 53.19 1.57 1.7220 -1 -2 11 2 53.34 1.03 1.7177 2 -2 9 2 53.36 1.81 1.7170 -4 2 6 2 53.39 3.36 1.7160 2 2 10 2 53.41 1.24 1.7155 -3 -4 1 2 53.65 3.08 1.7084 -2 4 7 2 53.88 2.30 1.7015 1 4 8 2 53.92 2.56 1.7004 -3 -4 2 2 53.93 1.01 1.7001 -4 -2 6 2 53.97 1.02 1.6989 0 -4 7 2 54.08 1.86 1.6957 -1 -4 7 2 54.09 3.32 1.6955 3 4 2 2 54.10 1.00 1.6951 0 5 4 2 54.11 3.96 1.6948 -1 5 1 2 54.15 1.24 1.6938 -1 5 2 2 54.16 1.25 1.6934 1 0 12 2 54.21 1.26 1.6921 -2 3 10 2 54.45 1.26 1.6852 -1 5 0 2 54.46 2.20 1.6849 4 3 0 2 54.61 2.28 1.6806 1 -3 9 2 54.78 3.24 1.6757 -3 4 1 2 54.79 3.39 1.6755 -3 0 11 2 54.81 1.11 1.6748 -1 3 11 2 54.90 1.20 1.6724 -1 -5 2 2 54.90 5.08 1.6724 -3 4 3 2 54.95 6.78 1.6710 4 0 6 2 54.97 1.37 1.6704 2 0 11 2 55.50 1.41 1.6556 -3 4 4 2 55.84 4.13 1.6464 -2 4 8 2 55.90 1.14 1.6447 2 -4 5 2 55.95 1.08 1.6434 -4 3 3 2 56.03 2.15 1.6414 0 0 13 2 56.36 3.99 1.6325 3 4 4 2 56.40 3.99 1.6313 1 -4 7 2 56.50 1.77 1.6288 -3 -1 11 2 56.54 2.72 1.6276 -2 2 12 2 56.78 1.72 1.6214 1 4 9 2 56.91 1.34 1.6180 1 3 11 2 57.19 3.13 1.6108 2 -2 10 2 57.29 1.52 1.6082 2 2 11 2 57.32 1.09 1.6073 -5 -1 2 2 57.60 2.08 1.6003 -3 -4 5 2 57.60 1.22 1.6003 -1 -5 4 2 57.62 1.84 1.5998 5 1 0 2 57.70 2.02 1.5977 5 0 1 2 57.71 6.16 1.5975 -5 -1 3 2 57.72 5.35 1.5971 0 -2 12 2 57.75 1.30 1.5964 4 0 7 2 57.78 1.53 1.5957 -4 -3 5 2 57.97 2.57 1.5908 -2 0 13 2 58.01 1.30 1.5899 -2 -5 2 2 58.29 1.59 1.5829 -1 4 10 2 58.33 4.17 1.5818 0 2 13 2 58.37 1.14 1.5810 1 -3 10 2 58.49 5.21 1.5780 -5 0 5 2 58.80 1.78 1.5704 5 0 2 2 58.84 1.29 1.5694 3 -4 3 2 58.93 1.19 1.5672 -4 0 10 2 59.44 2.65 1.5550 -1 -5 5 2 59.47 3.36 1.5543 1 -4 8 2 60.27 1.60 1.5356 -3 -1 12 2 60.46 1.61 1.5312 1 -2 12 2 60.85 4.16 1.5223 1 2 13 2 61.24 1.59 1.5136 0 4 11 2 61.35 3.40 1.5111 -3 4 8 2 61.37 1.20 1.5107 2 2 12 2 61.59 2.93 1.5058 -1 -5 6 2 61.68 2.95 1.5039 -3 -4 7 2 61.79 1.08 1.5015 -1 -2 13 2 62.68 1.34 1.4823 -4 -4 3 2 63.13 1.88 1.4727 5 2 3 2 63.80 2.42 1.4589 0 -4 10 2 63.83 1.59 1.4582 -5 2 6 2 63.99 2.29 1.4550 5 -2 2 2 64.04 1.33 1.4540 3 5 3 2 64.04 1.79 1.4539 -4 4 0 2 64.04 1.41 1.4539 -5 -2 6 2 64.21 1.91 1.4506 2 -4 8 2 64.26 3.62 1.4495 2 4 10 2 64.81 1.21 1.4386 0 4 12 2 64.97 1.78 1.4354 -1 4 12 2 65.05 1.08 1.4338 -4 -4 5 2 65.17 1.30 1.4314 -1 1 15 2 65.44 2.15 1.4263 2 -2 12 2 65.62 1.27 1.4227 2 2 13 2 65.63 3.37 1.4225 1 6 3 2 65.65 2.03 1.4221 -2 -4 10 2 65.92 1.43 1.4171 0 -6 2 2 66.13 2.17 1.4130 4 -4 2 2 66.47 1.24 1.4066 3 0 12 2 66.49 1.04 1.4062 -5 1 9 2 66.61 1.41 1.4041 3 5 5 2 66.69 1.23 1.4025 1 -6 1 2 67.07 1.11 1.3955 -4 -2 11 2 67.16 1.73 1.3939 -1 2 15 2 67.40 1.33 1.3894 -2 4 12 2 67.44 4.15 1.3888 -1 6 5 2 67.65 1.31 1.3850 4 -4 3 2 67.85 1.44 1.3814 -5 -2 8 2 68.00 1.03 1.3786 3 -4 7 2 68.34 1.29 1.3727 -4 2 12 2 68.35 1.52 1.3724 1 0 15 2 69.12 2.08 1.3590 -2 -6 2 2 69.13 1.13 1.3589 -4 0 13 2 69.35 1.52 1.3550 -2 6 1 2 69.39 1.00 1.3544 -2 6 3 2 69.79 1.55 1.3476 6 0 0 2 69.81 1.50 1.3472 -2 6 0 2 69.88 1.03 1.3460 -2 6 4 2 70.08 2.17 1.3427 -1 0 16 2 70.12 1.34 1.3420 -2 -6 3 2 70.48 1.04 1.3361 -4 -2 12 2 70.63 2.29 1.3335 4 4 7 2 70.92 1.29 1.3289 -2 4 13 2 71.72 2.75 1.3161 -5 1 11 2 72.04 1.28 1.3109 -1 -3 14 2 72.65 1.20 1.3015 5 4 2 2 72.75 1.01 1.2999 -6 1 6 2 73.44 1.24 1.2893 4 -2 10 2 73.62 1.03 1.2866 -2 -1 16 2 73.66 1.51 1.2861 0 6 9 2 75.08 1.20 1.2653 5 0 9 2 75.33 1.61 1.2617 -5 4 6 2 75.33 1.32 1.2617 3 0 14 2 76.20 1.21 1.2493 0 6 10 2 77.80 1.57 1.2277 -5 -3 10 2 78.13 1.21 1.2232 3 6 6 2 79.58 1.06 1.2046 -5 -5 1 2 79.87 1.01 1.2010 -5 -5 2 2 80.91 2.29 1.1881 3 -6 4 2 81.82 1.09 1.1772 -3 6 9 2 85.11 1.06 1.1399 1 2 18 2 86.22 1.48 1.1280 6 2 8 2 86.96 1.26 1.1204 6 -2 7 2 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.