data_global
_chemical_name_mineral 'Kinoshitalite'
loop_
_publ_author_name
'Brigatti M F'
'Poppi L'
_journal_name_full 'European Journal of Mineralogy'
_journal_volume 5 
_journal_year 1993
_journal_page_first 857
_journal_page_last 871
_publ_section_title
;
 Crystal chemistry of Ba-rich trioctahedral micas-1M
 Sample: 27
;
_database_code_amcsd 0006503
_chemical_formula_sum 'O11.286 (F.714 K.408) Na.039 Ca.01 Ba.543 Al1.997 Fe.272 Mg2.533 Mn.004 Ti.026 Si2.168 H1.286'
_cell_length_a 5.318
_cell_length_b 9.214
_cell_length_c 10.164
_cell_angle_alpha 90
_cell_angle_beta 100.11
_cell_angle_gamma 90
_cell_volume 490.303
_exptl_crystal_density_diffrn      3.253
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
O1  -0.00290   0.00000   0.16410   1.00000   0.02571
O2   0.33420   0.22110   0.16380   1.00000   0.02596
O3   0.13110   0.16630   0.39090   1.00000   0.01938
O-H4   0.13100   0.50000   0.39880   0.64320   0.01874
F4   0.13100   0.50000   0.39880   0.35680   0.01874
K   0.00000   0.50000   0.00000   0.40770   0.02748
Na   0.00000   0.50000   0.00000   0.03900   0.02748
Ca   0.00000   0.50000   0.00000   0.01050   0.02748
Ba   0.00000   0.50000   0.00000   0.54280   0.02748
AlM2   0.00000   0.33070   0.50000   0.05500   0.01697
FeM2   0.00000   0.33070   0.50000   0.09070   0.01697
MgM2   0.00000   0.33070   0.50000   0.84450   0.01697
MnM2   0.00000   0.33070   0.50000   0.00130   0.01697
TiM2   0.00000   0.33070   0.50000   0.00850   0.01697
AlM1   0.00000   0.00000   0.50000   0.05500   0.01621
FeM1   0.00000   0.00000   0.50000   0.09070   0.01621
MgM1   0.00000   0.00000   0.50000   0.84450   0.01621
MnM1   0.00000   0.00000   0.50000   0.00130   0.01621
TiM1   0.00000   0.00000   0.50000   0.00850   0.01621
SiT   0.07530   0.16660   0.22440   0.54210   0.01659
AlT   0.07530   0.16660   0.22440   0.45790   0.01659
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
O1 0.03027 0.02366 0.02232 0.00000 0.00027 0.00000
O2 0.02499 0.03140 0.02232 -0.00660 0.00663 -0.00327
O3 0.01819 0.01978 0.02029 0.00000 0.00345 -0.00047
O-H4 0.01666 0.02021 0.01927 0.00000 0.00292 0.00000
F4 0.01666 0.02021 0.01927 0.00000 0.00292 0.00000
K 0.02583 0.02753 0.02942 0.00000 0.00504 0.00000
Na 0.02583 0.02753 0.02942 0.00000 0.00504 0.00000
Ca 0.02583 0.02753 0.02942 0.00000 0.00504 0.00000
Ba 0.02583 0.02753 0.02942 0.00000 0.00504 0.00000
AlM2 0.01458 0.01677 0.01927 0.00000 0.00318 0.00000
FeM2 0.01458 0.01677 0.01927 0.00000 0.00318 0.00000
MgM2 0.01458 0.01677 0.01927 0.00000 0.00318 0.00000
MnM2 0.01458 0.01677 0.01927 0.00000 0.00318 0.00000
TiM2 0.01458 0.01677 0.01927 0.00000 0.00318 0.00000
AlM1 0.01430 0.01591 0.01877 0.00000 0.00345 0.00000
FeM1 0.01430 0.01591 0.01877 0.00000 0.00345 0.00000
MgM1 0.01430 0.01591 0.01877 0.00000 0.00345 0.00000
MnM1 0.01430 0.01591 0.01877 0.00000 0.00345 0.00000
TiM1 0.01430 0.01591 0.01877 0.00000 0.00345 0.00000
SiT 0.01527 0.01720 0.01725 0.00000 0.00318 -0.00047
AlT 0.01527 0.01720 0.01725 0.00000 0.00318 -0.00047