data_global
_chemical_name_mineral 'Sanmartinite'
loop_
_publ_author_name
'Redfern S A T'
'Bell A M T'
'Henderson M B'
'Schofield P F'
_journal_name_full 'European Journal of Mineralogy'
_journal_volume 7 
_journal_year 1995
_journal_page_first 1019
_journal_page_last 1028
_publ_section_title
;
 Rietveld study of the structural phase transition in the
 sanmartinite (ZnWO4)- cuproscheelite (CuWO4) solid solution
 Sample: x=0.55
;
_database_code_amcsd 0006599
_chemical_formula_sum '(Cu.45 Zn.55) W O4'
_cell_length_a 4.689
_cell_length_b 5.77
_cell_length_c 4.899
_cell_angle_alpha 90.84
_cell_angle_beta 91.52
_cell_angle_gamma 85.87
_cell_volume 132.144
_exptl_crystal_density_diffrn      7.852
_symmetry_space_group_name_H-M 'P -1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
CuM   0.50430   0.68160   0.24450   0.45000   0.01165
ZnM   0.50430   0.68160   0.24450   0.55000   0.01165
W   0.00900   0.17830   0.25250   1.00000   0.00532
O1   0.24900   0.33900   0.40900   1.00000   0.00253
O2   0.19500   0.88000   0.44000   1.00000   0.00253
O3   0.74100   0.37100   0.09600   1.00000   0.00253
O4   0.78400   0.89300   0.05900   1.00000   0.00253