Pillaite Meerschaut A, Palvadeau P, Moello Y, Orlandi P European Journal of Mineralogy 13 (2001) 779-790 Lead-antimony sulfosalts from Tuscany (Italy). IV. Crystal structure of pillaite, Pb9Sb10S23ClO0.5, an expanded monoclinic derivative of hexagonal Bi(Bi2S3)9I3, from the zinkenite group Locality: Buca della Vena mine, Tuscany, Italy Note: changed Pb2(z) to 0.2572 to match reported bond distances _database_code_amcsd 0006897 CELL PARAMETERS: 49.4900 4.1259 21.8280 90.000 99.620 90.000 SPACE GROUP: C2/m X-RAY WAVELENGTH: 1.541838 Cell Volume: 4394.400 Density (g/cm3): 5.860 MAX. ABS. INTENSITY / VOLUME**2: 28.15573624 RIR: 1.564 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 3.62 6.34 24.3970 2 0 0 2 5.91 11.05 14.9475 2 0 1 2 7.25 1.13 12.1985 4 0 0 2 7.71 1.12 11.4661 -4 0 1 2 8.22 8.83 10.7605 0 0 2 2 8.41 3.09 10.5156 -2 0 2 2 8.91 4.61 9.9246 4 0 1 2 9.52 2.82 9.2889 2 0 2 2 10.01 6.52 8.8352 -4 0 2 2 12.26 8.35 7.2189 6 0 1 2 12.34 8.33 7.1737 0 0 3 2 13.23 4.28 6.6916 -4 0 3 2 13.43 8.75 6.5907 2 0 3 2 14.42 2.79 6.1437 -8 0 1 2 15.04 9.14 5.8902 -6 0 3 2 15.75 2.78 5.6267 8 0 1 2 17.44 1.21 5.0850 -8 0 3 2 18.19 2.31 4.8779 -6 0 4 2 18.67 2.04 4.7526 -10 0 2 2 19.11 2.81 4.6445 4 0 4 2 20.10 4.54 4.4176 -8 0 4 2 20.34 4.99 4.3654 -2 0 5 2 20.64 1.31 4.3042 0 0 5 2 21.56 30.74 4.1225 2 0 5 2 21.62 16.26 4.1112 1 1 0 4 21.86 14.96 4.0662 12 0 0 2 21.95 1.69 4.0487 -1 1 1 4 22.04 3.32 4.0330 -12 0 2 2 22.07 7.13 4.0278 1 1 1 4 22.23 14.45 3.9992 3 1 0 4 22.44 2.90 3.9613 -3 1 1 4 22.46 29.83 3.9585 -10 0 4 2 22.78 4.85 3.9032 3 1 1 4 22.93 26.15 3.8790 12 0 1 2 23.03 2.06 3.8615 4 0 5 2 23.05 27.01 3.8586 -1 1 2 4 23.22 11.63 3.8312 -8 0 5 2 23.27 22.54 3.8226 1 1 2 4 23.27 3.32 3.8220 -12 0 3 2 23.41 2.21 3.8000 -3 1 2 4 23.51 6.40 3.7847 -5 1 1 4 23.70 16.72 3.7534 10 0 3 2 23.81 1.27 3.7369 8 0 4 2 24.04 36.17 3.7013 5 1 1 4 24.06 9.07 3.6994 3 1 2 4 24.47 8.46 3.6372 -2 0 6 2 24.66 61.26 3.6094 12 0 2 2 24.67 3.46 3.6082 -4 0 6 2 24.97 8.38 3.5658 6 0 5 2 25.04 9.36 3.5558 -3 1 3 4 25.07 3.68 3.5521 -7 1 1 4 25.12 5.43 3.5455 1 1 3 4 25.15 8.03 3.5411 -12 0 4 2 25.19 2.47 3.5350 -14 0 1 2 25.20 50.46 3.5341 -10 0 5 2 25.36 13.69 3.5123 5 1 2 4 25.41 3.37 3.5052 -6 0 6 2 25.56 18.88 3.4853 14 0 0 2 25.70 100.00 3.4663 2 0 6 2 25.78 32.17 3.4563 7 1 1 4 25.81 1.48 3.4523 -5 1 3 4 25.95 4.09 3.4336 3 1 3 4 26.50 4.55 3.3636 -14 0 3 2 26.58 40.35 3.3532 14 0 1 2 26.95 7.55 3.3082 12 0 3 2 27.06 2.57 3.2954 4 0 6 2 27.11 1.70 3.2895 7 1 2 4 27.11 10.03 3.2891 -1 1 4 4 27.16 18.87 3.2833 9 1 0 4 27.23 1.68 3.2747 -3 1 4 4 27.28 1.13 3.2688 8 0 5 2 27.49 5.18 3.2447 1 1 4 4 27.54 40.69 3.2382 -12 0 5 2 27.85 2.03 3.2038 -5 1 4 4 27.90 23.51 3.1978 9 1 1 4 28.08 6.46 3.1775 -14 0 4 2 28.20 3.64 3.1643 14 0 2 2 28.35 27.63 3.1483 3 1 4 4 28.73 10.74 3.1068 -9 1 3 4 28.83 1.17 3.0963 6 0 6 2 28.93 5.21 3.0867 -7 1 4 4 29.29 5.28 3.0496 16 0 0 2 29.29 1.54 3.0493 -6 0 7 2 29.38 14.32 3.0398 -11 1 1 4 29.57 25.68 3.0211 11 1 0 4 29.65 12.66 3.0130 5 1 4 4 29.79 4.71 2.9988 -11 1 2 4 29.86 2.04 2.9924 -16 0 3 2 29.87 20.67 2.9917 -3 1 5 4 29.89 2.79 2.9895 10 0 5 2 29.89 26.86 2.9890 2 0 7 2 30.27 46.93 2.9523 1 1 5 4 30.28 7.91 2.9517 16 0 1 2 30.33 1.53 2.9473 14 0 3 2 30.34 5.57 2.9459 11 1 1 4 30.35 34.13 2.9454 -5 1 5 4 30.35 15.34 2.9451 -12 0 6 2 30.42 20.77 2.9380 -9 1 4 4 30.78 57.43 2.9050 -11 1 3 4 31.08 2.59 2.8773 9 1 3 4 31.20 2.83 2.8665 -16 0 4 2 31.26 64.74 2.8611 -7 1 5 4 31.34 1.35 2.8539 7 1 4 4 31.66 31.11 2.8261 11 1 2 4 31.81 1.38 2.8133 16 0 2 2 31.99 3.03 2.7978 -13 1 1 4 32.24 64.03 2.7764 13 1 0 4 32.29 10.67 2.7726 -13 1 2 4 32.29 12.91 2.7724 -11 1 4 4 32.43 22.87 2.7610 5 1 5 4 32.58 12.81 2.7480 -9 1 5 4 32.69 1.71 2.7393 -18 0 2 2 32.70 3.74 2.7388 -14 0 6 2 32.85 4.00 2.7265 -3 1 6 4 32.87 3.66 2.7248 14 0 4 2 32.88 3.71 2.7240 -2 0 8 2 32.91 11.38 2.7218 -1 1 6 4 33.04 2.22 2.7114 13 1 1 4 33.13 10.42 2.7042 -13 1 3 4 33.31 1.25 2.6901 0 0 8 2 33.32 2.10 2.6887 -18 0 3 2 33.38 3.89 2.6844 9 1 4 4 33.38 11.68 2.6841 1 1 6 4 33.47 13.63 2.6774 11 1 3 4 33.80 3.06 2.6515 16 0 3 2 34.02 1.31 2.6355 18 0 1 2 34.07 2.65 2.6312 7 1 5 4 34.14 5.83 2.6265 2 0 8 2 34.34 5.81 2.6114 13 1 2 4 34.47 3.67 2.6018 -13 1 4 4 35.14 3.31 2.5540 -9 1 6 4 35.52 2.02 2.5276 5 1 6 4 35.56 1.18 2.5244 -14 0 7 2 35.73 5.04 2.5129 -15 1 3 4 35.76 2.94 2.5112 14 0 5 2 36.10 3.89 2.4878 13 1 3 4 36.11 2.77 2.4873 -3 1 7 4 36.24 1.12 2.4789 -1 1 7 4 36.37 1.98 2.4701 -5 1 7 4 36.65 6.52 2.4523 -11 1 6 4 36.88 1.53 2.4373 -20 0 3 2 36.91 2.59 2.4355 6 0 8 2 36.92 11.83 2.4347 -15 1 4 4 37.08 3.36 2.4243 -4 0 9 2 37.11 3.49 2.4224 7 1 6 4 37.23 3.25 2.4152 15 1 2 4 37.37 2.37 2.4063 18 0 3 2 37.38 1.96 2.4055 -6 0 9 2 37.62 1.46 2.3912 0 0 9 2 37.63 2.93 2.3904 3 1 7 4 37.84 1.32 2.3777 -17 1 1 4 37.86 1.02 2.3763 -20 0 4 2 37.96 6.56 2.3706 -17 1 2 4 38.02 8.75 2.3668 -9 1 7 4 38.06 1.08 2.3646 -8 0 9 2 38.20 3.64 2.3562 17 1 0 4 38.27 11.52 2.3517 13 1 4 4 38.30 7.80 2.3502 11 1 5 4 38.47 2.81 2.3400 -13 1 6 4 38.55 5.17 2.3354 -15 1 5 4 38.86 6.90 2.3176 5 1 7 4 38.92 6.87 2.3138 14 0 6 2 38.95 4.93 2.3125 15 1 3 4 39.02 1.42 2.3083 9 1 6 4 39.36 9.65 2.2890 -11 1 7 4 39.60 2.83 2.2761 -17 1 4 4 39.60 1.41 2.2759 -3 1 8 4 39.77 3.38 2.2663 -5 1 8 4 39.78 3.17 2.2657 -1 1 8 4 40.32 9.56 2.2367 1 1 8 4 40.41 7.55 2.2321 7 1 7 4 40.51 16.27 2.2266 -22 0 3 2 40.58 1.58 2.2232 -15 1 6 4 40.85 1.16 2.2088 -16 0 8 2 41.01 2.17 2.2007 -19 1 1 4 41.02 1.24 2.2004 20 0 3 2 41.05 8.71 2.1985 15 1 4 4 41.17 2.36 2.1925 -9 1 8 4 41.20 1.41 2.1911 11 1 6 4 41.55 9.53 2.1736 -19 1 3 4 41.57 10.34 2.1722 -6 0 10 2 41.97 2.76 2.1527 17 1 3 4 41.97 10.84 2.1526 16 0 6 2 42.26 7.70 2.1388 9 1 7 4 42.41 4.07 2.1312 5 1 8 4 42.79 1.57 2.1131 2 0 10 2 43.01 5.83 2.1031 -10 0 10 2 43.24 2.25 2.0923 -18 0 8 2 43.28 5.75 2.0905 -3 1 9 4 43.51 3.61 2.0802 15 1 5 4 43.51 2.33 2.0798 -1 1 9 4 43.62 4.68 2.0749 13 1 6 4 43.81 10.90 2.0665 -7 1 9 4 43.87 1.71 2.0637 -13 1 8 4 43.89 74.97 2.0629 0 2 0 2 43.92 4.58 2.0614 7 1 8 4 43.93 1.08 2.0613 4 0 10 2 44.02 1.34 2.0571 17 1 4 4 44.03 5.15 2.0565 -24 0 1 2 44.04 2.89 2.0559 -16 0 9 2 44.20 6.93 2.0489 -12 0 10 2 44.23 8.99 2.0479 -24 0 3 2 44.30 2.28 2.0445 -21 1 2 4 44.56 7.83 2.0333 -9 1 9 4 44.57 4.26 2.0331 24 0 0 2 44.70 10.83 2.0271 -21 1 3 4 44.95 7.46 2.0165 -24 0 4 2 44.96 4.01 2.0162 3 1 9 4 45.16 1.71 2.0078 -17 1 7 4 45.25 8.64 2.0041 16 0 7 2 45.36 1.05 1.9995 6 0 10 2 45.51 12.13 1.9929 -21 1 4 4 45.52 1.30 1.9928 -19 1 6 4 45.63 2.71 1.9883 -11 1 9 4 45.65 2.42 1.9872 -15 1 8 4 45.70 1.78 1.9855 -14 0 10 2 45.71 2.25 1.9847 9 1 8 4 45.86 2.34 1.9789 -6 0 11 2 45.93 4.12 1.9758 14 0 8 2 46.08 2.46 1.9698 -24 0 5 2 46.15 2.78 1.9670 5 1 9 4 46.26 16.89 1.9626 15 1 6 4 46.30 1.15 1.9609 -22 0 7 2 46.31 9.75 1.9607 -8 0 11 2 46.40 11.43 1.9568 17 1 5 4 46.72 9.09 1.9445 13 1 7 4 46.84 1.00 1.9395 22 0 4 2 46.84 1.20 1.9395 24 0 2 2 46.85 3.46 1.9390 21 1 2 4 46.99 1.18 1.9339 -13 1 9 4 47.07 2.57 1.9308 -10 0 11 2 47.15 3.62 1.9277 19 1 4 4 47.16 3.53 1.9272 -5 1 10 4 47.21 3.19 1.9254 12 0 9 2 47.50 4.50 1.9141 -7 1 10 4 47.68 9.19 1.9072 -23 1 2 4 47.69 1.68 1.9068 -17 1 8 4 47.76 4.58 1.9043 -23 1 1 4 47.78 3.02 1.9034 -26 0 2 2 47.95 1.41 1.8972 -26 0 1 2 47.99 5.59 1.8957 1 1 10 4 48.00 2.72 1.8952 -23 1 3 4 48.12 2.16 1.8908 -12 0 11 2 48.15 3.47 1.8897 -9 1 10 4 48.30 2.23 1.8845 -21 1 6 4 48.33 2.37 1.8832 4 0 11 2 48.54 3.34 1.8756 24 0 3 2 48.64 1.00 1.8719 -26 0 4 2 48.65 1.21 1.8717 -22 0 8 2 48.66 4.34 1.8712 -20 0 9 2 48.72 1.08 1.8692 -8 2 4 4 48.88 1.54 1.8634 3 1 10 4 49.03 1.09 1.8578 10 0 10 2 49.10 2.54 1.8555 -11 1 10 4 49.26 1.18 1.8497 22 0 5 2 49.28 1.16 1.8491 15 1 7 4 49.40 5.16 1.8449 2 2 5 4 49.45 1.44 1.8431 26 0 1 2 49.55 2.57 1.8397 12 2 0 4 49.64 1.06 1.8364 -26 0 5 2 49.71 5.82 1.8340 14 0 9 2 49.80 8.03 1.8309 -23 1 5 4 49.85 6.37 1.8294 -10 2 4 4 49.97 1.17 1.8252 -19 1 8 4 50.04 2.40 1.8227 13 1 8 4 50.05 3.47 1.8225 5 1 10 4 50.08 4.28 1.8214 12 2 1 4 50.16 1.40 1.8186 -4 0 12 2 50.23 2.69 1.8164 -8 2 5 4 50.33 10.02 1.8131 23 1 2 4 50.33 5.97 1.8129 -13 1 10 4 50.48 3.57 1.8079 10 2 3 4 50.51 3.39 1.8068 -17 1 9 4 50.58 1.88 1.8047 24 0 4 2 50.89 1.53 1.7944 -2 2 6 4 50.92 2.95 1.7934 0 0 12 2 50.99 14.63 1.7911 12 2 2 4 51.01 2.65 1.7903 -26 0 6 2 51.10 2.29 1.7875 -5 1 11 4 51.15 2.11 1.7857 6 2 5 4 51.24 2.29 1.7829 12 0 10 2 51.25 1.50 1.7825 -12 2 4 4 51.28 10.56 1.7816 -10 2 5 4 51.31 2.15 1.7805 -25 1 1 4 51.36 1.70 1.7790 11 1 9 4 51.37 2.76 1.7785 8 0 11 2 51.48 3.81 1.7753 14 2 0 4 51.49 6.49 1.7747 7 1 10 4 51.55 21.38 1.7728 2 2 6 4 51.62 2.84 1.7705 -24 0 8 2 51.82 1.35 1.7643 25 1 0 4 51.91 1.79 1.7614 23 1 3 4 51.93 6.17 1.7609 -9 1 11 4 52.00 1.13 1.7586 -14 2 3 4 52.05 9.05 1.7571 14 2 1 4 52.05 2.74 1.7569 -25 1 4 4 52.26 1.37 1.7505 12 2 3 4 52.42 2.09 1.7456 26 0 3 2 52.46 8.98 1.7443 -21 1 8 4 52.51 1.75 1.7426 28 0 0 2 52.54 1.43 1.7418 15 1 8 4 52.60 9.60 1.7399 -12 2 5 4 52.64 7.44 1.7386 -19 1 9 4 52.69 4.52 1.7372 25 1 1 4 52.82 3.54 1.7332 4 0 12 2 52.92 2.02 1.7303 -14 2 4 4 52.94 6.92 1.7296 3 1 11 4 53.04 1.67 1.7265 -23 1 7 4 53.46 1.19 1.7141 28 0 1 2 53.64 1.84 1.7087 16 2 0 4 53.92 4.40 1.7005 25 1 2 4 54.01 7.90 1.6978 2 2 7 4 54.11 1.35 1.6950 -24 0 9 2 54.20 8.12 1.6923 -22 0 10 2 54.25 2.45 1.6909 16 2 1 4 54.29 3.68 1.6897 -12 2 6 4 54.40 3.23 1.6865 26 0 4 2 54.69 1.06 1.6782 -4 0 13 2 54.75 3.11 1.6766 28 0 2 2 55.58 1.35 1.6534 -19 1 10 4 55.62 1.32 1.6524 -1 1 12 4 55.90 1.32 1.6447 14 2 4 4 55.91 1.38 1.6446 -2 2 8 4 56.15 1.19 1.6380 -28 0 7 2 56.40 1.23 1.6315 27 1 1 4 56.52 1.03 1.6282 16 2 3 4 56.74 1.70 1.6224 2 2 8 4 57.20 1.23 1.6105 9 1 11 4 57.85 1.04 1.5940 14 2 5 4 58.77 1.46 1.5711 -4 2 9 4 59.26 3.26 1.5592 26 0 6 2 59.63 1.66 1.5505 -2 0 14 2 59.71 1.16 1.5486 -30 0 7 2 59.82 1.20 1.5460 -32 0 2 2 60.09 2.64 1.5398 14 2 6 4 60.21 1.13 1.5369 29 1 1 4 60.33 1.98 1.5343 16 0 11 2 61.25 7.76 1.5133 -22 2 3 4 61.35 1.27 1.5110 23 1 7 4 61.75 1.19 1.5022 -14 0 14 2 62.04 5.13 1.4959 -6 2 10 4 62.11 1.91 1.4945 4 0 14 2 62.29 1.41 1.4905 17 1 10 4 62.34 4.68 1.4894 16 2 6 4 62.45 1.64 1.4871 -31 1 3 4 62.75 1.01 1.4808 -15 1 13 4 63.13 2.51 1.4727 -10 2 10 4 63.18 1.16 1.4718 -23 1 11 4 63.23 1.06 1.4706 31 1 0 4 63.31 1.17 1.4690 -18 2 8 4 63.92 2.55 1.4564 -24 2 1 4 63.93 1.61 1.4562 -16 2 9 4 63.99 1.28 1.4550 -3 1 14 4 64.05 3.64 1.4537 -12 2 10 4 64.07 4.81 1.4534 -24 2 3 4 64.16 1.12 1.4514 -17 1 13 4 64.29 2.09 1.4489 -29 1 8 4 64.33 2.07 1.4481 24 2 0 4 64.41 1.54 1.4466 -1 1 14 4 64.63 3.30 1.4420 -24 2 4 4 64.86 4.05 1.4375 16 2 7 4 65.34 1.29 1.4281 -6 2 11 4 65.40 2.41 1.4269 14 2 8 4 65.52 1.22 1.4247 -24 2 5 4 65.63 3.72 1.4225 27 1 6 4 65.69 1.74 1.4214 -13 1 14 4 65.70 4.80 1.4212 -8 2 11 4 66.00 3.47 1.4155 -31 1 7 4 66.13 2.92 1.4129 17 1 11 4 66.31 1.16 1.4097 -10 2 11 4 66.42 1.82 1.4076 12 2 9 4 66.78 1.56 1.4008 -15 1 14 4 66.88 1.56 1.3989 -26 2 2 4 67.32 1.22 1.3908 4 2 11 4 67.49 2.05 1.3877 24 2 3 4 67.59 2.68 1.3860 -20 2 9 4 67.78 3.09 1.3826 25 1 8 4 68.29 1.08 1.3735 -36 0 2 2 68.35 1.24 1.3725 -33 1 6 4 68.37 3.78 1.3721 -5 1 15 4 68.45 3.06 1.3706 14 2 9 4 68.65 1.48 1.3671 -36 0 1 2 68.77 1.06 1.3650 -25 1 12 4 68.81 2.46 1.3644 -34 0 8 2 68.88 4.82 1.3632 19 1 11 4 69.03 1.70 1.3606 -1 1 15 4 69.22 2.42 1.3573 -11 1 15 4 69.23 1.13 1.3571 5 3 1 4 69.44 1.58 1.3535 0 2 12 4 69.52 1.34 1.3521 -26 2 6 4 69.66 2.74 1.3498 -19 1 14 4 69.71 1.26 1.3489 12 2 10 4 69.82 1.79 1.3470 8 2 11 4 70.01 1.09 1.3439 7 3 1 4 70.03 1.57 1.3436 -24 2 8 4 70.17 1.56 1.3411 17 1 12 4 70.41 6.92 1.3372 -35 1 3 4 70.66 1.15 1.3332 3 1 15 4 70.69 1.45 1.3325 26 2 3 4 71.03 1.85 1.3270 4 2 12 4 71.21 1.82 1.3242 -33 1 8 4 71.32 3.08 1.3224 27 1 8 4 71.61 1.01 1.3177 36 0 2 2 71.87 1.41 1.3136 11 3 0 4 71.92 1.21 1.3128 15 1 13 4 72.03 1.05 1.3111 11 1 14 4 72.08 2.75 1.3104 29 1 7 4 72.20 4.82 1.3084 -22 2 10 4 72.24 2.90 1.3078 1 3 5 4 72.25 2.12 1.3077 -17 1 15 4 72.28 1.45 1.3072 -5 3 5 4 72.37 1.92 1.3057 26 2 4 4 72.51 2.47 1.3036 -11 3 3 4 72.67 1.83 1.3011 28 2 2 4 72.77 3.19 1.2996 -7 3 5 4 72.99 1.48 1.2962 11 3 2 4 73.08 1.02 1.2948 -33 1 9 4 73.23 1.49 1.2926 7 1 15 4 73.31 3.94 1.2913 13 3 0 4 73.41 1.06 1.2898 5 3 5 4 73.95 1.00 1.2817 1 3 6 4 74.17 1.14 1.2784 -10 0 17 2 76.47 1.19 1.2456 24 0 12 2 76.60 2.26 1.2439 26 2 6 4 76.92 1.27 1.2395 -2 2 14 4 77.34 2.96 1.2338 -29 1 13 4 77.54 1.39 1.2311 16 2 11 4 77.97 1.51 1.2254 37 1 2 4 78.10 1.63 1.2237 -27 1 14 4 78.81 1.02 1.2144 -14 2 14 4 79.13 1.36 1.2103 4 2 14 4 79.54 4.39 1.2052 37 1 3 4 79.73 2.67 1.2027 9 1 16 4 81.25 1.03 1.1840 -21 3 3 4 81.83 1.28 1.1771 -21 3 4 4 82.37 2.27 1.1708 15 3 6 4 83.80 1.03 1.1543 -35 1 12 4 85.02 1.17 1.1409 -23 3 5 4 85.14 1.18 1.1396 -36 2 1 4 85.28 2.24 1.1380 -34 2 8 4 85.42 1.23 1.1365 23 3 2 4 87.09 1.08 1.1190 -21 3 8 4 87.24 1.01 1.1175 -19 3 9 4 87.47 1.25 1.1151 3 3 11 4 89.27 1.34 1.0973 -13 1 19 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.