data_global _chemical_name_mineral 'Sadanagaite' loop_ _publ_author_name 'Banno Y' 'Miyawaki R' 'Matsubara S' 'Makino K' 'Bunno M' 'Yamada S' 'Kamiya T' _journal_name_full 'European Journal of Mineralogy' _journal_volume 16 _journal_year 2004 _journal_page_first 177 _journal_page_last 183 _publ_section_title ; Magnesiosadanagaite, a new member of the amphibole group from Kasuga-mura, Gifu Prefecture, central Japan Sample: GSJ M35151-1 ; _database_code_amcsd 0007034 _chemical_compound_source 'Kasuga-mura, Gifu Prefecture, central Japan' _chemical_formula_sum 'Na.94 K.09 Mg2.9 Fe.82 Al3.58 Ti.3 Ca1.95 Mn.02 Si5.4 O23.87 F.13 H1.87' _cell_length_a 9.869 _cell_length_b 17.933 _cell_length_c 5.322 _cell_angle_alpha 90 _cell_angle_beta 105.29 _cell_angle_gamma 90 _cell_volume 908.552 _exptl_crystal_density_diffrn 3.178 _symmetry_space_group_name_H-M 'C 1 2/m 1' loop_ _space_group_symop_operation_xyz 'x,y,z' '1/2+x,1/2+y,z' 'x,-y,z' '1/2+x,1/2-y,z' '-x,y,-z' '1/2-x,1/2+y,-z' '-x,-y,-z' '1/2-x,1/2-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy _atom_site_U_iso_or_equiv NaA2 0.00000 0.47760 0.00000 0.45500 0.06800 KA2 0.00000 0.47760 0.00000 0.04500 0.06800 Mg1 0.00000 0.08999 0.50000 0.81000 0.00790 Fe1 0.00000 0.08999 0.50000 0.19000 0.00790 Al2 0.00000 0.17726 0.00000 0.49000 0.01040 Mg2 0.00000 0.17726 0.00000 0.26500 0.01040 Ti2 0.00000 0.17726 0.00000 0.15000 0.01040 Fe2 0.00000 0.17726 0.00000 0.09500 0.01040 Mg3 0.00000 0.00000 0.00000 0.75000 0.00800 Fe3 0.00000 0.00000 0.00000 0.25000 0.00800 Ca4 0.00000 0.28122 0.50000 0.97500 0.01090 Na4 0.00000 0.28122 0.50000 0.01500 0.01090 Mn4 0.00000 0.28122 0.50000 0.01000 0.01090 Si1 0.27999 0.08616 0.30473 0.49000 0.00770 Al1 0.27999 0.08616 0.30473 0.51000 0.00770 Si2 0.29136 0.17386 0.81769 0.86000 0.00800 Al2 0.29136 0.17386 0.81769 0.14000 0.00800 O1 0.10500 0.09056 0.21220 1.00000 0.01320 O2 0.11820 0.17486 0.74020 1.00000 0.01080 O3 0.10830 0.00000 0.71390 0.93500 0.01120 F3 0.10830 0.00000 0.71390 0.06500 0.01120 O4 0.37000 0.25190 0.79210 1.00000 0.01260 O5 0.35220 0.14168 0.11760 1.00000 0.01300 O6 0.34250 0.11659 0.61410 1.00000 0.01430 O7 0.33680 0.00000 0.27150 1.00000 0.01540 H 0.17300 0.00000 0.85000 0.93500 0.15000 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 NaA2 0.05800 0.08000 0.08700 0.00000 0.05700 0.00000 KA2 0.05800 0.08000 0.08700 0.00000 0.05700 0.00000 Mg1 0.01110 0.00640 0.00780 0.00000 0.00530 0.00000 Fe1 0.01110 0.00640 0.00780 0.00000 0.00530 0.00000 Al2 0.01210 0.00900 0.01090 0.00000 0.00470 0.00000 Mg2 0.01210 0.00900 0.01090 0.00000 0.00470 0.00000 Ti2 0.01210 0.00900 0.01090 0.00000 0.00470 0.00000 Fe2 0.01210 0.00900 0.01090 0.00000 0.00470 0.00000 Mg3 0.01060 0.00610 0.00810 0.00000 0.00390 0.00000 Fe3 0.01060 0.00610 0.00810 0.00000 0.00390 0.00000 Ca4 0.01520 0.00760 0.01240 0.00000 0.00780 0.00000 Na4 0.01520 0.00760 0.01240 0.00000 0.00780 0.00000 Mn4 0.01520 0.00760 0.01240 0.00000 0.00780 0.00000 Si1 0.00920 0.00560 0.00890 -0.00080 0.00360 0.00020 Al1 0.00920 0.00560 0.00890 -0.00080 0.00360 0.00020 Si2 0.00980 0.00600 0.00960 0.00030 0.00500 0.00020 Al2 0.00980 0.00600 0.00960 0.00030 0.00500 0.00020 O1 0.01230 0.01730 0.01130 -0.00400 0.00540 -0.00110 O2 0.01150 0.00870 0.01280 0.00100 0.00390 0.00100 O3 0.01040 0.00880 0.01490 0.00000 0.00420 0.00000 F3 0.01040 0.00880 0.01490 0.00000 0.00420 0.00000 O4 0.01710 0.00830 0.01470 -0.00110 0.00810 0.00070 O5 0.01360 0.01100 0.01540 -0.00080 0.00560 0.00210 O6 0.01250 0.01360 0.01720 0.00090 0.00440 -0.00390 O7 0.01640 0.01220 0.01880 0.00000 0.00680 0.00000