data_global _chemical_name_mineral 'Sadanagaite' loop_ _publ_author_name 'Banno Y' 'Miyawaki R' 'Matsubara S' 'Makino K' 'Bunno M' 'Yamada S' 'Kamiya T' _journal_name_full 'European Journal of Mineralogy' _journal_volume 16 _journal_year 2004 _journal_page_first 177 _journal_page_last 183 _publ_section_title ; Magnesiosadanagaite, a new member of the amphibole group from Kasuga-mura, Gifu Prefecture, central Japan Sample: GSJ M35151-2 ; _database_code_amcsd 0007035 _chemical_compound_source 'Kasuga-mura, Gifu Prefecture, central Japan' _chemical_formula_sum 'Na.74 K.27 Mg3.07 Fe.78 Al3.4 Ti.29 Ca1.97 Mn.02 Si5.46 O23.9 F.07 Cl.03 H1.9' _cell_length_a 9.906 _cell_length_b 17.971 _cell_length_c 5.3190 _cell_angle_alpha 90 _cell_angle_beta 105.48 _cell_angle_gamma 90 _cell_volume 912.542 _exptl_crystal_density_diffrn 3.172 _symmetry_space_group_name_H-M 'C 1 2/m 1' loop_ _space_group_symop_operation_xyz 'x,y,z' '1/2+x,1/2+y,z' 'x,-y,z' '1/2+x,1/2-y,z' '-x,y,-z' '1/2-x,1/2+y,-z' '-x,-y,-z' '1/2-x,1/2-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy _atom_site_U_iso_or_equiv NaA2/m 0.00000 0.50000 0.00000 0.73000 0.11100 KA2/m 0.00000 0.50000 0.00000 0.27000 0.11100 Mg1 0.00000 0.08973 0.50000 0.83000 0.00740 Fe1 0.00000 0.08973 0.50000 0.17000 0.00740 Al2 0.00000 0.17709 0.00000 0.43000 0.01130 Mg2 0.00000 0.17709 0.00000 0.30000 0.01130 Ti2 0.00000 0.17709 0.00000 0.14500 0.01130 Fe2 0.00000 0.17709 0.00000 0.12500 0.01130 Mg3 0.00000 0.00000 0.00000 0.81000 0.00560 Fe3 0.00000 0.00000 0.00000 0.19000 0.00560 Ca4 0.00000 0.28089 0.50000 0.98500 0.00960 Mn4 0.00000 0.28089 0.50000 0.01000 0.00960 Na4 0.00000 0.28089 0.50000 0.00500 0.00960 Si1 0.27942 0.08595 0.30443 0.52500 0.00660 Al1 0.27942 0.08595 0.30443 0.47500 0.00660 Si2 0.29054 0.17353 0.81600 0.84000 0.00680 Al2 0.29054 0.17353 0.81600 0.16000 0.00680 O1 0.10562 0.08934 0.21470 1.00000 0.01190 O2 0.11888 0.17438 0.73710 1.00000 0.01010 O3 0.10880 0.00000 0.71570 0.95000 0.01400 F3 0.10880 0.00000 0.71570 0.03500 0.01400 Cl3 0.10880 0.00000 0.71570 0.01500 0.01400 O4 0.36869 0.25114 0.79140 1.00000 0.01120 O5 0.35101 0.14053 0.11550 1.00000 0.01220 O6 0.34361 0.11710 0.61250 1.00000 0.01310 O7 0.33720 0.00000 0.27660 1.00000 0.01590 H 0.18900 0.00000 0.75000 0.95000 ? loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 NaA2/m 0.06300 0.20500 0.08900 0.00000 0.06200 0.00000 KA2/m 0.06300 0.20500 0.08900 0.00000 0.06200 0.00000 Mg1 0.00850 0.00850 0.00620 0.00000 0.00400 0.00000 Fe1 0.00850 0.00850 0.00620 0.00000 0.00400 0.00000 Al2 0.01190 0.01130 0.01170 0.00000 0.00470 0.00000 Mg2 0.01190 0.01130 0.01170 0.00000 0.00470 0.00000 Ti2 0.01190 0.01130 0.01170 0.00000 0.00470 0.00000 Fe2 0.01190 0.01130 0.01170 0.00000 0.00470 0.00000 Mg3 0.00750 0.00500 0.00420 0.00000 0.00110 0.00000 Fe3 0.00750 0.00500 0.00420 0.00000 0.00110 0.00000 Ca4 0.01090 0.00890 0.01090 0.00000 0.00620 0.00000 Mn4 0.01090 0.00890 0.01090 0.00000 0.00620 0.00000 Na4 0.01090 0.00890 0.01090 0.00000 0.00620 0.00000 Si1 0.00620 0.00690 0.00690 -0.00080 0.00220 0.00000 Al1 0.00620 0.00690 0.00690 -0.00080 0.00220 0.00000 Si2 0.00720 0.00690 0.00700 0.00000 0.00320 0.00030 Al2 0.00720 0.00690 0.00700 0.00000 0.00320 0.00030 O1 0.00950 0.01650 0.00990 -0.00250 0.00300 -0.00070 O2 0.00760 0.01240 0.00990 0.00040 0.00130 0.00140 O3 0.01620 0.01190 0.01410 0.00000 0.00440 0.00000 F3 0.01620 0.01190 0.01410 0.00000 0.00440 0.00000 Cl3 0.01620 0.01190 0.01410 0.00000 0.00440 0.00000 O4 0.01350 0.00940 0.01250 -0.00090 0.00660 0.00010 O5 0.01150 0.01410 0.01140 0.00030 0.00360 0.00490 O6 0.01020 0.01500 0.01420 0.00030 0.00360 -0.00430 O7 0.01150 0.01490 0.01920 0.00000 0.00060 0.00000