Pellouxite Palvadeau P, Meerschaut A, Orlandi P, Moelo Y European Journal of Mineralogy 16 (2004) 845-855 Lead-antimony sulfosalts from Tuscany (Italy). VII. Crystal structure of pellouxite, ~ (Cu,Ag)2Pb21Sb23S55ClO, an expanded monoclinic derivative of Ba12Bi24S48 hexagonal sub-type (zinkenite group) Locality: Tuscany, Italy _database_code_amcsd 0007082 CELL PARAMETERS: 55.8240 4.0892 24.1280 90.000 113.140 90.000 SPACE GROUP: C2/m X-RAY WAVELENGTH: 1.541838 Cell Volume: 5064.712 Density (g/cm3): 5.966 MAX. ABS. INTENSITY / VOLUME**2: 32.93108757 RIR: 1.797 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 3.44 5.94 25.6664 2 0 0 2 3.98 5.29 22.1868 0 0 1 2 4.12 2.39 21.4706 -2 0 1 2 8.24 4.68 10.7353 -4 0 2 2 9.22 2.48 9.5942 4 0 1 2 9.51 9.03 9.3037 -6 0 1 2 10.28 2.54 8.6045 -6 0 2 2 10.34 3.92 8.5555 6 0 0 2 11.22 8.22 7.8875 -4 0 3 2 12.47 6.33 7.1006 6 0 1 2 12.94 5.72 6.8403 -8 0 2 2 14.28 1.20 6.2007 -8 0 3 2 14.70 3.38 6.0265 -4 0 4 2 15.81 3.19 5.6042 8 0 1 2 15.98 1.13 5.5467 0 0 4 2 18.37 3.30 4.8309 -10 0 4 2 18.69 2.06 4.7476 6 0 3 2 19.08 3.71 4.6519 -12 0 2 2 19.47 2.81 4.5602 -12 0 3 2 19.53 5.03 4.5455 -12 0 1 2 20.65 1.79 4.3023 -12 0 4 2 21.61 19.33 4.1123 8 0 3 2 21.80 3.61 4.0763 1 1 0 4 22.05 7.18 4.0316 -1 1 1 4 22.13 12.69 4.0177 -6 0 6 2 22.25 26.84 3.9955 -4 0 6 2 22.27 3.03 3.9927 6 0 4 2 22.30 10.32 3.9871 1 1 1 4 22.35 1.06 3.9783 -14 0 2 2 22.44 5.05 3.9627 -14 0 3 2 22.50 2.57 3.9520 -12 0 5 2 22.66 10.89 3.9235 12 0 1 2 22.91 21.37 3.8816 -2 0 6 2 23.01 8.20 3.8654 -1 1 2 4 23.06 11.57 3.8575 -3 1 2 4 23.08 9.55 3.8541 3 1 1 4 23.17 9.20 3.8385 -5 1 1 4 23.24 5.73 3.8281 -14 0 4 2 23.42 23.78 3.7989 5 1 0 4 23.48 5.52 3.7884 -10 0 6 2 23.48 3.56 3.7881 1 1 2 4 23.63 5.32 3.7658 -5 1 2 4 23.65 6.90 3.7619 4 0 5 2 24.34 6.07 3.6570 5 1 1 4 24.42 33.09 3.6444 -3 1 3 4 24.46 9.11 3.6397 3 1 2 4 24.48 3.49 3.6370 -7 1 1 4 24.61 3.87 3.6180 -1 1 3 4 24.68 9.24 3.6070 -7 1 2 4 24.69 4.14 3.6053 10 0 3 2 25.01 26.41 3.5607 8 0 4 2 25.08 26.85 3.5503 12 0 2 2 25.54 5.64 3.4881 -7 1 3 4 25.56 1.05 3.4856 -16 0 3 2 25.70 9.21 3.4670 -16 0 2 2 25.86 3.03 3.4458 -6 0 7 2 26.00 1.60 3.4269 6 0 5 2 26.01 36.88 3.4263 -8 0 7 2 26.05 100.00 3.4201 -16 0 4 2 26.14 3.26 3.4085 14 0 1 2 26.18 25.82 3.4042 -4 0 7 2 26.19 2.01 3.4028 -9 1 1 4 26.35 8.06 3.3818 -3 1 4 4 26.40 3.01 3.3765 3 1 3 4 26.44 9.96 3.3712 -5 1 4 4 26.73 3.38 3.3347 -1 1 4 4 26.77 1.30 3.3298 -9 1 3 4 26.83 4.05 3.3233 9 1 0 4 26.96 8.85 3.3077 -2 0 7 2 26.98 2.09 3.3045 -7 1 4 4 27.56 2.12 3.2368 1 1 4 4 27.60 1.44 3.2314 4 0 6 2 27.67 2.50 3.2244 7 1 2 4 27.67 2.28 3.2238 -12 0 7 2 27.90 38.67 3.1981 12 0 3 2 28.03 15.22 3.1836 -11 1 2 4 28.15 3.17 3.1695 0 0 7 2 28.40 5.51 3.1430 -11 1 3 4 28.48 2.84 3.1337 14 0 2 2 28.60 8.23 3.1208 8 0 5 2 28.62 34.81 3.1185 -5 1 5 4 28.79 1.29 3.1012 -18 0 3 2 28.80 2.30 3.1003 -16 0 6 2 29.03 15.81 3.0755 11 1 0 4 29.04 10.08 3.0748 -18 0 4 2 29.11 1.23 3.0672 -14 0 7 2 29.28 23.93 3.0497 -1 1 5 4 29.33 16.64 3.0449 -11 1 4 4 29.65 18.35 3.0133 -8 0 8 2 29.73 1.03 3.0053 2 0 7 2 29.78 30.96 3.0003 9 1 2 4 29.79 9.89 2.9992 7 1 3 4 30.01 2.33 2.9780 -10 0 8 2 30.18 1.05 2.9617 -4 0 8 2 30.19 9.31 2.9602 -13 1 2 4 30.23 6.88 2.9563 1 1 5 4 30.35 12.11 2.9449 -13 1 3 4 30.36 50.06 2.9444 11 1 1 4 30.39 17.22 2.9412 5 1 4 4 30.58 25.31 2.9235 -13 1 1 4 30.79 4.26 2.9043 -11 1 5 4 31.01 7.57 2.8834 12 0 4 2 31.04 3.06 2.8809 -2 0 8 2 31.05 9.98 2.8801 -13 1 4 4 31.20 13.08 2.8671 14 0 3 2 31.20 1.18 2.8663 -5 1 6 4 31.31 44.46 2.8566 -7 1 6 4 31.40 1.30 2.8485 10 0 5 2 31.49 3.48 2.8406 -3 1 6 4 31.50 16.82 2.8405 13 1 0 4 31.63 1.29 2.8291 4 0 7 2 31.82 7.18 2.8126 -9 1 6 4 31.91 1.49 2.8049 -14 0 8 2 31.95 2.83 2.8010 9 1 3 4 32.15 6.69 2.7839 11 1 2 4 32.16 1.03 2.7832 -20 0 4 2 32.17 23.49 2.7823 -1 1 6 4 32.26 23.59 2.7749 -13 1 5 4 32.31 15.27 2.7711 7 1 4 4 32.58 7.60 2.7481 -15 1 3 4 32.61 13.65 2.7460 -15 1 2 4 32.70 1.33 2.7389 -11 1 6 4 32.73 6.86 2.7361 -20 0 5 2 32.90 3.75 2.7223 13 1 1 4 33.14 10.94 2.7030 -15 1 1 4 33.20 10.52 2.6985 5 1 5 4 33.22 1.25 2.6972 1 1 6 4 33.43 6.05 2.6808 -8 0 9 2 33.58 4.49 2.6689 -10 0 9 2 33.65 1.65 2.6636 -6 0 9 2 33.80 1.32 2.6520 6 0 7 2 34.04 10.84 2.6341 -7 1 7 4 34.05 7.73 2.6332 -15 1 5 4 34.10 3.04 2.6292 -12 0 9 2 34.21 1.41 2.6213 14 0 4 2 34.34 2.50 2.6117 -9 1 7 4 34.49 2.80 2.6003 9 1 4 4 34.54 6.63 2.5970 -3 1 7 4 34.98 2.80 2.5651 -14 0 9 2 35.00 7.09 2.5639 -11 1 7 4 35.05 1.24 2.5602 -17 1 3 4 35.14 3.69 2.5537 7 1 5 4 35.24 1.27 2.5471 -17 1 2 4 35.32 1.34 2.5409 -1 1 7 4 35.34 3.22 2.5396 -17 1 4 4 35.50 4.28 2.5285 -22 0 3 2 35.64 4.08 2.5192 15 1 1 4 36.00 4.85 2.4947 -13 1 7 4 36.28 3.37 2.4759 5 1 6 4 36.45 8.23 2.4652 1 1 7 4 36.91 2.09 2.4355 11 1 4 4 37.04 3.58 2.4270 -7 1 8 4 37.13 1.28 2.4216 -22 0 1 2 37.32 2.00 2.4097 -17 1 6 4 37.34 4.25 2.4085 9 1 5 4 37.52 2.92 2.3972 15 1 2 4 37.63 1.98 2.3904 -11 1 8 4 37.71 1.98 2.3856 -18 0 9 2 37.71 5.38 2.3854 -19 1 3 4 37.83 1.69 2.3783 6 0 8 2 38.04 9.59 2.3656 -19 1 2 4 38.24 10.13 2.3537 7 1 6 4 38.41 3.56 2.3438 -19 1 5 4 38.42 6.16 2.3429 -13 1 8 4 38.54 3.94 2.3361 17 1 1 4 38.69 5.20 2.3270 -1 1 8 4 38.90 1.51 2.3152 -24 0 5 2 38.97 1.30 2.3113 -24 0 3 2 39.41 10.39 2.2866 -19 1 6 4 39.59 11.54 2.2763 5 1 7 4 39.66 4.90 2.2728 -24 0 2 2 39.75 3.48 2.2677 11 1 5 4 39.76 1.59 2.2673 15 1 3 4 39.86 10.68 2.2619 4 0 9 2 39.88 1.14 2.2604 1 1 8 4 40.00 1.86 2.2542 19 1 0 4 40.45 5.06 2.2301 17 1 2 4 40.51 6.05 2.2266 -21 1 4 4 40.53 8.54 2.2256 -18 0 10 2 40.54 6.22 2.2252 -11 1 9 4 40.54 6.60 2.2251 -21 1 3 4 40.63 1.20 2.2207 -5 1 9 4 40.76 2.02 2.2137 -24 0 1 2 40.81 11.80 2.2110 -19 1 7 4 41.14 5.54 2.1940 -13 1 9 4 41.35 2.46 2.1832 3 1 8 4 41.53 2.46 2.1745 20 0 3 2 41.58 2.52 2.1721 19 1 1 4 42.08 2.28 2.1471 -20 0 10 2 42.25 1.93 2.1392 -1 1 9 4 42.25 14.54 2.1389 24 0 0 2 42.31 2.14 2.1364 15 1 4 4 42.59 1.75 2.1228 -19 1 8 4 42.60 1.75 2.1223 -26 0 6 2 42.69 1.71 2.1178 17 1 3 4 42.84 1.40 2.1110 11 1 6 4 43.09 6.63 2.0993 5 1 8 4 43.11 1.33 2.0981 21 1 0 4 43.24 7.55 2.0922 -17 1 9 4 43.49 3.67 2.0809 1 1 9 4 43.55 1.91 2.0780 -9 1 10 4 43.59 3.80 2.0762 -23 1 5 4 43.61 2.63 2.0756 -18 0 11 2 43.61 6.30 2.0755 -2 0 11 2 43.69 2.95 2.0719 -11 1 10 4 43.89 1.70 2.0628 -22 0 10 2 44.07 2.44 2.0549 4 0 10 2 44.10 5.92 2.0533 24 0 1 2 44.23 1.09 2.0478 -23 1 6 4 44.24 2.99 2.0476 8 0 9 2 44.30 62.16 2.0446 0 2 0 2 44.50 1.45 2.0360 -21 1 8 4 44.70 1.70 2.0272 -19 1 9 4 44.93 1.59 2.0176 -3 1 10 4 44.94 7.38 2.0171 -20 0 11 2 44.94 2.91 2.0170 0 0 11 2 45.00 1.29 2.0146 3 1 9 4 45.06 4.91 2.0119 7 1 8 4 45.12 1.49 2.0094 -10 0 12 2 45.13 3.44 2.0091 15 1 5 4 45.24 2.12 2.0044 17 1 4 4 45.25 1.59 2.0040 -23 1 7 4 45.85 3.03 1.9791 -17 1 10 4 45.96 1.06 1.9745 -6 0 12 2 46.09 3.68 1.9694 -28 0 3 2 46.13 3.69 1.9679 6 0 10 2 46.34 2.39 1.9593 -25 1 4 4 46.35 5.70 1.9591 23 1 0 4 46.41 7.51 1.9563 -21 1 9 4 46.63 5.36 1.9477 -23 1 8 4 46.73 4.39 1.9440 10 0 9 2 46.75 2.67 1.9430 5 1 9 4 46.81 2.02 1.9408 -4 0 12 2 46.90 1.31 1.9374 -18 0 12 2 46.91 4.12 1.9367 -25 1 6 4 46.95 3.66 1.9353 -28 0 2 2 47.25 13.59 1.9237 1 1 10 4 47.29 7.38 1.9223 -25 1 2 4 47.38 2.38 1.9188 20 0 5 2 47.60 3.25 1.9105 16 0 7 2 47.89 9.51 1.8996 -15 1 11 4 48.01 7.15 1.8950 23 1 1 4 48.05 3.59 1.8935 17 1 5 4 48.17 3.83 1.8890 -28 0 1 2 48.17 2.45 1.8889 -26 0 10 2 48.31 1.31 1.8839 19 1 4 4 48.35 4.60 1.8824 -24 0 11 2 48.39 1.25 1.8810 8 0 10 2 48.64 2.07 1.8719 -21 1 10 4 48.64 1.12 1.8718 -12 2 2 4 48.72 2.84 1.8691 -17 1 11 4 48.84 1.01 1.8647 -12 2 1 4 48.96 4.44 1.8604 21 1 3 4 49.09 3.33 1.8560 -12 0 13 2 49.10 1.50 1.8555 -30 0 6 2 49.29 2.30 1.8489 0 0 12 2 49.64 7.56 1.8366 11 1 8 4 49.69 1.77 1.8350 25 1 0 4 49.73 3.63 1.8333 28 0 0 2 49.76 2.55 1.8325 -27 1 6 4 49.81 2.78 1.8308 8 2 3 4 49.81 1.11 1.8307 -19 1 11 4 49.81 1.07 1.8306 -1 1 11 4 49.85 3.71 1.8293 -27 1 3 4 49.99 2.59 1.8244 23 1 2 4 50.06 2.95 1.8222 -6 2 6 4 50.12 5.72 1.8201 -4 2 6 4 50.23 2.53 1.8162 -6 0 13 2 50.32 2.26 1.8132 12 2 1 4 50.40 3.89 1.8108 -26 0 11 2 50.40 6.63 1.8108 -23 1 10 4 50.45 3.84 1.8090 -2 2 6 4 50.57 1.51 1.8050 5 1 10 4 50.59 2.46 1.8043 -11 1 12 4 50.61 1.46 1.8035 -14 2 4 4 50.71 5.86 1.8003 -9 1 12 4 50.74 1.01 1.7993 -10 2 6 4 50.83 1.44 1.7964 4 2 5 4 51.05 1.38 1.7892 -24 0 12 2 51.10 5.81 1.7874 17 1 6 4 51.32 2.14 1.7803 16 0 8 2 51.49 2.48 1.7750 -27 1 8 4 51.50 2.01 1.7743 21 1 4 4 51.54 4.75 1.7731 8 2 4 4 51.58 6.83 1.7718 12 2 2 4 51.70 5.54 1.7682 -27 1 1 4 51.75 5.41 1.7666 -5 1 12 4 51.92 1.40 1.7612 -16 2 2 4 52.09 7.21 1.7557 -8 2 7 4 52.12 20.06 1.7549 -16 2 4 4 52.19 4.99 1.7528 -4 2 7 4 52.51 3.85 1.7428 -32 0 6 2 52.56 1.99 1.7412 7 1 10 4 52.63 2.10 1.7392 -2 2 7 4 52.65 1.40 1.7384 -3 1 12 4 52.69 1.08 1.7371 -29 1 4 4 52.75 1.27 1.7355 -29 1 6 4 53.17 8.59 1.7226 12 2 3 4 53.20 1.14 1.7219 -14 0 14 2 53.29 2.46 1.7190 -29 1 7 4 53.48 1.99 1.7135 12 0 10 2 53.59 1.49 1.7102 8 2 5 4 53.59 6.81 1.7101 -32 0 8 2 53.85 2.21 1.7025 -18 2 4 4 53.86 2.07 1.7021 -8 0 14 2 54.09 4.00 1.6954 22 0 6 2 54.15 1.81 1.6937 19 1 6 4 54.21 3.94 1.6919 -8 2 8 4 54.32 1.32 1.6888 -13 1 13 4 54.36 1.08 1.6876 17 1 7 4 54.45 2.55 1.6850 24 0 5 2 54.53 1.33 1.6828 -9 1 13 4 54.54 1.70 1.6824 -27 1 10 4 54.76 1.05 1.6763 6 0 12 2 54.82 1.13 1.6747 23 1 4 4 55.06 2.31 1.6679 12 2 4 4 55.18 3.72 1.6647 14 2 3 4 55.19 1.64 1.6642 16 0 9 2 55.39 1.58 1.6589 -29 1 9 4 55.57 1.15 1.6539 -4 0 14 2 55.79 1.22 1.6477 -31 1 5 4 56.01 1.01 1.6419 -32 0 10 2 56.02 1.11 1.6417 -34 0 6 2 56.16 2.47 1.6378 -20 2 5 4 56.61 1.31 1.6257 -8 2 9 4 56.72 1.11 1.6231 -10 2 9 4 56.72 1.59 1.6230 -3 1 13 4 57.06 1.16 1.6140 -12 2 9 4 57.21 1.04 1.6103 -30 0 12 2 57.65 1.66 1.5990 24 0 6 2 57.65 1.27 1.5988 -14 2 9 4 57.86 2.64 1.5937 -18 0 15 2 58.01 1.71 1.5899 -22 2 3 4 58.24 1.04 1.5842 -15 1 14 4 60.95 2.23 1.5200 -24 2 2 4 61.00 1.67 1.5189 3 1 13 4 61.10 5.02 1.5168 4 2 9 4 61.32 1.19 1.5118 -27 1 13 4 61.60 3.55 1.5057 -18 2 10 4 62.12 1.71 1.4942 31 1 1 4 62.34 1.39 1.4896 20 2 3 4 62.42 1.01 1.4877 15 1 10 4 62.51 2.83 1.4859 -35 1 6 4 62.75 1.20 1.4806 -20 2 10 4 62.88 6.12 1.4780 24 2 0 4 63.21 1.50 1.4710 -29 1 13 4 63.69 4.95 1.4611 13 1 11 4 63.91 1.15 1.4566 -18 2 11 4 63.91 2.89 1.4566 -2 2 11 4 64.04 1.61 1.4539 33 1 0 4 64.13 1.05 1.4522 -22 2 10 4 64.27 1.05 1.4494 4 2 10 4 64.29 2.12 1.4488 24 2 1 4 64.40 1.57 1.4468 8 2 9 4 64.52 1.45 1.4443 19 1 9 4 64.94 3.18 1.4359 -20 2 11 4 64.94 1.22 1.4359 0 2 11 4 65.04 1.24 1.4340 -35 1 10 4 65.26 2.04 1.4297 -3 1 15 4 65.85 1.95 1.4184 -28 2 3 4 65.87 1.63 1.4179 6 2 10 4 65.91 1.00 1.4172 33 1 1 4 66.35 2.28 1.4088 10 2 9 4 66.53 2.19 1.4055 -28 2 2 4 66.59 1.51 1.4043 -19 1 16 4 66.87 1.36 1.3992 20 2 5 4 67.05 1.57 1.3959 16 2 7 4 67.51 1.79 1.3875 -28 2 1 4 67.51 1.24 1.3875 -26 2 10 4 67.62 1.09 1.3854 -37 1 3 4 67.65 2.07 1.3849 -24 2 11 4 67.71 1.36 1.3839 16 0 12 2 68.04 1.53 1.3778 33 1 2 4 68.25 2.17 1.3742 -12 2 13 4 68.31 1.08 1.3731 -6 0 17 2 68.41 1.12 1.3714 0 2 12 4 68.78 2.27 1.3650 28 2 0 4 69.09 3.85 1.3596 -25 1 16 4 69.19 1.39 1.3579 -6 2 13 4 69.32 1.83 1.3556 -26 2 11 4 69.58 1.38 1.3512 11 1 13 4 69.84 4.35 1.3467 3 1 15 4 70.08 1.09 1.3427 16 2 8 4 70.16 1.20 1.3413 -37 1 1 4 70.52 4.28 1.3355 -31 1 15 4 70.54 2.17 1.3351 -19 1 17 4 71.08 1.79 1.3263 -32 2 6 4 71.51 1.34 1.3193 -39 1 3 4 71.89 1.18 1.3133 12 2 10 4 71.99 1.05 1.3118 35 1 2 4 71.99 3.56 1.3117 -32 2 8 4 71.99 1.02 1.3117 -5 3 5 4 72.18 1.00 1.3087 13 1 13 4 72.22 1.10 1.3081 -8 2 14 4 72.41 2.24 1.3051 22 2 6 4 72.59 1.08 1.3024 9 3 2 4 72.67 1.93 1.3011 -37 1 13 4 72.72 1.75 1.3003 24 2 5 4 72.89 2.01 1.2978 11 3 1 4 73.01 1.11 1.2959 -13 3 1 4 73.40 1.78 1.2900 -7 3 6 4 73.41 1.18 1.2898 -41 1 6 4 73.80 2.02 1.2840 -39 1 12 4 73.87 1.48 1.2829 -1 3 6 4 73.92 1.28 1.2822 -13 3 5 4 73.95 1.22 1.2818 7 3 4 4 74.19 1.25 1.2781 -39 1 1 4 74.60 1.22 1.2721 -41 1 10 4 74.65 3.39 1.2714 29 1 7 4 75.48 1.02 1.2596 24 2 6 4 75.66 1.66 1.2570 -18 2 15 4 78.44 1.22 1.2193 25 1 10 4 79.42 3.57 1.2066 -13 1 19 4 79.76 1.24 1.2023 -42 0 15 2 81.01 1.25 1.1869 24 0 12 2 83.68 1.14 1.1557 1 3 10 4 84.55 1.19 1.1460 16 2 12 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.