data_global
_chemical_name_mineral 'Phlogopite'
loop_
_publ_author_name
'Brigatti M F'
'Caprilli E'
'Funiciello R'
'Giordano G'
'Mottana A'
'Poppi L'
_journal_name_full 'European Journal of Mineralogy'
_journal_volume 17 
_journal_year 2005
_journal_page_first 611
_journal_page_last 621
_publ_section_title
;
 Crystal chemisty of ferroan phlogopites from the Albano maar lake
 (Colli Albani volcano, central Italy)
 Sample: CC
;
_database_code_amcsd 0007120
_chemical_compound_source 'Colli Albani volcano, central Italy'
_chemical_formula_sum 'Ba.035 K.964 Al1.336 Ti.123 Cr.003 Fe.606 Mg2.226 Mn.009 Si2.7 O12'
_cell_length_a 5.385
_cell_length_b 9.202
_cell_length_c 10.181
_cell_angle_alpha 90
_cell_angle_beta 100.13
_cell_angle_gamma 90
_cell_volume 496.632
_exptl_crystal_density_diffrn      2.948
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
BaA   0.00000   0.50000   0.00000   0.03500   0.02710
KA   0.00000   0.50000   0.00000   0.96400   0.02710
AlM1   0.00000   0.00000   0.50000   0.01200   0.01001
TiM1   0.00000   0.00000   0.50000   0.04100   0.01001
Cr3+M1   0.00000   0.00000   0.50000   0.00100   0.01001
Fe2+M1   0.00000   0.00000   0.50000   0.20200   0.01001
MgM1   0.00000   0.00000   0.50000   0.74200   0.01001
MnM1   0.00000   0.00000   0.50000   0.00300   0.01001
AlM2   0.00000   0.33910   0.50000   0.01200   0.01165
TiM2   0.00000   0.33910   0.50000   0.04100   0.01165
Cr3+M2   0.00000   0.33910   0.50000   0.00100   0.01165
Fe2+M2   0.00000   0.33910   0.50000   0.20200   0.01165
MgM2   0.00000   0.33910   0.50000   0.74200   0.01165
MnM2   0.00000   0.33910   0.50000   0.00300   0.01165
SiT   0.07390   0.16690   0.22510   0.67500   0.00899
AlT   0.07390   0.16690   0.22510   0.32500   0.00899
O1   0.00890   0.00000   0.16920   1.00000   0.01760
O2   0.32860   0.22720   0.16750   1.00000   0.01824
O3   0.12980   0.16800   0.39190   1.00000   0.01077
O4   0.13430   0.50000   0.40080   1.00000   0.01077
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
BaA 0.02890 0.02531 0.02697 0.00000 0.00350 0.00000
KA 0.02890 0.02531 0.02697 0.00000 0.00350 0.00000
AlM1 0.01153 0.00729 0.01120 0.00000 0.00242 0.00000
TiM1 0.01153 0.00729 0.01120 0.00000 0.00242 0.00000
Cr3+M1 0.01153 0.00729 0.01120 0.00000 0.00242 0.00000
Fe2+M1 0.01153 0.00729 0.01120 0.00000 0.00242 0.00000
MgM1 0.01153 0.00729 0.01120 0.00000 0.00242 0.00000
MnM1 0.01153 0.00729 0.01120 0.00000 0.00242 0.00000
AlM2 0.01153 0.01287 0.01018 0.00000 0.00054 0.00000
TiM2 0.01153 0.01287 0.01018 0.00000 0.00054 0.00000
Cr3+M2 0.01153 0.01287 0.01018 0.00000 0.00054 0.00000
Fe2+M2 0.01153 0.01287 0.01018 0.00000 0.00054 0.00000
MgM2 0.01153 0.01287 0.01018 0.00000 0.00054 0.00000
MnM2 0.01153 0.01287 0.01018 0.00000 0.00054 0.00000
SiT 0.01182 0.00729 0.00763 0.00025 0.00054 0.00000
AlT 0.01182 0.00729 0.00763 0.00025 0.00054 0.00000
O1 0.02520 0.01287 0.01323 0.00000 -0.00135 0.00000
O2 0.02064 0.02102 0.01323 -0.00593 0.00377 -0.00374
O3 0.01438 0.00987 0.00814 0.00000 0.00108 0.00000
O4 0.01395 0.01030 0.00763 0.00000 0.00027 0.00000