data_global
_chemical_name_mineral 'Phlogopite'
loop_
_publ_author_name
'Brigatti M F'
'Caprilli E'
'Funiciello R'
'Giordano G'
'Mottana A'
'Poppi L'
_journal_name_full 'European Journal of Mineralogy'
_journal_volume 17 
_journal_year 2005
_journal_page_first 611
_journal_page_last 621
_publ_section_title
;
 Crystal chemisty of ferroan phlogopites from the Albano maar lake
 (Colli Albani volcano, central Italy)
 Sample: 6B
;
_database_code_amcsd 0007124
_chemical_compound_source 'Colli Albani volcano, central Italy'
_chemical_formula_sum 'Ba.005 K.994 Al1.452 Ti.144 Fe.597 Mg1.848 Si2.896 O12'
_cell_length_a 5.3235
_cell_length_b 9.217
_cell_length_c 10.243
_cell_angle_alpha 90
_cell_angle_beta 99.98
_cell_angle_gamma 90
_cell_volume 494.985
_exptl_crystal_density_diffrn      2.933
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
BaA   0.00000   0.50000   0.00000   0.00500   0.03065
KA   0.00000   0.50000   0.00000   0.99400   0.03065
AlM1   0.00000   0.00000   0.50000   0.11600   0.00950
TiM1   0.00000   0.00000   0.50000   0.04800   0.00950
Fe2+M1   0.00000   0.00000   0.50000   0.19900   0.00950
MgM1   0.00000   0.00000   0.50000   0.61600   0.00950
AlM2   0.00000   0.33440   0.50000   0.11600   0.00975
TiM2   0.00000   0.33440   0.50000   0.04800   0.00975
Fe2+M2   0.00000   0.33440   0.50000   0.19900   0.00975
MgM2   0.00000   0.33440   0.50000   0.61600   0.00975
SiT   0.07550   0.16680   0.22680   0.72400   0.00785
AlT   0.07550   0.16680   0.22680   0.27600   0.00785
O1   0.00830   0.00000   0.17030   1.00000   0.01798
O2   0.33080   0.22550   0.17020   1.00000   0.01773
O3   0.13030   0.16720   0.39170   1.00000   0.01013
O4   0.13270   0.50000   0.39860   1.00000   0.01064
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
BaA 0.03175 0.03185 0.02836 0.00000 0.00536 0.00000
KA 0.03175 0.03185 0.02836 0.00000 0.00536 0.00000
AlM1 0.00808 0.00646 0.01444 0.00000 0.00348 0.00000
TiM1 0.00808 0.00646 0.01444 0.00000 0.00348 0.00000
Fe2+M1 0.00808 0.00646 0.01444 0.00000 0.00348 0.00000
MgM1 0.00808 0.00646 0.01444 0.00000 0.00348 0.00000
AlM2 0.00668 0.00990 0.01237 0.00000 0.00134 0.00000
TiM2 0.00668 0.00990 0.01237 0.00000 0.00134 0.00000
Fe2+M2 0.00668 0.00990 0.01237 0.00000 0.00134 0.00000
MgM2 0.00668 0.00990 0.01237 0.00000 0.00134 0.00000
SiT 0.00641 0.00689 0.00980 0.00000 0.00161 0.00000
AlT 0.00641 0.00689 0.00980 0.00000 0.00161 0.00000
O1 0.02465 0.01291 0.01444 0.00000 -0.00134 0.00000
O2 0.01601 0.02195 0.01547 -0.00465 0.00348 -0.00377
O3 0.00961 0.00904 0.01186 0.00000 0.00188 0.00047
O4 0.00933 0.01033 0.01186 0.00000 0.00188 0.00000