data_global
_chemical_name_mineral 'Phlogopite'
loop_
_publ_author_name
'Ventruti G'
'Levy D'
'Pavese A'
'Scordari F'
'Suard E'
_journal_name_full 'European Journal of Mineralogy'
_journal_volume 21 
_journal_year 2009
_journal_page_first 385
_journal_page_last 396
_publ_section_title
;
 High-temperature treatment, hydrogen behaviour and cation
 partitioning of a Fe-Ti bearing volcanic phlogopite by in situ neutron
 powder diffraction and FTIR spectroscopy
 Note: Phlogopite-1M
 Note: T = 298 K, X-Ray
;
_database_code_amcsd 0007278
_chemical_compound_source 'Cava St.Antonio, Mt.Vulture, Italy'
_chemical_formula_sum 'K.86 Na.08 Ba.04 Mg1.97 Fe.67 Al1.45 Mn.01 Ti.18 Si2.72 O11.88 F.12 H1.2'
_cell_length_a 5.3305
_cell_length_b 9.2301
_cell_length_c 10.2241
_cell_angle_alpha 90
_cell_angle_beta 100.018
_cell_angle_gamma 90
_cell_volume 495.367
_exptl_crystal_density_diffrn      2.980
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
K   0.00000   0.50000   0.00000   0.86000   0.02470
Na   0.00000   0.50000   0.00000   0.08000   0.02470
Ba   0.00000   0.50000   0.00000   0.04000   0.02470
MgM1   0.00000   0.00000   0.50000   0.59000   0.00530
FeM1   0.00000   0.00000   0.50000   0.23000   0.00530
AlM1   0.00000   0.00000   0.50000   0.17000   0.00530
MnM1   0.00000   0.00000   0.50000   0.01000   0.00530
MgM2   0.00000   0.33470   0.50000   0.69000   0.00890
FeM2   0.00000   0.33470   0.50000   0.22000   0.00890
TiM2   0.00000   0.33470   0.50000   0.09000   0.00890
SiT   0.07800   0.16610   0.22540   0.68000   0.00930
AlT   0.07800   0.16610   0.22540   0.32000   0.00930
O1   0.33100   0.22790   0.16680   1.00000   0.02640
O2   0.01000   0.00000   0.16470   1.00000   0.02040
O3   0.13100   0.16760   0.39200   1.00000   0.01130
O4   0.13300   0.50000   0.39770   0.34000   0.01640
O-H4   0.13300   0.50000   0.39770   0.60000   0.01640
F4   0.13300   0.50000   0.39770   0.06000   0.01640