data_global
_chemical_name_mineral 'Cupromolybdite'
loop_
_publ_author_name
'Zelenski M E'
'Zubkova N V'
'Pekov I V'
'Polekhovsky Y S'
'Pushcharovsky D Y'
_journal_name_full 'European Journal of Mineralogy'
_journal_volume 24 
_journal_year 2012
_journal_page_first 749
_journal_page_last 757
_publ_section_title
;
 Cupromolybdite, Cu3O(MoO4)2, a new fumarolic mineral from
 the Tolbachik volcano, Kamchatka Peninsula, Russia
;
_database_code_amcsd 0019362
_chemical_compound_source 'the Tolbachik volcano, Kamchatka Peninsula, Russia'
_chemical_formula_sum 'Mo1.94 S.06 Cu3 O9'
_cell_length_a 7.6638
_cell_length_b 6.8670
_cell_length_c 14.5554
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 766.012
_exptl_crystal_density_diffrn      4.532
_symmetry_space_group_name_H-M 'P n m a'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2-y,z'
  '-x,1/2+y,-z'
  '1/2-x,1/2+y,1/2+z'
  '1/2+x,1/2-y,1/2-z'
  '1/2+x,y,1/2-z'
  '1/2-x,-y,1/2+z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Mo1   0.26159   0.25000   0.16717   1.00000   0.01409
Mo2   0.15141   0.75000   0.38593   0.94000   0.01329
S2   0.15141   0.75000   0.38593   0.06000   0.01329
Cu1   0.00000   0.00000   0.00000   1.00000   0.01350
Cu2   0.16122   0.75000   0.14124   1.00000   0.01502
Cu3   0.20362   0.25000   0.43602   1.00000   0.01650
O1   0.08970   0.75000   0.01410   1.00000   0.01380
O2   0.19730   0.75000   0.26930   1.00000   0.03780
O3   0.43030   0.75000   0.09700   1.00000   0.03770
O4   0.24440   0.96000   0.43609   1.00000   0.02150
O5   0.13940   0.03880   0.13535   1.00000   0.02070
O6   0.29620   0.25000   0.28310   1.00000   0.03110
O7   0.46510   0.25000   0.11120   1.00000   0.02800