data_global
_chemical_name_mineral 'Graulichite-(La)'
loop_
_publ_author_name
'Biagioni C'
'Ciriotti M E'
'Favreau G'
'Mauro D'
'Zaccarini F'
_journal_name_full 'European Journal of Mineralogy'
_journal_volume 34 
_journal_year 2022
_journal_page_first 365
_journal_page_last 374
_publ_section_title
;
 Graulichite-(La), LaFe3+3(AsO4)2(OH)6, a new addition to the alunite supergroup
 from the Patte d'Oie mine, Bou Skour mining district, Morocco
;
_database_code_amcsd 0021068
_chemical_compound_source 'Patte d'Oie mine, Bou Skour, Morocco'
_chemical_formula_sum '(La.43 Ce.25 Ca.11 Sr.1 Pb.06 K.05) (Fe2.37 Al.45 Cu.18) (As.86 P.48 S.66) O14 H6'
_cell_length_a 7.252
_cell_length_b 7.252
_cell_length_c 16.77
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 763.799
_exptl_crystal_density_diffrn      3.970
_symmetry_space_group_name_H-M 'R -3 m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '2/3+x,1/3+y,1/3+z'
  '1/3+x,2/3+y,2/3+z'
  'x,x-y,z'
  '2/3+x,1/3+x-y,1/3+z'
  '1/3+x,2/3+x-y,2/3+z'
  'y,x,-z'
  '2/3+y,1/3+x,1/3-z'
  '1/3+y,2/3+x,2/3-z'
  '-x+y,y,z'
  '2/3-x+y,1/3+y,1/3+z'
  '1/3-x+y,2/3+y,2/3+z'
  '-x,-x+y,-z'
  '2/3-x,1/3-x+y,1/3-z'
  '1/3-x,2/3-x+y,2/3-z'
  '-y,-x,z'
  '2/3-y,1/3-x,1/3+z'
  '1/3-y,2/3-x,2/3+z'
  'x-y,-y,-z'
  '2/3+x-y,1/3-y,1/3-z'
  '1/3+x-y,2/3-y,2/3-z'
  'y,-x+y,-z'
  '2/3+y,1/3-x+y,1/3-z'
  '1/3+y,2/3-x+y,2/3-z'
  '-x+y,-x,z'
  '2/3-x+y,1/3-x,1/3+z'
  '1/3-x+y,2/3-x,2/3+z'
  '-x,-y,-z'
  '2/3-x,1/3-y,1/3-z'
  '1/3-x,2/3-y,2/3-z'
  '-y,x-y,z'
  '2/3-y,1/3+x-y,1/3+z'
  '1/3-y,2/3+x-y,2/3+z'
  'x-y,x,-z'
  '2/3+x-y,1/3+x,1/3-z'
  '1/3+x-y,2/3+x,2/3-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
LaA   0.00000   0.00000   0.00000   0.43000   0.03000
CeA   0.00000   0.00000   0.00000   0.25000   0.03000
CaA   0.00000   0.00000   0.00000   0.11000   0.03000
SrA   0.00000   0.00000   0.00000   0.10000   0.03000
PbA   0.00000   0.00000   0.00000   0.06000   0.03000
KA   0.00000   0.00000   0.00000   0.05000   0.03000
FeB   0.50000   0.50000   0.50000   0.79000   0.01500
AlB   0.50000   0.50000   0.50000   0.15000   0.01500
CuB   0.50000   0.50000   0.50000   0.06000   0.01500
AsX   0.00000   0.00000   0.31630   0.43000   0.02000
PX   0.00000   0.00000   0.31630   0.24000   0.02000
SX   0.00000   0.00000   0.31630   0.33000   0.02000
O1   0.00000   0.00000   0.41500   1.00000   0.02500
O2   0.21900  -0.21900  -0.05200   1.00000   0.02500
O-H   0.12000  -0.12000   0.13200   1.00000   0.02500