Pumpellyite-(Fe2+) Artioli G, Geiger C A Physics and Chemistry of Minerals 20 (1994) 443-453 The crystal chemistry of pumpellyite: An X-ray Rietveld refinement and 57Fe Mossbauer study Note: sample BU Locality: Torrente Bulla, Italy _database_code_amcsd 0007761 CELL PARAMETERS: 8.8375 5.9520 19.1812 90.000 97.461 90.000 SPACE GROUP: A2/m X-RAY WAVELENGTH: 1.541838 Cell Volume: 1000.404 Density (g/cm3): 3.271 MAX. ABS. INTENSITY / VOLUME**2: 5.814259244 RIR: 0.579 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 9.30 5.98 9.5094 0 0 2 2 10.09 3.10 8.7627 1 0 0 2 12.82 2.55 6.9064 -1 0 2 2 14.61 7.86 6.0636 1 0 2 2 18.28 9.33 4.8531 -1 1 1 4 18.66 26.90 4.7547 0 0 4 2 18.95 47.77 4.6843 1 1 1 4 20.06 5.21 4.4270 -1 0 4 2 20.27 18.57 4.3813 2 0 0 2 22.04 6.60 4.0338 -1 1 3 4 22.40 2.76 3.9687 1 0 4 2 23.43 49.62 3.7963 2 0 2 2 23.68 3.76 3.7580 1 1 3 4 25.18 2.99 3.5362 -2 1 1 4 25.80 12.62 3.4532 -2 0 4 2 26.16 3.50 3.4060 2 1 1 4 27.62 1.45 3.2300 -2 1 3 4 28.59 5.18 3.1223 -1 1 5 4 29.46 17.39 3.0318 2 0 4 2 30.03 18.73 2.9760 0 2 0 2 30.25 7.93 2.9546 2 1 3 4 30.61 22.23 2.9209 3 0 0 2 30.73 100.00 2.9092 1 1 5 4 30.83 19.95 2.8998 -3 0 2 2 31.23 1.91 2.8642 1 0 6 2 31.50 14.44 2.8402 0 2 2 4 31.75 12.13 2.8179 1 2 0 4 32.65 49.81 2.7429 -2 0 6 2 32.76 5.43 2.7333 -2 1 5 4 32.77 7.21 2.7331 -1 2 2 4 33.24 3.42 2.6956 3 0 2 2 33.54 8.58 2.6716 1 2 2 4 33.96 50.92 2.6396 -3 1 1 4 35.09 4.67 2.5576 3 1 1 4 35.59 56.11 2.5226 0 2 4 4 36.35 1.50 2.4716 0 1 7 4 36.38 5.34 2.4698 -1 2 4 4 36.50 16.73 2.4618 2 2 0 4 36.50 4.04 2.4617 2 1 5 4 36.59 32.94 2.4558 -1 1 7 4 37.05 5.98 2.4266 -2 2 2 4 37.10 1.15 2.4231 2 0 6 2 37.91 2.79 2.3736 -1 0 8 2 38.43 33.16 2.3421 2 2 2 4 38.66 15.75 2.3291 3 1 3 4 39.01 1.25 2.3086 1 1 7 4 39.13 1.50 2.3021 -3 0 6 2 39.40 9.25 2.2871 -3 1 5 4 39.99 3.97 2.2543 -2 2 4 4 40.76 28.01 2.2135 -2 0 8 2 41.06 7.93 2.1981 -4 0 2 2 41.21 6.43 2.1907 4 0 0 2 41.63 13.07 2.1696 0 2 6 4 42.00 3.42 2.1511 -1 2 6 4 42.57 27.14 2.1238 2 2 4 4 43.17 9.01 2.0958 -4 0 4 2 43.41 4.67 2.0846 3 2 0 4 43.58 2.70 2.0769 -3 2 2 4 43.58 3.94 2.0766 4 0 2 2 43.71 3.78 2.0711 -4 1 1 4 43.87 1.87 2.0637 1 2 6 4 44.18 1.85 2.0501 3 1 5 4 44.94 7.25 2.0169 -2 2 6 4 45.17 4.63 2.0073 -3 1 7 4 47.28 6.20 1.9227 -4 0 6 2 47.36 3.76 1.9195 1 3 1 4 47.65 1.43 1.9085 -4 1 5 4 47.83 1.64 1.9019 0 0 10 2 48.08 2.12 1.8925 1 1 9 4 48.17 4.55 1.8892 4 1 3 4 48.44 9.57 1.8790 2 2 6 4 48.81 1.20 1.8657 -1 3 3 4 49.04 17.98 1.8574 0 2 8 4 49.09 2.38 1.8557 -1 2 8 4 49.33 3.36 1.8472 3 2 4 4 50.10 1.30 1.8209 -3 2 6 4 51.82 1.27 1.7642 4 2 0 4 52.44 4.73 1.7449 -4 1 7 4 52.71 2.09 1.7367 3 0 8 2 53.04 1.23 1.7266 -4 0 8 2 53.16 6.50 1.7229 4 1 5 4 53.48 11.80 1.7135 -4 2 4 4 53.76 7.91 1.7050 1 3 5 4 53.83 1.43 1.7030 4 2 2 4 53.87 4.46 1.7018 4 0 6 2 54.01 1.73 1.6978 -3 0 10 2 54.71 4.27 1.6776 -5 1 3 4 54.99 6.56 1.6699 -1 1 11 4 55.08 4.96 1.6673 2 0 10 2 55.88 12.62 1.6454 -3 3 1 4 57.51 2.93 1.6026 0 2 10 4 57.60 43.09 1.6004 4 2 4 4 57.63 1.02 1.5996 2 3 5 4 57.69 3.36 1.5979 -1 3 7 4 58.21 14.79 1.5849 0 0 12 2 58.72 2.65 1.5724 -4 1 9 4 59.17 1.45 1.5614 3 3 3 4 59.18 19.18 1.5612 -2 2 10 4 59.38 1.69 1.5564 -2 0 12 2 59.71 3.04 1.5486 -3 3 5 4 59.79 3.47 1.5468 1 2 10 4 60.15 1.24 1.5385 -4 0 10 2 61.04 1.53 1.5180 -5 2 2 4 61.14 8.04 1.5159 4 0 8 2 61.39 1.14 1.5101 5 2 0 4 61.54 1.92 1.5068 3 0 10 2 62.16 22.13 1.4934 -4 2 8 4 62.40 2.98 1.4881 -5 2 4 4 62.41 29.19 1.4880 0 4 0 2 64.01 8.88 1.4546 2 2 10 4 65.96 2.59 1.4162 6 0 2 2 66.46 3.07 1.4067 -1 2 12 4 66.51 1.09 1.4058 4 3 3 4 66.98 1.93 1.3972 -6 0 6 2 67.62 2.21 1.3854 2 4 2 4 68.38 1.01 1.3718 3 1 11 4 68.41 5.32 1.3714 -4 0 12 2 69.60 1.26 1.3508 4 2 8 4 69.88 2.47 1.3461 -3 1 13 4 70.05 1.80 1.3432 -4 3 7 4 70.50 1.11 1.3358 2 4 4 4 70.66 2.40 1.3331 4 3 5 4 71.10 2.09 1.3259 3 4 0 4 71.23 2.03 1.3239 -3 4 2 4 71.48 5.96 1.3198 -6 2 2 4 71.99 2.99 1.3118 -5 3 3 4 72.22 2.79 1.3081 -1 3 11 4 72.23 6.18 1.3079 -2 4 6 4 72.52 7.16 1.3034 -6 2 4 4 73.52 1.16 1.2882 -5 1 11 4 74.15 1.44 1.2788 6 2 2 4 75.06 1.17 1.2654 6 0 6 2 75.27 1.08 1.2625 -7 0 2 2 75.47 1.11 1.2596 -4 3 9 4 75.95 1.48 1.2529 -5 2 10 4 75.99 3.64 1.2524 2 0 14 2 76.15 1.28 1.2501 -1 1 15 4 76.71 1.86 1.2424 5 1 9 4 77.19 3.59 1.2358 0 2 14 4 77.26 3.34 1.2349 -2 4 8 4 77.56 1.46 1.2309 4 4 0 4 78.79 1.21 1.2147 5 2 8 4 78.90 1.41 1.2133 -4 4 4 4 81.86 1.01 1.1768 -4 4 6 4 85.66 1.90 1.1339 -3 3 13 4 86.70 1.19 1.1230 5 2 10 4 86.89 3.55 1.1211 1 5 5 4 86.98 1.09 1.1202 4 4 6 4 87.96 1.30 1.1102 2 4 10 4 88.59 2.52 1.1039 0 2 16 4 88.62 1.08 1.1036 -3 5 1 4 89.09 1.19 1.0991 -8 0 4 2 89.47 1.21 1.0953 6 2 8 4 89.84 1.62 1.0918 7 2 4 4 89.96 1.14 1.0906 -7 2 8 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.