Giacovazzoite Biagioni C, Bindi L, Mauro D, Pasero M Physics and Chemistry of Minerals 47 (2020) 7 Crystal-chemistry of sulfates from the Apuan Alps (Tuscany, Italy). IV. Giacovazzoite, K5Fe3+3O(SO4)6(H2O)9*H2O, the natural analogue of the ß-Maus's salt and its dehydration product Note: T = 100 K Locality: the Monte Arsiccio mine, Apuan Alps, Tuscany, Italy _database_code_amcsd 0020910 9.4480 18.3183 17.9825 90 92.274 90 P2_1/c atom x y z Uiso U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3) K1 .54415 .15573 .24416 .01300 .0140 .0119 .0130 -.0008 -.0005 -.0003 K2 .63785 .22595 .03564 .01687 .0195 .0104 .0202 -.0009 -.0054 .0010 K3 .26611 .10184 .04798 .01583 .0197 .0110 .0167 -.0018 -.0005 -.0025 K4 .12505 .20433 .27235 .01689 .0143 .0103 .0258 .0028 -.0028 .0006 K5 .32617 .11271 .44081 .01598 .0211 .0116 .0153 .0010 .0016 .0021 Fe1 .31621 .41663 .25801 .00789 .0090 .00540 .00925 .00017 -.00064 -.00021 Fe2 .63609 .40773 .34320 .00819 .0090 .00558 .00984 .00021 -.00081 .00020 Fe3 .59944 .39646 .15778 .00847 .0094 .00609 .00986 .00054 -.00017 -.00016 S1 .39126 .52165 .39297 .00851 .0098 .0056 .0100 .0002 -.0005 -.0008 S2 .39806 .29491 .38371 .00901 .0104 .0058 .0107 -.0004 -.0006 .0011 S3 .78161 .52346 .24106 .00932 .0101 .0058 .0120 -.0006 -.0003 .0002 S4 .81673 .29379 .24349 .00920 .0094 .0061 .0120 .0007 -.0003 .0003 S5 .36450 .51371 .10715 .00941 .0118 .0066 .0098 .0011 -.0011 .0004 S6 .31440 .29483 .12870 .00908 .0100 .0061 .0109 .0006 -.0019 -.0014 O1 .3331 .51081 .31504 .0106 .0128 .0083 .0106 .0011 -.0018 -.0017 O2 .5094 .46856 .40712 .0120 .0126 .0109 .0124 .0015 -.0011 -.0007 O3 .2797 .50662 .44520 .0124 .0149 .0094 .0131 -.0007 .0009 -.0011 O4 .4442 .59605 .40020 .0133 .0159 .0077 .0160 -.0029 -.0019 -.0007 O5 .3076 .35512 .35081 .0108 .0127 .0081 .0116 .0025 .0005 .0010 O6 .5500 .31631 .37780 .0136 .0095 .0098 .0215 .0000 -.0003 .0061 O7 .3680 .28700 .46209 .0145 .0183 .0140 .0114 .0000 .0005 .0037 O8 .3743 .22766 .34214 .0146 .0191 .0062 .0181 .0001 -.0037 -.0019 O9 .7352 .50089 .31633 .0124 .0180 .0078 .0116 -.0034 .0023 -.0003 O10 .7679 .45952 .18991 .0104 .0111 .0068 .0131 -.0005 -.0005 -.0016 O11 .9320 .54472 .24815 .0122 .0117 .0085 .0163 -.0014 -.0010 .0002 O12 .6962 .58470 .21386 .0128 .0142 .0067 .0172 .0011 -.0028 .0003 O13 .7938 .34690 .30513 .0128 .0121 .0127 .0136 .0024 .0006 -.0033 O14 .6979 .30248 .18645 .0119 .0119 .0084 .0152 .0017 -.0021 -.0005 O15 .9524 .31061 .21054 .0126 .0105 .0096 .0178 .0005 .0012 -.0006 O16 .8143 .21918 .27127 .0140 .0165 .0059 .0194 -.0004 -.0012 .0032 O17 .5112 .48214 .10742 .0134 .0127 .0136 .0142 .0025 .0027 .0056 O18 .2841 .47660 .16563 .0130 .0122 .0144 .0124 .0006 .0005 .0012 O19 .2937 .50093 .03541 .0132 .0170 .0114 .0109 -.0024 -.0022 .0004 O20 .3787 .59139 .12256 .0165 .0227 .0073 .0193 .0000 -.0025 -.0014 O21 .4500 .33140 .10840 .0146 .0116 .0181 .0142 -.0031 .0020 -.0050 O22 .2710 .32571 .20116 .0115 .0134 .0091 .0123 -.0026 .0016 -.0038 O23 .2070 .31122 .07069 .0140 .0131 .0139 .0147 .0031 -.0039 -.0019 O24 .3376 .21723 .13912 .0176 .0297 .0078 .0151 .0030 -.0022 -.0014 O25 .5174 .40817 .25241 .0097 .0102 .0091 .0097 .0014 -.0016 .0007 OW26 .0990 .42464 .27070 .0113 .0092 .0085 .0161 .0006 -.0004 -.0008 OW27 .7620 .40300 .43961 .0130 .0140 .0114 .0133 .0018 -.0023 -.0024 OW28 .7038 .38409 .05968 .0127 .0138 .0127 .0117 .0010 .0012 .0016 OW29 -.0024 .0701 .1013 .0388 .031 .053 .0310 -.0108 -.0090 .0135 OW30 .9195 .2133 .0743 .0414 .038 .037 .048 .0012 -.0072 -.0034 OW31 .9775 .40551 .05600 .0163 .0126 .0151 .0212 .0018 .0008 .0031 OW32 .9556 .55378 .08561 .0210 .0245 .0181 .0208 .0013 .0054 -.0002 OW33 .9251 .72919 .07272 .0196 .0172 .0197 .0219 .0009 -.0009 -.0006 OW34 .9614 .88056 .06621 .0172 .0156 .0149 .0214 -.0024 .0043 -.0046 OW35 .7890 .20698 .42857 .0180 .0186 .0176 .0177 -.0043 -.0016 .0050 H261 .049 .387 .246 .05 H262 .057 .463 .244 .06 H271 .751 .438 .478 .07 H272 .861 .403 .433 .05 H281 .804 .384 .059 .022 H282 .717 .427 .032 .06 H291 -.009 .065 .1543 .06 H292 -.088 .052 .075 .08 H311 .055 .381 .076 .015 H321 .024 .565 .051 .06 H322 .023 .564 .124 .027 H331 .882 .732 .0248 .046 H332 .020 .719 .060 .024 H341 .970 .8296 .069 .07 H342 .926 .904 .107 .037 H351 .795 .225 .3796 .036 H352 .715 .173 .430 .11