data_global _amcsd_formula_title 'Mn2Fe(CO)14' loop_ _publ_author_name 'Agron P' 'Ellison R' 'Levy H' _journal_name_full 'Acta Crystallographica' _journal_volume 23 _journal_year 1967 _journal_page_first 1079 _journal_page_last 1086 _publ_section_title ; The crystal structure of dimanganese iron carbonyl, Mn2Fe(CO)14 _cod_database_code 1008061 ; _database_code_amcsd 0016003 _chemical_formula_sum 'Mn2 Fe C14 O14' _cell_length_a 11.935 _cell_length_b 14.287 _cell_length_c 11.732 _cell_angle_alpha 90 _cell_angle_beta 97.23 _cell_angle_gamma 90 _cell_volume 1984.580 _exptl_crystal_density_diffrn 1.867 _symmetry_space_group_name_H-M 'C 1 2/m 1' loop_ _space_group_symop_operation_xyz 'x,y,z' '1/2+x,1/2+y,z' 'x,-y,z' '1/2+x,1/2-y,z' '-x,y,-z' '1/2-x,1/2+y,-z' '-x,-y,-z' '1/2-x,1/2-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z Mn1 0.22000 0.00000 -0.06530 Mn2 0.00000 0.30410 0.50000 Fe1 0.00000 0.00000 0.00000 Fe2 0.00000 0.50000 0.50000 C1 0.05800 0.00000 0.14860 O1 0.09460 0.00000 0.24410 C2 0.00000 0.12500 0.00000 O2 0.00000 0.20620 0.00000 C3 0.16930 0.09120 -0.17170 O3 0.14010 0.14650 -0.23770 C4 0.36100 0.00000 -0.10420 O4 0.44980 0.00000 -0.12880 C5 0.25250 0.09400 0.04320 O5 0.27490 0.15370 0.10550 C6 0.12820 0.50000 0.43580 O6 0.21060 0.50000 0.39480 C7 0.08190 0.50000 0.64080 O7 0.13530 0.50000 0.72830 C8 0.00000 0.17720 0.50000 O8 0.00000 0.09820 0.50000 C9 0.14900 0.31520 0.56500 O9 0.24020 0.32100 0.60550 C10 0.04370 0.30880 0.35380 O10 0.07000 0.30960 0.26350