data_global
_chemical_name_mineral 'Stephanite'
loop_
_publ_author_name
'Ribar B'
'Nowacki W'
_journal_name_full 'Acta Crystallographica, Section B'
_journal_volume 26 
_journal_year 1970
_journal_page_first 201
_journal_page_last 207
_publ_section_title
;
 Die kristallstruktur von stephanit, [SbS3|S|Ag5]
;
_database_code_amcsd 0009367
_chemical_formula_sum 'Sb Ag5 S4'
_cell_length_a 7.873
_cell_length_b 12.467
_cell_length_c 8.583
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 842.445
_exptl_crystal_density_diffrn      6.224
_symmetry_space_group_name_H-M 'C m c 21'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
  '-x,y,z'
  '1/2-x,1/2+y,z'
  '-x,-y,1/2+z'
  '1/2-x,1/2-y,1/2+z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Sb   0.00000   0.33072   0.09900
Ag1   0.50000   0.35543   0.16922
Ag2   0.18902   0.06219   0.32683
Ag3   0.31406   0.12312   0.01357
S1   0.00000   0.03031   0.02449
S2   0.50000   0.01522   0.20585
S3   0.23005   0.26679   0.27307
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Sb 0.02518 0.01961 0.01414 0.00000 0.00000 -0.00217
Ag1 0.04424 0.05039 0.05158 0.00000 0.00000 0.01420
Ag2 0.05885 0.06953 0.04318 -0.02178 0.01095 0.21413
Ag3 0.05194 0.05299 0.02243 0.01626 0.00113 0.01041
S1 0.02452 0.01929 0.01657 0.00000 0.00000 -0.00434
S2 0.02704 0.01528 0.01728 0.00000 0.00000 -0.00217
S3 0.02452 0.01646 0.02489 -0.00045 -0.00168 -0.00461