data_global
_chemical_name_mineral 'Zincolivenite'
loop_
_publ_author_name
'Toman K'
_journal_name_full 'Acta Crystallographica, Section B'
_journal_volume 34 
_journal_year 1978
_journal_page_first 715
_journal_page_last 721
_publ_section_title
;
 Ordering in olivenite-adamite solid solutions
;
_database_code_amcsd 0009626
_chemical_compound_source 'Tsumeb, Southwest Africa'
_chemical_formula_sum 'As Zn1.14 Cu.86 O5 H'
_cell_length_a 8.50
_cell_length_b 8.52
_cell_length_c 5.99
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 433.796
_exptl_crystal_density_diffrn      4.366
_symmetry_space_group_name_H-M 'P n n m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2-y,1/2+z'
  '1/2-x,1/2+y,1/2-z'
  '1/2-x,1/2+y,1/2+z'
  '1/2+x,1/2-y,1/2-z'
  'x,y,-z'
  '-x,-y,z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
As   0.25220   0.26180   0.00000   1.00000 ?
Zn  -0.12760   0.36210   0.00000   1.00000 ?
Cu   0.00000   0.00000   0.24870   0.86000 ?
Zn   0.00000   0.00000   0.24870   0.14000 ?
O1   0.10600   0.39400   0.00000   1.00000   0.01267
O2   0.42400   0.36700   0.00000   1.00000   0.00887
O-H3  -0.10400   0.11900   0.00000   1.00000   0.02026
O4   0.23700   0.14400   0.22400   1.00000   0.02026
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
As 0.00590 0.01190 0.00730 -0.00030 0.00000 0.00000
Zn 0.00650 0.01440 0.01140 0.00090 0.00000 0.00000
Cu 0.01180 0.01650 0.00750 0.00730 0.00000 0.00000
Zn 0.01180 0.01650 0.00750 0.00730 0.00000 0.00000