data_global
_amcsd_formula_title 'O3 Tl0.3 W'
loop_
_publ_author_name
'Labbe P'
'Goreaud M'
'Raveau B'
'Monier J'
_journal_name_full 'Acta Crystallographica, Section B'
_journal_volume 34 
_journal_year 1978
_journal_page_first 1433
_journal_page_last 1438
_publ_section_title
;
 Etude comparative des structures Mx WO3 de type bronze hexagonal.
 I. Analyse structurale des bronzes de composition  M0.30 W O3 .
 Stereochimie des elements M=Rb, Tl et In
 _cod_database_code 1001021
;
_database_code_amcsd 0009640
_chemical_formula_sum 'W3 O9 Tl.9'
_cell_length_a 7.3810
_cell_length_b 7.3810
_cell_length_c 7.5091
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 354.282
_exptl_crystal_density_diffrn      8.244
_symmetry_space_group_name_H-M 'P 63/m c m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x,-x+y,z'
  'x,x-y,-z'
  '-x+y,-x,1/2-z'
  'x-y,x,1/2+z'
  '-y,-x,1/2+z'
  'y,x,1/2-z'
  'y,-x+y,-z'
  '-y,x-y,z'
  'x-y,-y,z'
  '-x+y,y,-z'
  'x,y,1/2-z'
  '-x,-y,1/2+z'
  'x,x-y,1/2+z'
  '-x,-x+y,1/2-z'
  'x-y,x,-z'
  '-x+y,-x,z'
  'y,x,z'
  '-y,-x,-z'
  '-y,x-y,1/2-z'
  'y,-x+y,1/2+z'
  '-x+y,y,1/2+z'
  'x-y,-y,1/2-z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
W1   0.00000   0.47744   0.25000   1.00000
O1   0.21180   0.42000   0.25000   1.00000
O2   0.00000   0.46350  -0.00200   0.50000
Tl1   0.00000   0.00000   0.03070   0.45000